Alkali Synthesis of Fatty Acid Butyl and Ethyl Esters and Comparative Bench Motor Testing of Blended Fuels on Their Basis

dc.citation.epage117
dc.citation.issue1
dc.citation.spage105
dc.contributor.affiliationV. P. Kukhar Institute of Bioorganic Chemistry and Petrochemistry of National Academy of Science of Ukraine
dc.contributor.affiliationA. M. Pydgorny Institute of Engineering Problems of National Academy of Science of Ukraine
dc.contributor.authorKonovalov, Serhiy
dc.contributor.authorPatrylak, Liubov
dc.contributor.authorZubenko, Stepan
dc.contributor.authorOkhrimenko, Mykhaylo
dc.contributor.authorYakovenko, Angela
dc.contributor.authorLevterov, Anton
dc.contributor.authorAvramenko, Andriy
dc.coverage.placenameЛьвів
dc.coverage.placenameLviv
dc.date.accessioned2024-01-09T09:32:56Z
dc.date.available2024-01-09T09:32:56Z
dc.date.created2021-03-16
dc.date.issued2021-03-16
dc.description.abstractПроведено лужну переестерифікацію соняшникової олії н-бутанолом та етанолом на алкоголятвмісних осушених розчинах гідроксиду калію. Виявлено складний характер самочинного розшарування продуктів синтезу бутилових естерів, який супроводжувався утворенням трьох відмінних різновидностей гліцеринового шару. Виявлено, що одним з них є високолужний чистий гліцерин. Стендові моторні випробування сумішей біодизеля з дизпаливом продемонстрували дещо кращі енергетичні показники бутилових естерів порівняно з етиловими естерами та закономірне зниження шкідливих викидів (CO2, CO, NOx , CH) із збільшенням частки біодизелю в суміші.
dc.description.abstractAlkaline transesterification of sunflower oil by n-butanol and ethanol on alkoxide-containing dried solutions of potassium hydroxide has been carried out. Complex character of spontaneous dividing of butanolysis products, accompanying with formation of three different species of glycerol layers, was observed. One of the later was found to be high-alkaline pure glycerol. Bench motor testing of biodiesel/diesel blends demonstrated slightly better power performance of butyl esters comparing with ethyl esters and regular decrease of harmful emissions (CO2, CO, NOx, CH) while increasing biodiesel fraction in mixture.
dc.format.extent105-117
dc.format.pages13
dc.identifier.citationAlkali Synthesis of Fatty Acid Butyl and Ethyl Esters and Comparative Bench Motor Testing of Blended Fuels on Their Basis / Serhiy Konovalov, Liubov Patrylak, Stepan Zubenko, Mykhaylo Okhrimenko, Angela Yakovenko, Anton Levterov, Andriy Avramenko // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2021. — Vol 15. — No 1. — P. 105–117.
dc.identifier.citationenAlkali Synthesis of Fatty Acid Butyl and Ethyl Esters and Comparative Bench Motor Testing of Blended Fuels on Their Basis / Serhiy Konovalov, Liubov Patrylak, Stepan Zubenko, Mykhaylo Okhrimenko, Angela Yakovenko, Anton Levterov, Andriy Avramenko // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2021. — Vol 15. — No 1. — P. 105–117.
dc.identifier.doidoi.org/10.23939/chcht15.01.105
dc.identifier.urihttps://ena.lpnu.ua/handle/ntb/60692
dc.language.isoen
dc.publisherВидавництво Львівської політехніки
dc.publisherLviv Politechnic Publishing House
dc.relation.ispartofChemistry & Chemical Technology, 1 (15), 2021
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dc.relation.urihttps://doi.org/10.1016/j.rser.2012.01.003
dc.relation.urihttps://www.bp.com/content/dam/bp/en/corporate/pdf/energyeconomics/statistical-review/bp-stats-review-2018-full-report.pdf
dc.relation.urihttps://doi.org/ef700720w
dc.relation.urihttps://doi.org/10.1016/j.jclepro.2016.07.007
dc.relation.urihttps://doi.org/10.1002/bbb.253
dc.relation.urihttps://doi.org/10.1016/j.rser.2012.01.071
dc.relation.urihttps://doi.org/10.1016/j.jcat.2014.09.016
dc.relation.urihttps://doi.org/10.1016/j.energy.2014.06.067
dc.relation.urihttps://doi.org/10.1016/j.fuproc.2016.02.031
dc.relation.urihttps://doi.org/10.1016/j.rser.2011.07.079
dc.relation.urihttps://doi.org/10.3103/S0095452713060042
dc.relation.urihttps://doi.org/10.1016/j.fuel.2011.06.049
dc.relation.urihttps://doi.org/10.1016/j.rser.2013.05.043
dc.relation.urihttps://doi.org/10.1016/j.pecs.2011.11.001
dc.relation.urihttps://doi.org/10.23939/chcht11.03.365
dc.relation.urihttps://doi.org/10.1007/s11746-000-0045-1
dc.relation.urihttps://doi.org/10.1007/bf02679606
dc.relation.urihttps://doi.org/10.1016/j.cej.2013.10.022
dc.relation.urihttps://doi.org/10.1016/S0960-8524(01)00051-7
dc.relation.urihttps://doi.org/10.1007/BF02541648
dc.relation.urihttps://doi.org/10.1016/j.apenergy.2005.05.003
dc.relation.urihttps://doi.org/10.1016/j.renene.2012.04.032
dc.relation.urihttps://doi.org/10.23939/chcht09.03.383
dc.relation.urihttps://doi.org/10.1016/j.fuel.2013.06.020
dc.relation.urihttps://doi.org/10.4271/2007-01-4040
dc.relation.urihttps://doi.org/10.1016/S0960-1481(03)00142-3
dc.relation.urihttps://doi.org/10.4271/961114
dc.relation.urihttps://doi.org/10.1016/j.fuel.2010.12.032
dc.relation.urihttps://doi.org/10.1016/j.seppur.2016.10.036
dc.relation.urihttps://doi.org/10.1016/j.jiec.2016.10.038
dc.relation.urihttps://doi.org/10.1016/j.fuel.2011.06.070
dc.relation.urihttps://doi.org/10.3390/en20200362
dc.relation.urihttps://doi.org/10.1016/j.fuel.2007.08.007
dc.relation.urihttp://online.budstandart.com/ua/catalog/doc-page?id_doc=64384
dc.relation.urihttp://shop.uas.org.ua/ua/katalog-normativnih-dokumentiv/75-nafta-y-sumizhni-tekhnolohiyi/75-160-palyvo/palivo-al-ternativneesteri-etilovi-zhirnih-kislot-olij-ta-zhiriv-dlja-dizel-nih-dvigunivtehnichni-vimogi-ta-metodi-kontroljuvannja.html
dc.rights.holder© Національний університет “Львівська політехніка”, 2021
dc.rights.holder© Konovalov S., Patrylak L., Zubenko S., Okhrimenko M., Yakovenko A., Levterov A., Avramenko A., 2021
dc.subjectбіодизель
dc.subjectлужна переестерифікація
dc.subjectетилові естери жирних кислот
dc.subjectбутилові естери жирних кислот
dc.subjectгліцерин
dc.subjectbiodiesel
dc.subjectalkaline transesterification
dc.subjectfatty acid ethyl esters
dc.subjectfatty acid butyl esters
dc.subjectglycerin
dc.subjectmotor testing
dc.titleAlkali Synthesis of Fatty Acid Butyl and Ethyl Esters and Comparative Bench Motor Testing of Blended Fuels on Their Basis
dc.title.alternativeЛужний синтез бутилових і етилових естерів жирних кислот і порівняльні стендові моторні випробування сумішевих палив на їх основі
dc.typeArticle

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