Use of Chemically Modified Chitosan for the Adsorptive Removal of Toxic Metal Ions in Aqueous Solutions

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dc.citation.epage419
dc.citation.issue2
dc.citation.spage407
dc.contributor.affiliationImam Abdulrahman Bin Faisal University
dc.contributor.affiliationUniversity of Punjab
dc.contributor.authorAlakhras, Fadi
dc.contributor.authorAlghamdi, Huda
dc.contributor.authorRehman, Rabia
dc.coverage.placenameЛьвів
dc.coverage.placenameLviv
dc.date.accessioned2024-02-12T08:30:37Z
dc.date.available2024-02-12T08:30:37Z
dc.date.created2023-03-16
dc.date.issued2023-03-16
dc.description.abstractРеакцією конденсації було успішно здійснено хімічну модифікацію хітозану з використанням трьох похідних, а саме: 3-гідроксибензальдегіду, 2,3-дигідроксибензальдегіду та 3,5-ди-трет-бутил-2-гідроксибензальдегіду. Методи інфрачервоної спектроскопії з перетворенням Фур’є (FTIR), сканувальної електронної мікроскопії (СЕМ), площі поверхні Брунауера–Еммета–Теллера (БЕТ), термогравіметричного аналізу (ТГА) та рентгенівської дифракції (XRD) були виконані для характеризації адсорбентів-основ Шиффа – похідних хітозану. Досліджено ефективність синтезованих адсорбентів щодо вилучення іонів кобальту і нікелю з водного розчину та проаналізовано експериментальні дані за допомогою ізотермічної та кінетичної моделей. Площа поверхні за БЕТ хімічно модифікованого хітозану була значно збільшена до 125,83 м2 × г-1 з мезопористими характеристиками. Максимальне поглинання зафіксовано за pH 5-6, а максимальна здатність вилучення становила 243,90 мг × г-1 для іонів кобальту та 166,67 мг × г-1 для іонів нікелю. Кінетичні дані краще описуються за допомогою псевдодругого порядку.
dc.description.abstractChemical modification of chitosan was successfully carried out using three derivatives namely: 3-hydroxybenzaldehyde, 2,3-dihydroxybenzaldehyde, and 3,5-di-tert-butyl-2-hydroxybenzaldehyde by a condensation reaction. Fourier transform infrared (FTIR) spectroscopy, scanning electron microscopy (SEM), Brunauer–Emmett–Teller (BET) surface area, thermal gravimetric analysis (TGA), and X-ray diffraction (XRD) methods were performed for characterization of the chitosanderived Schiff base adsorbent materials. The efficiency of the prepared adsorbents in removing cobalt and nickel ions from aqueous solution was explored, and experimental data were analyzed using isothermal and kinetic models. The BET surface area of chemically modified chitosan was greatly enhanced 125.83 m2 g-1 with mesoporous characteristics. The maximum uptake was recorded at pH 5-6, while the maximum removal capacity was 243.90 mg g-1 for cobalt ions whereas 166.67 mg g-1 was achieved for nickel ions. The kinetic data were better fitted using pseudo-second-order.
dc.format.extent407-419
dc.format.pages13
dc.identifier.citationAlakhras F. Use of Chemically Modified Chitosan for the Adsorptive Removal of Toxic Metal Ions in Aqueous Solutions / Fadi Alakhras, Huda Alghamdi, Rabia Rehman // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2023. — Vol 17. — No 2. — P. 407–419.
dc.identifier.citationenAlakhras F. Use of Chemically Modified Chitosan for the Adsorptive Removal of Toxic Metal Ions in Aqueous Solutions / Fadi Alakhras, Huda Alghamdi, Rabia Rehman // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2023. — Vol 17. — No 2. — P. 407–419.
dc.identifier.doidoi.org/10.23939/chcht17.02.407
dc.identifier.issn1996-4196
dc.identifier.urihttps://ena.lpnu.ua/handle/ntb/61245
dc.language.isoen
dc.publisherВидавництво Львівської політехніки
dc.publisherLviv Politechnic Publishing House
dc.relation.ispartofChemistry & Chemical Technology, 2 (17), 2023
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dc.rights.holder© Національний університет “Львівська політехніка”, 2023
dc.rights.holder© Alakhras F., Alghamdi H., Rehman R., 2023
dc.subjectтоксичні іони
dc.subjectхітозан
dc.subjectочищення стічних вод
dc.subjectадсорбція
dc.subjectадсорбент-основа Шиффа
dc.subjecttoxic ions
dc.subjectchitosan
dc.subjectwastewater treatment
dc.subjectadsorption
dc.subjectSchiff-based adsorbent
dc.titleUse of Chemically Modified Chitosan for the Adsorptive Removal of Toxic Metal Ions in Aqueous Solutions
dc.title.alternativeВикористання хімічно модифікованого хітозану для адсорбційного вилучення іонів токсичних металів у водних розчинах
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Chemistry & Chemical Technology. – 2023. – Vol. 17, No. 2