Activation of Mo2B Catalyst in the Epoxidation Reaction of α-Ethylallyl Ethyl Acrylate with tert-Butyl Hydroperoxide

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dc.citation.epage23
dc.citation.issue1
dc.citation.spage18
dc.contributor.affiliationLviv Polytechnic National University
dc.contributor.authorKomarenska, Zoryana
dc.contributor.authorOliynyk, Lilianna
dc.contributor.authorMakota, Oksana
dc.coverage.placenameЛьвів
dc.coverage.placenameLviv
dc.date.accessioned2024-02-09T10:29:40Z
dc.date.available2024-02-09T10:29:40Z
dc.date.created2023-02-28
dc.date.issued2023-02-28
dc.description.abstractВивчено закономірності активування каталізатора Мо2В у реакції епоксидування α етилалілетилакрилату трет-бутилгідропероксидом. Показано, що процес активування каталізатора описується топохімічним рівнянням Аврамі-Єрофеєва і містить дві послідовні стадії – зародкоутворення і формування нової фази, активної в реакції епоксидування. Утворення епоксиду відбувається тільки в присутності активованої форми каталізатора. Обчислено ефективні й топохімічні константи процесу.
dc.description.abstractThe regularities of Mo2B catalyst activation in the epoxidation reaction of alfa-ethylallyl ethyl acrylate with tert-butyl hydroperoxide have been studied. It has been shown that the catalyst activation process is described by the Avrami-Erofeev topokinetic equation and includes two successive stages – the nucleation and formation of a new phase active in the epoxidation reaction. The formation of epoxy only occurs in the presence of the activated form of the catalyst. The effective and topochemical process constants have been calculated.
dc.format.extent18-23
dc.format.pages6
dc.identifier.citationKomarenska Z. Activation of Mo2B Catalyst in the Epoxidation Reaction of α-Ethylallyl Ethyl Acrylate with tert-Butyl Hydroperoxide / Zoryana Komarenska, Lilianna Oliynyk, Oksana Makota // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2023. — Vol 17. — No 1. — P. 18–23.
dc.identifier.citationenKomarenska Z. Activation of Mo2B Catalyst in the Epoxidation Reaction of α-Ethylallyl Ethyl Acrylate with tert-Butyl Hydroperoxide / Zoryana Komarenska, Lilianna Oliynyk, Oksana Makota // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2023. — Vol 17. — No 1. — P. 18–23.
dc.identifier.doidoi.org/10.23939/chcht17.01.018
dc.identifier.issn1196-4196
dc.identifier.urihttps://ena.lpnu.ua/handle/ntb/61225
dc.language.isoen
dc.publisherВидавництво Львівської політехніки
dc.publisherLviv Politechnic Publishing House
dc.relation.ispartofChemistry & Chemical Technology, 1 (17), 2023
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dc.rights.holder© Національний університет “Львівська політехніка”, 2023
dc.rights.holder© Komarenska Z., Oliynyk L., Makota O., 2023
dc.subjectокиснення
dc.subjectкінетичні закономірності
dc.subjectкаталізатор
dc.subjectолефін
dc.subjectoxidation
dc.subjectkinetic laws
dc.subjectcatalyst olefin
dc.titleActivation of Mo2B Catalyst in the Epoxidation Reaction of α-Ethylallyl Ethyl Acrylate with tert-Butyl Hydroperoxide
dc.title.alternativeАктивування каталізатора Мо2В в реакції епоксидування α-етилалілетилакрилату трет-бутилгідропероксидом
dc.typeArticle

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Chemistry & Chemical Technology. – 2023. – Vol. 17, No. 1