Photopolymerization of Poly(Hydroxyethyl Acrylate) (PHEA): Experimental Parameters-Viscoelastic Properties Relationship

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dc.citation.epage600
dc.citation.issue3
dc.citation.spage592
dc.contributor.affiliationCentre de Recherche (CRAPC)
dc.contributor.affiliationUniversite de Tlemcen (UABT)
dc.contributor.authorBouchikhi, Nouria
dc.contributor.authorLerari, Djahida
dc.contributor.authorHamri, Salah
dc.contributor.authorDergal, Faycal
dc.contributor.authorBachari, Khaldoun
dc.contributor.authorBedjaoui-Alachaher, Lamia
dc.coverage.placenameЛьвів
dc.coverage.placenameLviv
dc.date.accessioned2024-02-12T08:51:57Z
dc.date.available2024-02-12T08:51:57Z
dc.date.created2023-02-28
dc.date.issued2023-02-28
dc.description.abstractОцінено активність фотоініціювальної системи на основі триетаноламіну (ТЕОА) і метиленового синього (МС) у фотополімеризації мономеру гідроксіетил-акрилату (ГЕА) в умовах дуже м'якого опромінення. Виявлено помітну різницю в кінетиці полімеризації для серії експериментів ПГЕА залежно від концентрацій ТЕОА/МС, а також рН розчинів. Дійсно, комплексна в'язкість (η*), модуль зберігання (G') і модуль втрат (G") отриманих полімерів потенційно залежали від цих експериментальних параметрів, незважаючи на співрозмірні значення конверсії мономеру.
dc.description.abstractThe activity of the photoinitiator system, based on triethanolamine (TEOA) and methylene blue (MB), on the photopolymerization of hydroxyethyl acrylate (HEA) monomer under very soft irradiation conditions, was evaluated. A remarkable difference in the polymerization kinetics of a set of PHEA experiments was underlined according to TEOA/MB concentrations, as well as the solutions pH. Indeed, the complex viscosity (η*), storage modulus (G'), and loss modulus (G") of the resulting polymers were potentially dependent on these experimental parameters despite comparable values of monomer conversion.
dc.format.extent592-600
dc.format.pages9
dc.identifier.citationPhotopolymerization of Poly(Hydroxyethyl Acrylate) (PHEA): Experimental Parameters-Viscoelastic Properties Relationship / Nouria Bouchikhi, Djahida Lerari, Salah Hamri, Faycal Dergal, Khaldoun Bachari, Lamia Bedjaoui-Alachaher // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2023. — Vol 17. — No 3. — P. 592–600.
dc.identifier.citationenPhotopolymerization of Poly(Hydroxyethyl Acrylate) (PHEA): Experimental Parameters-Viscoelastic Properties Relationship / Nouria Bouchikhi, Djahida Lerari, Salah Hamri, Faycal Dergal, Khaldoun Bachari, Lamia Bedjaoui-Alachaher // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2023. — Vol 17. — No 3. — P. 592–600.
dc.identifier.doidoi.org/10.23939/chcht17.03.592
dc.identifier.issn1196-4196
dc.identifier.urihttps://ena.lpnu.ua/handle/ntb/61264
dc.language.isoen
dc.publisherВидавництво Львівської політехніки
dc.publisherLviv Politechnic Publishing House
dc.relation.ispartofChemistry & Chemical Technology, 3 (17), 2023
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dc.relation.referencesen[25] Encinas, M.V.; Rufs, A.M.; Neumann, M.G.; Previtali, C.M. Photoinitiated Vinyl Polymerization by Safranine T/triethanolamine in Aqueous Solution. Polymer 1996, 37, 1395-1398. https://doi.org/10.1016/0032-3861(96)81137-2
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dc.relation.referencesen[28] Cho, J.D.; Kim, H.K.; Kim, Y.S.; Hong, J.W. Dual Curing of Cationic UV-curable Clear and Pigmented Coating Systems Photo-sensitized by Thioxanthone and Anthracene. Polym. Test. 2003, 22, 633-645. https://doi.org/10.1016/S0142-9418(02)00169-1
dc.relation.referencesen[29] Sheng, C.K.; Bin Mat Yunus, W.M.; Yunus, W.M.Z.W.; Talib, Z.A.; Moksin, M.M. UV-Visible Photodegradation of Methylene Blue Doped in Poly (Vinyl Alcohol)(pva) Solid Matrix. Solid State Science and Technology 2003, 11, 124-130. http://psasir.upm.edu.my/id/eprint/42204
dc.relation.referencesen[30] Danziger, R.M.; Bar-Eli, K.H.; Weiss, K. The Laser Photoly-sis of Methylene Blue. J. Phys. Chem. 1967, 71, 2633-2640. https://doi.org/10.1021/j100867a037
dc.relation.referencesen[31] Tuite, E.M.; Kelly, J.M. New Trends in Photobiology: Photo-chemical Interactions of Methylene Blue and Analogues with DNA and Other Biological Substrates. J. Photochem. Photobiol. B, Biol. 1993, 21, 103-124. https://doi.org/10.1016/1011-1344(93)80173-7
dc.relation.referencesen[32] Bonneau, R.; Pottier, R.; Bagno, O.; Joussot-Dubien. J. pH Dependence of Singlet Oxygen Production in Aqueous Solutions Using Thiazine Dyes as Photosensitizers. Photochem. Photobiol. 1975, 21, 159-163. https://doi.org/10.1111/j.1751-1097.1975.tb06646.x
dc.relation.referencesen[33] Azmat, R.; Uddin, F. Photo Bleaching of Methylene Blue with Galactose and D-mannose by High Intensity Radiations. Canadian Journal of Pure and Applied Sciences 2008, 2, 275-283.
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dc.rights.holder© Національний університет “Львівська політехніка”, 2023
dc.rights.holder© Bouchikhi N., Lerari D., Hamri S., Dergal F., Bachari Kh., Bedjaoui-Alachaher L., 2023
dc.subjectфотополімеризація
dc.subjectбарвник
dc.subjectамін
dc.subjectpH
dc.subjectреологічні властивості
dc.subjectphotopolymerization
dc.subjectdye
dc.subjectamine
dc.subjectpH
dc.subjectrheological properties
dc.titlePhotopolymerization of Poly(Hydroxyethyl Acrylate) (PHEA): Experimental Parameters-Viscoelastic Properties Relationship
dc.title.alternativeФотополімеризація полігідроксіетилакрилату (ПГЕА): зв'язок експериментальних параметрів і в'язкопружних властивостей
dc.typeArticle

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Chemistry & Chemical Technology. – 2023. – Vol. 17, No. 3