Synthesis of Epoxyperoxides and Peroxide Derivatives of a-D-Galactopyranose Based Thereon

Simple item page
dc.citation.epage447
dc.citation.issue4
dc.citation.spage439
dc.contributor.affiliationLviv Polytechnic National University
dc.contributor.authorFleychuk, Roman
dc.contributor.authorVuytsyk, Lidiya
dc.contributor.authorKohut, Ananiy
dc.contributor.authorHevus, Orest
dc.coverage.placenameЛьвів
dc.coverage.placenameLviv
dc.date.accessioned2023-12-13T10:02:45Z
dc.date.available2023-12-13T10:02:45Z
dc.date.created2010-03-16
dc.date.issued2010-03-16
dc.description.abstractРеакцією епіхлоргідрину з дитретинними ωгідроксиалкілпероксидами синтезовано нові епоксидовмісні пероксиди. З’ясовано вплив умов проведення реакцій на вихід та склад продуктів взаємодії. Реакціями отриманих пероксидовмісних гліцидилових етерів з 1,2;3,4-діізопропіліден-α-D-галактопіранозою або 6-гліцидил-1,2;3,4-діізопропіліден-α-D-галактопіранози з ω-гідроксиалкілпероксидами синтезовано нові пероксидні похідні з дитретинними та первинно-третинними пероксидними групами. Методом комплексного термічного аналізу досліджено розклад синтезованих сполук та визначено кінетичні параметри термолізу.
dc.description.abstractNew epoxide-containing peroxides have been synthesized via the interaction between epichlorohydrin and ditertiary w-hydroxyalkyl peroxides. The effect of reaction conditions on both the yield and composition of the reaction products has been established. Through the reactions of either the synthesized epoxide-containing peroxides with 1,2;3,4-di-O-isopropylidene-a-D-galactopyranose or 6-O-glycidyl-1,2;3,4-di-O-isopropylidene-a-D-galactopyranose with the w-hydroxyalkyl peroxides, new peroxide derivatives with ditertiary and primarytertiary peroxide groups have been synthesized successfully. The decomposition of the developed substances has been studied by complex thermal analysis and the kinetic parameters of the thermolysis have been determined.
dc.format.extent439-447
dc.format.pages9
dc.identifier.citationSynthesis of Epoxyperoxides and Peroxide Derivatives of a-D-Galactopyranose Based Thereon / Roman Fleychuk, Lidiya Vuytsyk, Ananiy Kohut, Orest Hevus // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2020. — Vol 14. — No 4. — P. 439–447.
dc.identifier.citationenSynthesis of Epoxyperoxides and Peroxide Derivatives of a-D-Galactopyranose Based Thereon / Roman Fleychuk, Lidiya Vuytsyk, Ananiy Kohut, Orest Hevus // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2020. — Vol 14. — No 4. — P. 439–447.
dc.identifier.doidoi.org/10.23939/chcht14.04.439
dc.identifier.urihttps://ena.lpnu.ua/handle/ntb/60559
dc.language.isoen
dc.publisherВидавництво Львівської політехніки
dc.publisherLviv Politechnic Publishing House
dc.relation.ispartofChemistry & Chemical Technology, 4 (14), 2020
dc.relation.references[1] Samaryk V., Varvarenko S., Tarnavchyk I. et al.: Macromol. Symp., 2008, 267, 113. https://doi.org/10.1002/masy.200850721
dc.relation.references[2] Samaryk V., Voronov A., Tarnavchyk I. et al.: Prog. Org. Coat., 2012, 74, 687. https://doi.org/10.1016/j.porgcoat.2011.07.015
dc.relation.references[3] Revilla J., Elaissari A., Carriere P. et al.: J Colloid Interf. Sci., 1996, 180, 405. https://doi.org/10.1006/jcis.1996.0319
dc.relation.references[4] Tirrelli M., Kokkoli E., Biesalski M.: Surf. Sci., 2002, 500, 61. https://doi.org/10.1016/S0039-6028(01)01548-5
dc.relation.references[5] Basinska T.: Macromol. Biosci., 2005, 5, 1145. https://doi.org/10.1002/mabi.200500138
dc.relation.references[6] Voronov S., Donchak V., Harhai H. et al.: Polym. Int., 2001, 50, 688. https://doi.org/10.1002/pi.683
dc.relation.references[7] Solomko N., Dron I., Budishevskaya O., Voronov S.: Procedia Chem., 2009, 1, 1567. https://doi.org/10.1016/j.proche.2009.11.005
dc.relation.references[8] Chobit M.: Chem. Technol. Appl. Substance, 2019, 1, 139. https://doi.org/10.23939/ctas2018.01
dc.relation.references[9] Nudelman Z.: Khimiia Organicheskikh Peroksidov. Izd-vo Volhohradskogo Politech. Inst., Volhohrad 1982.
dc.relation.references[10] Bratychak M., Ivashkiv O., Astakhova O.: Dopovidi Nats. Akad. Nauk Ukrainy, 2015, 5, 119.
dc.relation.references[11] Ivashkiv O., Namiesnik J., Astakhova O. et al.: Chem. Chem. Technol., 2015, 9, 313. https://doi.org/10.23939/chcht09.03.313
dc.relation.references[12] Puchyn V., Schevchuk V., Jelahin H. et al.: UdSSR, A. s. 481631, Publ. Aug. 25, 1975.
dc.relation.references[13] Hetmanchuk Yu., Hrebeniuk I., Sembai E. et al.: UdSSR, A.s. 443890, Publ. Sep. 25, 1974.
dc.relation.references[14] Onyshchenko Z., Krasnobrytaia R., Blokh H. et al.: UdSSR, A.s. 414273 Publ. Nov. 05, 1974.
dc.relation.references[15] Bazyliak L., Bratychak M., Brostow W. et al. Int. Conf. on Polymer Characterization (POLYCHAR-6). USA, Denton 1998, 09.
dc.relation.references[16] Sembai E., Yelahin H., Yurzhenko T. et al.: UdSSR, A. s. 382649 Publ. May 23, 1973.
dc.relation.references[17] Antonovskii V. et al: Sintez Perekisei Cyklicheskikh Ketonov i Ocenka ikh Iniciiruiushchikh Sposobnostei [in:] Emanuelia N. et al. (Eds.) Uspekhi Khimii. Khimia, Moskva 1969, 100-106.
dc.relation.references[18] Bobrova K., Fleychuk R., Hevus O.: Visnyk Lviv Polytechnic National University, 2018, 886, 52.
dc.relation.references[19] Fleichuk R., Gevus' O., Voronov S.: Russ. J. Org. Chem., 2003, 39, 1799. https://doi.org/10.1023/B:RUJO.0000019748.73690.d2
dc.relation.references[20] Fleychuk R.: PhD thesis, Lviv Plytechnic National University, Lviv 2004.
dc.relation.references[21] Nikolskii B.: Spravochnik Khimika, Т. 2. Khimia, MoskvaLeningrad 1964.
dc.relation.references[22] Belcher R.: Submicro Methods of Organic Analysis. Elsevier, Amsterdam 1966.
dc.relation.references[23] Isaacs N.: Experiments in Physical Organic Chemistry. Macmillan, London 1969.
dc.relation.references[24] Uendland U.: Termicheskiie Metody Analiza. Mir, Moskva 1978.
dc.relation.references[25] Berg L.: Vvedeniie v Termohrafiiu. Nauka, Moskva 1969.
dc.relation.references[26] Siggia S., Hanna J.: Quantitative Organic Analysis via Functional Groups. Wiley, New York 1979.
dc.relation.references[27] Gagin M., Bratychak M., Brostow W. et al.: Mater. Res. Innovat., 2003, 7, 291. https://doi.org/10.1007/s10019-003-0266-y
dc.relation.references[28] Weygand-Hilgetag: Organisch-Chemische Experimentierkunst. Johann Ambrosius Barth Verlag, Leipzig 1964.
dc.relation.references[29] Fleychuk R., Kohut A., Hevus O. et al.: Macromol. Symp., 2004, 210, 85. https://doi.org/10.1002/masy.200450610
dc.relation.references[30] Vostres V., Fleichuk R., Voronov S. et al.: Russ. J. Org. Chem. 2013, 49, 1270. https://doi.org/10.1134/S1070428013090042
dc.relation.references[31] Kropf H., Ball M., Schroder H. et al.: Tetrahedron, 1974, 30, 2943. https://doi.org/10.1016/S0040-4020(01)97470-8
dc.relation.references[32] Semenishin D., Kochubei V., Borova O. et al.: Russ. J. Coord. Chem., 2003, 29, 196. https://doi.org/10.1023/A:1022883731123
dc.relation.referencesen[1] Samaryk V., Varvarenko S., Tarnavchyk I. et al., Macromol. Symp., 2008, 267, 113. https://doi.org/10.1002/masy.200850721
dc.relation.referencesen[2] Samaryk V., Voronov A., Tarnavchyk I. et al., Prog. Org. Coat., 2012, 74, 687. https://doi.org/10.1016/j.porgcoat.2011.07.015
dc.relation.referencesen[3] Revilla J., Elaissari A., Carriere P. et al., J Colloid Interf. Sci., 1996, 180, 405. https://doi.org/10.1006/jcis.1996.0319
dc.relation.referencesen[4] Tirrelli M., Kokkoli E., Biesalski M., Surf. Sci., 2002, 500, 61. https://doi.org/10.1016/S0039-6028(01)01548-5
dc.relation.referencesen[5] Basinska T., Macromol. Biosci., 2005, 5, 1145. https://doi.org/10.1002/mabi.200500138
dc.relation.referencesen[6] Voronov S., Donchak V., Harhai H. et al., Polym. Int., 2001, 50, 688. https://doi.org/10.1002/pi.683
dc.relation.referencesen[7] Solomko N., Dron I., Budishevskaya O., Voronov S., Procedia Chem., 2009, 1, 1567. https://doi.org/10.1016/j.proche.2009.11.005
dc.relation.referencesen[8] Chobit M., Chem. Technol. Appl. Substance, 2019, 1, 139. https://doi.org/10.23939/ctas2018.01
dc.relation.referencesen[9] Nudelman Z., Khimiia Organicheskikh Peroksidov. Izd-vo Volhohradskogo Politech. Inst., Volhohrad 1982.
dc.relation.referencesen[10] Bratychak M., Ivashkiv O., Astakhova O., Dopovidi Nats. Akad. Nauk Ukrainy, 2015, 5, 119.
dc.relation.referencesen[11] Ivashkiv O., Namiesnik J., Astakhova O. et al., Chem. Chem. Technol., 2015, 9, 313. https://doi.org/10.23939/chcht09.03.313
dc.relation.referencesen[12] Puchyn V., Schevchuk V., Jelahin H. et al., UdSSR, A. s. 481631, Publ. Aug. 25, 1975.
dc.relation.referencesen[13] Hetmanchuk Yu., Hrebeniuk I., Sembai E. et al., UdSSR, A.s. 443890, Publ. Sep. 25, 1974.
dc.relation.referencesen[14] Onyshchenko Z., Krasnobrytaia R., Blokh H. et al., UdSSR, A.s. 414273 Publ. Nov. 05, 1974.
dc.relation.referencesen[15] Bazyliak L., Bratychak M., Brostow W. et al. Int. Conf. on Polymer Characterization (POLYCHAR-6). USA, Denton 1998, 09.
dc.relation.referencesen[16] Sembai E., Yelahin H., Yurzhenko T. et al., UdSSR, A. s. 382649 Publ. May 23, 1973.
dc.relation.referencesen[17] Antonovskii V. et al: Sintez Perekisei Cyklicheskikh Ketonov i Ocenka ikh Iniciiruiushchikh Sposobnostei [in:] Emanuelia N. et al. (Eds.) Uspekhi Khimii. Khimia, Moskva 1969, 100-106.
dc.relation.referencesen[18] Bobrova K., Fleychuk R., Hevus O., Visnyk Lviv Polytechnic National University, 2018, 886, 52.
dc.relation.referencesen[19] Fleichuk R., Gevus' O., Voronov S., Russ. J. Org. Chem., 2003, 39, 1799. https://doi.org/10.1023/B:RUJO.0000019748.73690.d2
dc.relation.referencesen[20] Fleychuk R., PhD thesis, Lviv Plytechnic National University, Lviv 2004.
dc.relation.referencesen[21] Nikolskii B., Spravochnik Khimika, V. 2. Khimia, MoskvaLeningrad 1964.
dc.relation.referencesen[22] Belcher R., Submicro Methods of Organic Analysis. Elsevier, Amsterdam 1966.
dc.relation.referencesen[23] Isaacs N., Experiments in Physical Organic Chemistry. Macmillan, London 1969.
dc.relation.referencesen[24] Uendland U., Termicheskiie Metody Analiza. Mir, Moskva 1978.
dc.relation.referencesen[25] Berg L., Vvedeniie v Termohrafiiu. Nauka, Moskva 1969.
dc.relation.referencesen[26] Siggia S., Hanna J., Quantitative Organic Analysis via Functional Groups. Wiley, New York 1979.
dc.relation.referencesen[27] Gagin M., Bratychak M., Brostow W. et al., Mater. Res. Innovat., 2003, 7, 291. https://doi.org/10.1007/s10019-003-0266-y
dc.relation.referencesen[28] Weygand-Hilgetag: Organisch-Chemische Experimentierkunst. Johann Ambrosius Barth Verlag, Leipzig 1964.
dc.relation.referencesen[29] Fleychuk R., Kohut A., Hevus O. et al., Macromol. Symp., 2004, 210, 85. https://doi.org/10.1002/masy.200450610
dc.relation.referencesen[30] Vostres V., Fleichuk R., Voronov S. et al., Russ. J. Org. Chem. 2013, 49, 1270. https://doi.org/10.1134/S1070428013090042
dc.relation.referencesen[31] Kropf H., Ball M., Schroder H. et al., Tetrahedron, 1974, 30, 2943. https://doi.org/10.1016/S0040-4020(01)97470-8
dc.relation.referencesen[32] Semenishin D., Kochubei V., Borova O. et al., Russ. J. Coord. Chem., 2003, 29, 196. https://doi.org/10.1023/A:1022883731123
dc.relation.urihttps://doi.org/10.1002/masy.200850721
dc.relation.urihttps://doi.org/10.1016/j.porgcoat.2011.07.015
dc.relation.urihttps://doi.org/10.1006/jcis.1996.0319
dc.relation.urihttps://doi.org/10.1016/S0039-6028(01)01548-5
dc.relation.urihttps://doi.org/10.1002/mabi.200500138
dc.relation.urihttps://doi.org/10.1002/pi.683
dc.relation.urihttps://doi.org/10.1016/j.proche.2009.11.005
dc.relation.urihttps://doi.org/10.23939/ctas2018.01
dc.relation.urihttps://doi.org/10.23939/chcht09.03.313
dc.relation.urihttps://doi.org/10.1023/B:RUJO.0000019748.73690.d2
dc.relation.urihttps://doi.org/10.1007/s10019-003-0266-y
dc.relation.urihttps://doi.org/10.1002/masy.200450610
dc.relation.urihttps://doi.org/10.1134/S1070428013090042
dc.relation.urihttps://doi.org/10.1016/S0040-4020(01)97470-8
dc.relation.urihttps://doi.org/10.1023/A:1022883731123
dc.rights.holder© Національний університет “Львівська політехніка”, 2020
dc.rights.holder© Fleychuk R., VuytsykL., Kohut A., Hevus O., 2020
dc.subjectгідроксилвмісні пероксиди
dc.subjectепоксиалкілпероксиди
dc.subjectсахариди з пероксидними групами
dc.subjectтермогравіметричний аналіз
dc.subjecthydroxy-containing peroxides
dc.subjectepoxyalkyl peroxides
dc.subjectsaccharides with peroxide groups
dc.subjectthermogravimetric analysis
dc.titleSynthesis of Epoxyperoxides and Peroxide Derivatives of a-D-Galactopyranose Based Thereon
dc.title.alternativeСинтез нових епоксипероксидів та пероксидовмісних похідних α-D-галактопіранози на їх основі
dc.typeArticle

Files

Original bundle

Now showing 1 - 2 of 2
Thumbnail Image
Name:
2020v14n4_Fleychuk_R-Synthesis_of_Epoxyperoxides_439-447.pdf
Size:
784.79 KB
Format:
Adobe Portable Document Format
Download
Thumbnail Image
Name:
2020v14n4_Fleychuk_R-Synthesis_of_Epoxyperoxides_439-447__COVER.png
Size:
566.7 KB
Format:
Portable Network Graphics
Download

License bundle

Now showing 1 - 1 of 1
No Thumbnail Available
Name:
license.txt
Size:
1.79 KB
Format:
Plain Text
Description:
Download

Collections

Chemistry & Chemical Technology. – 2020. – Vol. 14, No. 4