Electrochemical Determination of Dopamine and Uric Acid Using Poly(proline) Modified Carbon Paste Electrode: A Cyclic Voltammetric Study

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dc.citation.epage160
dc.citation.issue2
dc.citation.spage153
dc.contributor.affiliationConstituent College of Mangalore University
dc.contributor.authorEdwin S. D’ Souza
dc.contributor.authorManjunath, Jamballi G.
dc.contributor.authorRaril, Chenthattil
dc.coverage.placenameЛьвів
dc.coverage.placenameLviv
dc.date.accessioned2024-01-09T10:19:03Z
dc.date.available2024-01-09T10:19:03Z
dc.date.created2021-03-16
dc.date.issued2021-03-16
dc.description.abstractЗа допомогою циклічної вольтаметрії проведено електрополімеризацію проліну на поверхні вугільно-пастового електроду та для індивідуального та одночасного визначення допаміну та сечової кислоти. Морфологію поверхні розробленого електрода вивчено методом емісійної скануючої електронної мікроскопії. Виявлено, що модифікований електрод виявив високу чутливість струму на допамін порівняно з оголеним електродом. Доведена висока каталітична активність розробленого модифікованого електроду з різним потенціалом окиснення допаміну та сечової кислоти. Встановлено, що перебіг електродного процесу контролюється адсорбцією. Показана достатньо непогана стабільність та відтворюваність розробленого методу. За оптимальних умов діапазон концентрацій становить від 1∙10-4 до 2∙10-4 М, а межа виявлення 4,7∙10-6 М. Проведені реальні випробовування розробленого електроду із задовільним результатом.
dc.description.abstractA cyclic voltammetric technique was used for electropolymerisation of proline on the surface of carbon paste electrode and for individual and concurrent determination of dopamine (DA) and uric acid (UA). The surface morphology of the developed electrode was studied by using field emission scanning electron microscopy. The modified electrode showed a high current response towards DA as compared to the bare electrode. The modified electrode shows good catalytic activity with a different oxidation potential of dopamine and UA. The electrode process was found to be adsorption controlled. The developed method shows very good stability and reproducibility. Under the optimized conditions, the concentration range is (1–2)∙10-4 M and the observed detection limit was 4.7∙10-6 M. The developed sensor was applied for the determination of DA in the real sample with a good recovery.
dc.format.extent153-160
dc.format.pages8
dc.identifier.citationEdwin S. D’ Souza Electrochemical Determination of Dopamine and Uric Acid Using Poly(proline) Modified Carbon Paste Electrode: A Cyclic Voltammetric Study / Edwin S. D’ Souza, Jamballi G. Manjunath, Chenthattil Raril // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2021. — Vol 15. — No 2. — P. 153–160.
dc.identifier.citationenEdwin S. D’ Souza Electrochemical Determination of Dopamine and Uric Acid Using Poly(proline) Modified Carbon Paste Electrode: A Cyclic Voltammetric Study / Edwin S. D’ Souza, Jamballi G. Manjunath, Chenthattil Raril // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2021. — Vol 15. — No 2. — P. 153–160.
dc.identifier.doidoi.org/10.23939/chcht15.02.153
dc.identifier.urihttps://ena.lpnu.ua/handle/ntb/60710
dc.language.isoen
dc.publisherВидавництво Львівської політехніки
dc.publisherLviv Politechnic Publishing House
dc.relation.ispartofChemistry & Chemical Technology, 2 (15), 2021
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dc.relation.urihttps://doi.org/10.1113/jphysiol.2005.100271
dc.relation.urihttps://doi.org/10.1021/ac00164a001
dc.relation.urihttps://doi.org/10.1289/ehp.5798
dc.relation.urihttps://doi.org/10.1289/ehp.93101378
dc.relation.urihttps://doi.org/10.1021/es9710870
dc.relation.urihttps://doi.org/10.1021/es9707973
dc.relation.urihttps://doi.org/10.1016/j.aquatox.2005.11.001
dc.relation.urihttps://doi.org/10.1016/S0925-4005(99)00210-5
dc.relation.urihttps://doi.org/10.1016/S0925-4005(99)00100-8
dc.relation.urihttps://doi.org/10.1007/s00216-006-0845-z
dc.relation.urihttps://doi.org/10.1007/s13206-012-6207-3
dc.relation.urihttps://doi.org/10.29333/ejac/20190101
dc.relation.urihttps://doi.org/10.1021/ac801854j
dc.relation.urihttps://doi.org/10.1007/s00604-009-0147-1
dc.relation.urihttps://doi.org/10.1007/s00604-007-0837-5
dc.relation.urihttps://doi.org/10.1016/S0022-0728(83)80338-6
dc.relation.urihttps://doi.org/10.1016/S0022-0728(80)80332-
dc.relation.urihttps://doi.org/10.1016/S0039-9140(01)00432-5
dc.relation.urihttps://doi.org/10.1002/elan.200303044
dc.relation.urihttps://doi.org/10.1016/S0003-2670(97)00016-0
dc.relation.urihttps://doi.org/10.1016/S1567-5394(02)00156-1
dc.relation.urihttps://doi.org/10.1016/S0927-796X(01)00035-3
dc.relation.urihttps://doi.org/10.1007/s00604-005-0376-x
dc.relation.urihttps://doi.org/10.1016/j.bios.2006.12.011
dc.relation.urihttps://doi.org/10.1016/j.bios.2006.10.023
dc.relation.urihttps://doi.org/10.1002/elan.201400635
dc.relation.urihttps://doi.org/10.1016/j.arabjc.2014.10.009
dc.relation.urihttps://doi.org/10.1016/j.sbsr.2017.11.006
dc.relation.urihttps://doi.org/10.5599/jese.386
dc.relation.urihttps://doi.org/10.26717/BJSTR.2018.09.001804
dc.relation.urihttps://doi.org/10.22159/ajpcr.2017.v10i12.21028
dc.relation.urihttps://doi.org/10.1016/j.jfda.2017.05.002
dc.relation.urihttps://doi.org/10.1016/j.crci.2013.09.016
dc.relation.urihttps://doi.org/10.1007/s10008-007-0410-5
dc.relation.urihttps://doi.org/10.2174/157341110791517025
dc.rights.holder© Національний університет “Львівська політехніка”, 2021
dc.rights.holder© D’Souza E., Manjunatha J., Raril C., 2021
dc.subjectдопамін
dc.subjectсечова кислота
dc.subjectпролін
dc.subjectелектрополімерізація
dc.subjectциклічна вольтамперометрія
dc.subjectdopamine
dc.subjecturic acid
dc.subjectproline
dc.subjectelectropoly merization
dc.subjectcyclic voltammetry
dc.titleElectrochemical Determination of Dopamine and Uric Acid Using Poly(proline) Modified Carbon Paste Electrode: A Cyclic Voltammetric Study
dc.title.alternativeЕлектрохімічне визначення допаміну та сечової кислоти з використанням вугільно-пастового електроду, модифікованого поліпроліном. циклічне волтаметричне дослідження
dc.typeArticle

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Chemistry & Chemical Technology. – 2021. – Vol. 15, No. 2