Одержання і характеристика катіонних крохмалів

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dc.citation.epage165
dc.citation.issue1
dc.citation.spage159
dc.contributor.affiliationНаціональний університет “Львівська політехніка”
dc.contributor.affiliationLviv Polytechnic National University
dc.contributor.authorКостик, О. А.
dc.contributor.authorБудішевська, О. Г.
dc.contributor.authorВострес, В. Б.
dc.contributor.authorНадашкевич, З. Я.
dc.contributor.authorВоронов, С. А.
dc.contributor.authorKostyk, O. A.
dc.contributor.authorBudishevska, O. H.
dc.contributor.authorVostres, V. B.
dc.contributor.authorNadashkevych, Z. Y.
dc.contributor.authorVoronov, S. A.
dc.coverage.placenameLviv
dc.coverage.placenameLviv
dc.date.accessioned2020-02-28T13:09:33Z
dc.date.available2020-02-28T13:09:33Z
dc.date.created2019-02-28
dc.date.issued2019-02-28
dc.description.abstractДосліджено процес одержання катіонізованих крохмалів із ступенем заміщення DS 0,02– 0,45 взаємодією амінуючого реагенту 3-хлоро-2-гідроксипропілтриетиламоній хлориду (АР) з кукурудзяним крохмалем напівсухим методом у присутності натрій гідроксиду. АР одержано в одному реакторі взаємодією триетиламіну з HCl з подальшою взаємодією з епіхлоргідрином у присутності каталізатора триметилцетиламоній броміду. Показано, що катіонізований крохмаль з найвищим ступенем заміщення утворюється за мольного співвідношення NaOH: АР = 1,2–2,0. Найбільша ефективність реакції катіонування крохмалю у досліджуваному інтервалі спостерігалась за співвідношення АР: крохмаль=1,0.
dc.description.abstractThe process of obtaining cationized starches with the degree of substitution equal to DS 0.02–0.45 by interaction of the 3-chloro-2-hydroxypropyltrietilammonium chloride (AR) amine reagent with corn starch by a semi-dry method in the presence of sodium hydroxide was investigated. AR was obtained by the one-pot interaction of triethylamine with HCl followed by reaction with epichlorohydrin in the presence of cetyltrimethylammonium bromide as a catalyst. It was shown that cationized starch with the highest degree of substitution was formed at a molar ratio NaOH: AP = 1.2–2.0. The greatest efficiency of the cationization of starch in the investigated interval was observed at the ratio of AP: starch = 1.0.
dc.format.extent159-165
dc.format.pages7
dc.identifier.citationОдержання і характеристика катіонних крохмалів / О. А. Костик, О. Г. Будішевська, В. Б. Вострес, З. Я. Надашкевич, С. А. Воронов // Chemistry, Technology and Application of Substances. — Lviv : Lviv Politechnic Publishing House, 2019. — Том 2. — № 1. — С. 159–165.
dc.identifier.citationenPreparation and characteristics of cationic starches / O. A. Kostyk, O. H. Budishevska, V. B. Vostres, Z. Y. Nadashkevych, S. A. Voronov // Chemistry, Technology and Application of Substances. — Lviv : Lviv Politechnic Publishing House, 2019. — Vol 2. — No 1. — P. 159–165.
dc.identifier.urihttps://ena.lpnu.ua/handle/ntb/46374
dc.language.isouk
dc.publisherLviv Politechnic Publishing House
dc.relation.ispartofChemistry, Technology and Application of Substances, 1 (2), 2019
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dc.subjectкатіонний крохмаль
dc.subjectступінь заміщення
dc.subjectтриетиламін
dc.subjectcationic starch
dc.subjectdegree of substitution
dc.subjecttriethylamine
dc.titleОдержання і характеристика катіонних крохмалів
dc.title.alternativePreparation and characteristics of cationic starches
dc.typeArticle

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Chemistry, Technology and Application of Substances. – 2019. – Vol. 2, No. 1