The influence of exposure time on changing of the properties of the soda solution of quinhydrone during the quinhydrone catalyst preparation
| dc.citation.epage | 72 | |
| dc.citation.issue | 2 | |
| dc.citation.spage | 68 | |
| dc.contributor.affiliation | Національний університет “Львівська політехніка” | |
| dc.contributor.affiliation | Lviv Polytechnic National University | |
| dc.contributor.author | Слюзар, А. В. | |
| dc.contributor.author | Хом’як, С. В. | |
| dc.contributor.author | Калимон, Я. А. | |
| dc.contributor.author | Slyuzar, A. V. | |
| dc.contributor.author | Khomyak, S. V. | |
| dc.contributor.author | Kalymon, Ya. A. | |
| dc.coverage.placename | Lviv | |
| dc.coverage.placename | Lviv | |
| dc.date.accessioned | 2020-03-02T09:14:31Z | |
| dc.date.available | 2020-03-02T09:14:31Z | |
| dc.date.created | 2019-02-28 | |
| dc.date.issued | 2019-02-28 | |
| dc.description.abstract | Методами ЦВА, ІЧ та УФ спектроскопії досліджено содові розчини хінгідрону під час їх вистоювання (експозиції) за доступу повітря. Показано, що в процесі вистоювання розчину відбувається олігомеризація хінгідрону і зміна його окисно-відновних властивостей. У часі вистоювання редокс потенціал розчинів зростає, рН знижується, зменшуються і повністю загасають струми піків окиснення, що вказує на стабілізацію властивостей олігомера. Встановлено, що за часу вистоювання понад 8 років у розчині хінгідронного каталізатора присутні окисні форми, і такий розчин не втрачає окисних властивостей щодо хемосорбованого сірководню. | |
| dc.description.abstract | Change of the properties of soda solution of quinhydrone during their exposure in the presence of air has been investigated by the methods of cyclic voltammetry and spectroscopy (IR and UV). It has been shown that in the process of exposure of the solution occurs the process of quinhydrone oligomerization and changes its redox properties. The redox potential of the solution increases, the pH decreases, the currents of oxidation peaks decrease and completely dampen, indicating the stabilization of the properties of the oligomer. It has been established that the oxidizing forms of the oligomer are still present in the quinhydrone catalyst solution for more than 8 years and the solution does not lose oxidizing properties to chemisorbed hydrogen sulfide. | |
| dc.format.extent | 68-72 | |
| dc.format.pages | 5 | |
| dc.identifier.citation | Slyuzar A. V. The influence of exposure time on changing of the properties of the soda solution of quinhydrone during the quinhydrone catalyst preparation / A. V. Slyuzar, S. V. Khomyak, Ya. A. Kalymon // Chemistry, Technology and Application of Substances. — Lviv : Lviv Politechnic Publishing House, 2019. — Том 2. — № 2. — С. 68–72. | |
| dc.identifier.citationen | Slyuzar A. V. The influence of exposure time on changing of the properties of the soda solution of quinhydrone during the quinhydrone catalyst preparation / A. V. Slyuzar, S. V. Khomyak, Ya. A. Kalymon // Chemistry, Technology and Application of Substances. — Lviv : Lviv Politechnic Publishing House, 2019. — Vol 2. — No 2. — P. 68–72. | |
| dc.identifier.uri | https://ena.lpnu.ua/handle/ntb/46386 | |
| dc.language.iso | en | |
| dc.publisher | Lviv Politechnic Publishing House | |
| dc.publisher | Lviv Politechnic Publishing House | |
| dc.relation.ispartof | Chemistry, Technology and Application of Substances, 2 (2), 2019 | |
| dc.relation.references | 1. Slyuzar, A. V., Znak, Z. O., Kalymon, Ya. A., & Bukliv, R. L. (2019). Metody ochyshchennia i pereroblennia sirkovodenvmisnykh haziv (ohliad) [Methods of purification and processing of hydrogen sulfide-containing gases: a review.] Voprosy Khimii i Khimicheskoi Tekhnologii – Issues of Chemistry and Chemical Technology, 3, 83-97. [in Ukrainian]. | |
| dc.relation.references | 2. Kohl, A. L., & Nielsen, R. B. (1997). Gas Purification. Houston: Gulf Publishing Company. | |
| dc.relation.references | 3. Yavorskiy, V., Slyuzar, A., & Kalymon, Ya. (2016). Sulfur gas production in Ukraine (review). Chemistry and Chemical Technology, 10, 4(s), 613-619. | |
| dc.relation.references | 4. Znak, Z. О. (1992) Intensyfikatsiia i optymizatsiia khinhidronnoho metodu ochystky haziv vid sirkovodniu z oderzhanniam sirky – [Intensification and optimization of the quinhydrone purification method from hydrogen sulfide to sulfur production: (Extended abstract of Candidate’s thesis). Lviv. [in Ukrainian]. | |
| dc.relation.references | 5. Znak, Z. О., Yavorskiy, V. T., & Levashova, V. L. (1990). Protcess polimerizatcii khingidrona v shchelochnoi srede. Kinetika i kataliz – Kinetics and catalysis, 31, 1, 197-202. [in Russian]. | |
| dc.relation.references | 6. Yavorskiy, V. T., Kalymon, Ya. A., Znak, Z. O., & Chaiko, N. Y. (2000). Tekhnolohiia pryhotuvannia pohlynalnoho rozchynu na osnovi khinhidronu dlia ochyshchennia haziv vid sirkovodniu // Ekotekhnologii i resursosberezhenie – Ecotechnology and resource-saving, 5, 56-59. [in Ukrainian]. | |
| dc.relation.references | 7. Yavorskiy, V. T., Slyuzar, A. V., Mertsalo, I. P., Kalymon, Ya. A. (2011). Vplyv metodyky pryhotuvannia khinhidronnoho rozchynu ochyshchennia haziv vid sirkovodniu na yoho fizyko-khimichni i okysno-vidnovni vlastyvosti. Voprosy Khimii i Khimicheskoi Tekhnologii – Issues of Chemistry and Chemical Technology, 4(2), 301-304 [in Ukrainian]. | |
| dc.relation.references | 8. Yavorskiy, V. T., Slyuzar, A. V., Kalymon Ya. A., & Mertsalo, I. P. (2005). Elektrokhimichni vlastyvosti khinhidronu v luzhnomu rozchyni. Visnyk NTU ”Kharkivskyi politekhnichnyi instytut”, 16, 166-169. [in Ukrainian]. | |
| dc.relation.references | 9. Danylov, F. Y., & Protsenko, V. S. (2016). Liniina ta tsyklichna voltamperometriia – Linear and cyclic voltammetry. Dnipro: LIRA. [in Ukrainian]. | |
| dc.relation.references | 10. Rafiee, M., & Nematollahi D. (2007). Voltammetry of Electroinactive Species Using Quinone/ Hydroquinone Redox: A Known Redox System Viewed in a New Perspective. Electroanalysis, 19(13), 1382-1386. | |
| dc.relation.references | 11. Guin, P. S., Das, S. & Mandal, P. C. (2011) Electrochemical Reduction of Quinones in Different Media: A Review. International Journal of Electrochemistry, 1-22. | |
| dc.relation.references | 12. Rojas de Astudillo L., Rivera L., Brito-Gómez R. & Tremont R. J. (2010). Еlectrochemical study of 1,4- benzoquinone on gold surface modified Journal of Electroanalytical Chemistry, 56-60. | |
| dc.relation.references | 13. Anamul Haque, M., Muhibur Rahman, M. & Abu Bin Hasan Susan, M. (2011). Aqueous Electrochemistry of Anthraquinone and Its Correlation with the Dissolved States of a Cationic Surfactant. Journal of Solution Chemistry, 40(5), 861-875. | |
| dc.relation.references | 14. May Quan, Sanchez, D., Wasylkiw M. F., & Smith D. F. (2007). Voltammetry of Quinones in Unbuffered Aqueous Solution: Reassessing the Roles of Proton Transfer and Hydrogen Bonding in the Aqueous Electrochemistry of Quinones. Journal of the American Chemical Society. 129, 42, 12847-12856. | |
| dc.relation.references | 15. Skoog, D. A., & Holler, F. J. (2007). Principles of Instrumental Analysis. Australia: Thomson Brooks. | |
| dc.relation.referencesen | 1. Slyuzar, A. V., Znak, Z. O., Kalymon, Ya. A., & Bukliv, R. L. (2019). Metody ochyshchennia i pereroblennia sirkovodenvmisnykh haziv (ohliad) [Methods of purification and processing of hydrogen sulfide-containing gases: a review.] Voprosy Khimii i Khimicheskoi Tekhnologii – Issues of Chemistry and Chemical Technology, 3, 83-97. [in Ukrainian]. | |
| dc.relation.referencesen | 2. Kohl, A. L., & Nielsen, R. B. (1997). Gas Purification. Houston: Gulf Publishing Company. | |
| dc.relation.referencesen | 3. Yavorskiy, V., Slyuzar, A., & Kalymon, Ya. (2016). Sulfur gas production in Ukraine (review). Chemistry and Chemical Technology, 10, 4(s), 613-619. | |
| dc.relation.referencesen | 4. Znak, Z. O. (1992) Intensyfikatsiia i optymizatsiia khinhidronnoho metodu ochystky haziv vid sirkovodniu z oderzhanniam sirky – [Intensification and optimization of the quinhydrone purification method from hydrogen sulfide to sulfur production: (Extended abstract of Candidate’s thesis). Lviv. [in Ukrainian]. | |
| dc.relation.referencesen | 5. Znak, Z. O., Yavorskiy, V. T., & Levashova, V. L. (1990). Protcess polimerizatcii khingidrona v shchelochnoi srede. Kinetika i kataliz – Kinetics and catalysis, 31, 1, 197-202. [in Russian]. | |
| dc.relation.referencesen | 6. Yavorskiy, V. T., Kalymon, Ya. A., Znak, Z. O., & Chaiko, N. Y. (2000). Tekhnolohiia pryhotuvannia pohlynalnoho rozchynu na osnovi khinhidronu dlia ochyshchennia haziv vid sirkovodniu, Ekotekhnologii i resursosberezhenie – Ecotechnology and resource-saving, 5, 56-59. [in Ukrainian]. | |
| dc.relation.referencesen | 7. Yavorskiy, V. T., Slyuzar, A. V., Mertsalo, I. P., Kalymon, Ya. A. (2011). Vplyv metodyky pryhotuvannia khinhidronnoho rozchynu ochyshchennia haziv vid sirkovodniu na yoho fizyko-khimichni i okysno-vidnovni vlastyvosti. Voprosy Khimii i Khimicheskoi Tekhnologii – Issues of Chemistry and Chemical Technology, 4(2), 301-304 [in Ukrainian]. | |
| dc.relation.referencesen | 8. Yavorskiy, V. T., Slyuzar, A. V., Kalymon Ya. A., & Mertsalo, I. P. (2005). Elektrokhimichni vlastyvosti khinhidronu v luzhnomu rozchyni. Visnyk NTU "Kharkivskyi politekhnichnyi instytut", 16, 166-169. [in Ukrainian]. | |
| dc.relation.referencesen | 9. Danylov, F. Y., & Protsenko, V. S. (2016). Liniina ta tsyklichna voltamperometriia – Linear and cyclic voltammetry. Dnipro: LIRA. [in Ukrainian]. | |
| dc.relation.referencesen | 10. Rafiee, M., & Nematollahi D. (2007). Voltammetry of Electroinactive Species Using Quinone/ Hydroquinone Redox: A Known Redox System Viewed in a New Perspective. Electroanalysis, 19(13), 1382-1386. | |
| dc.relation.referencesen | 11. Guin, P. S., Das, S. & Mandal, P. C. (2011) Electrochemical Reduction of Quinones in Different Media: A Review. International Journal of Electrochemistry, 1-22. | |
| dc.relation.referencesen | 12. Rojas de Astudillo L., Rivera L., Brito-Gómez R. & Tremont R. J. (2010). Electrochemical study of 1,4- benzoquinone on gold surface modified Journal of Electroanalytical Chemistry, 56-60. | |
| dc.relation.referencesen | 13. Anamul Haque, M., Muhibur Rahman, M. & Abu Bin Hasan Susan, M. (2011). Aqueous Electrochemistry of Anthraquinone and Its Correlation with the Dissolved States of a Cationic Surfactant. Journal of Solution Chemistry, 40(5), 861-875. | |
| dc.relation.referencesen | 14. May Quan, Sanchez, D., Wasylkiw M. F., & Smith D. F. (2007). Voltammetry of Quinones in Unbuffered Aqueous Solution: Reassessing the Roles of Proton Transfer and Hydrogen Bonding in the Aqueous Electrochemistry of Quinones. Journal of the American Chemical Society. 129, 42, 12847-12856. | |
| dc.relation.referencesen | 15. Skoog, D. A., & Holler, F. J. (2007). Principles of Instrumental Analysis. Australia: Thomson Brooks. | |
| dc.rights.holder | © Національний університет „Львівська політехніка“, 2019 | |
| dc.subject | хінгідрон | |
| dc.subject | карбонатний розчин | |
| dc.subject | олігомеризація | |
| dc.subject | час експозиції | |
| dc.subject | окисно-відновні властивості | |
| dc.subject | quinhydrone | |
| dc.subject | carbonate solution | |
| dc.subject | oligomerization | |
| dc.subject | exposure time | |
| dc.subject | redox properties | |
| dc.title | The influence of exposure time on changing of the properties of the soda solution of quinhydrone during the quinhydrone catalyst preparation | |
| dc.title.alternative | Вплив часу експозиції на зміну властивостей карбонатного розчину хінгідрону в процесі приготування хінгідронного каталізатора | |
| dc.type | Article |
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