Parametric and Kinetic Study of Nitrate Removal from Water by Modified Chitosan Composite Beads

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dc.citation.epage93
dc.citation.issue1
dc.citation.journalTitleХімія та хімічна технологія
dc.citation.spage83
dc.citation.volume18
dc.contributor.affiliationUniversity of Baghdad
dc.contributor.authorJamka, Zainab N.
dc.contributor.authorMohammed, Wadood T.
dc.coverage.placenameЛьвів
dc.coverage.placenameLviv
dc.date.accessioned2025-09-24T06:19:50Z
dc.date.created2024-03-01
dc.date.issued2024-03-01
dc.description.abstractЗабруднення водних об'єктів шкідливими забруднюючими речовинами є однією з найгостріших глобальних проблем. Поточне дослідження зосереджено на розробці ефективного адсорбенту для видалення нітрат-іонів з водних розчинів. У дослідженні запропоновано модифіковані композитні хітозан-цеолітні кульки для підвищення ефективності процесу адсорбції. Цеоліт використовували для збільшення площі поверхні, а цирконій наносили на кульки для підвищення селективності щодо нітрат-аніонів. Механізм адсорбції оцінювали, характеризуючи вихідні кульки та кульки з адсорбованим сорбатом за допомогою рентгеноструктурного аналізу (XRD), інфрачервоної спектроскопії з перетворенням Фур'є (FTIR), польової емісійної сканувальної електронної мікроскопії (FESEM) та аналізу за допомогою енергодисперсійного рентгенівського аналізатора (EDX). Досліди проводили в системі періодичної дії та вивчали вплив ключових параметрів, таких як час контакту, початкова концентрація нітрат-аніонів і дозування адсорбенту на ефективність адсорбції. Результати показали, що найвищий ступінь вилучення нітрат-іонів був зафіксований на рівні 95,42 % за використання 0,2 г Cs-Ze-Zr адсорбенту з початковою концентрацією 50 мг/л і часом контакту 120 хвилин. Максимальна адсорбційна здатність щодо нітрат-іонів на виготовленій кульці становила 80,15 мг/г. Крім того, серед ізотерм Фрейндліха, Ленгмюра і Темкіна дані про рівновагу ізотерми узгоджувалися з моделлю ізотерми Фрейндліха. Кінетичні дані для адсорбції були задовільно апроксимовані псевдопершим порядком. Отримані результати чітко вказують на те, що запропонований адсорбент (Cs-Ze-Zr) може бути успішно використаний для вилучення нітрат-іонів, що підтверджується високою ефективністю вилучення й адсорбційною здатністю, отриманою в дослідженні.
dc.description.abstractThe contamination of water bodies with harmful pollutants considers an aggravating global problem. The current research focuses on a developing efficient adsorbed for removing nitrate ions from aqueous solutions. The study proposed modified chitosan-zeolite composite beads to enhance the performance of the adsorption process. The zeolite was used to increase the surface area, and Zirconium was loaded on the beads to promote the selectivity for nitrate anions. The adsorption mechanism was assessed by characterizing the beads and sorbate adsorbed beads utilizing X-ray diffraction analysis (XRD), Fourier transform infrared spectroscopy (FTIR), Field Emission Scanning Electron Microscopy (FESEM), and analysis with an energy dispersive X-ray analyzer (EDX). The experiments were conducted in a batch system, and the effect of key parameters like contact time, initial nitrate anion concentration, and adsorbent dosage on the adsorption performance was investigated. The results demonstrated that the highest removal of nitrate ions was determined to be 95.42% at 0.2 g of Cs-Ze-Zr adsorbent with an initial concentration of 50 mg/L and a contact time of 120 minutes. The maximum adsorption capacity of the nitrate ions on the manufactured bead was 80.15 mg/g. In addition, among the Freundlich, Langmuir, and Temkin isotherms, the isotherm equilibrium data were consistent with a Freundlich isotherm model. The kinetic data for adsorption were satisfactorily fitted by a pseudo-first order. Subsequently, the results distinctly indicated that the proposed adsorbed (Cs-Ze-Zr) could be employed fruitfully in removing nitrate ions, demonstrated through the remarkable removal efficiency and adsorption capacity obtained in the study.
dc.format.extent83-93
dc.format.pages11
dc.identifier.citationJamka Z. N. Parametric and Kinetic Study of Nitrate Removal from Water by Modified Chitosan Composite Beads / Zainab N. Jamka, Wadood T. Mohammed // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2024. — Vol 18. — No 1. — P. 83–93.
dc.identifier.citationenJamka Z. N. Parametric and Kinetic Study of Nitrate Removal from Water by Modified Chitosan Composite Beads / Zainab N. Jamka, Wadood T. Mohammed // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2024. — Vol 18. — No 1. — P. 83–93.
dc.identifier.doidoi.org/10.23939/chcht18.01.083
dc.identifier.urihttps://ena.lpnu.ua/handle/ntb/111773
dc.language.isoen
dc.publisherВидавництво Львівської політехніки
dc.publisherLviv Politechnic Publishing House
dc.relation.ispartofХімія та хімічна технологія, 1 (18), 2024
dc.relation.ispartofChemistry & Chemical Technology, 1 (18), 2024
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dc.rights.holder© Національний університет “Львівська політехніка”, 2024
dc.rights.holder© Jamka Z. N., Mohammed W. T., 2024
dc.subjectмодифікований хітозан
dc.subjectперіодична адсорбція
dc.subjectнітрат
dc.subjectцеоліт
dc.subjectцирконій
dc.subjectmodified chitosan
dc.subjectbatch adsorption
dc.subjectnitrate
dc.subjectzeolite
dc.subjectzirconium
dc.titleParametric and Kinetic Study of Nitrate Removal from Water by Modified Chitosan Composite Beads
dc.title.alternativeПараметричне та кінетичне дослідження видалення нітратів з води модифікованими композитними кульками з хітозану
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Chemistry & Chemical Technology. – 2024. – Vol. 18, No. 1