Одержання і характеристика катіонних крохмалів
| dc.citation.epage | 165 | |
| dc.citation.issue | 1 | |
| dc.citation.spage | 159 | |
| dc.contributor.affiliation | Національний університет “Львівська політехніка” | |
| dc.contributor.affiliation | Lviv Polytechnic National University | |
| dc.contributor.author | Костик, О. А. | |
| dc.contributor.author | Будішевська, О. Г. | |
| dc.contributor.author | Вострес, В. Б. | |
| dc.contributor.author | Надашкевич, З. Я. | |
| dc.contributor.author | Воронов, С. А. | |
| dc.contributor.author | Kostyk, O. A. | |
| dc.contributor.author | Budishevska, O. H. | |
| dc.contributor.author | Vostres, V. B. | |
| dc.contributor.author | Nadashkevych, Z. Y. | |
| dc.contributor.author | Voronov, S. A. | |
| dc.coverage.placename | Lviv | |
| dc.coverage.placename | Lviv | |
| dc.date.accessioned | 2020-02-28T13:09:33Z | |
| dc.date.available | 2020-02-28T13:09:33Z | |
| dc.date.created | 2019-02-28 | |
| dc.date.issued | 2019-02-28 | |
| dc.description.abstract | Досліджено процес одержання катіонізованих крохмалів із ступенем заміщення DS 0,02– 0,45 взаємодією амінуючого реагенту 3-хлоро-2-гідроксипропілтриетиламоній хлориду (АР) з кукурудзяним крохмалем напівсухим методом у присутності натрій гідроксиду. АР одержано в одному реакторі взаємодією триетиламіну з HCl з подальшою взаємодією з епіхлоргідрином у присутності каталізатора триметилцетиламоній броміду. Показано, що катіонізований крохмаль з найвищим ступенем заміщення утворюється за мольного співвідношення NaOH: АР = 1,2–2,0. Найбільша ефективність реакції катіонування крохмалю у досліджуваному інтервалі спостерігалась за співвідношення АР: крохмаль=1,0. | |
| dc.description.abstract | The process of obtaining cationized starches with the degree of substitution equal to DS 0.02–0.45 by interaction of the 3-chloro-2-hydroxypropyltrietilammonium chloride (AR) amine reagent with corn starch by a semi-dry method in the presence of sodium hydroxide was investigated. AR was obtained by the one-pot interaction of triethylamine with HCl followed by reaction with epichlorohydrin in the presence of cetyltrimethylammonium bromide as a catalyst. It was shown that cationized starch with the highest degree of substitution was formed at a molar ratio NaOH: AP = 1.2–2.0. The greatest efficiency of the cationization of starch in the investigated interval was observed at the ratio of AP: starch = 1.0. | |
| dc.format.extent | 159-165 | |
| dc.format.pages | 7 | |
| dc.identifier.citation | Одержання і характеристика катіонних крохмалів / О. А. Костик, О. Г. Будішевська, В. Б. Вострес, З. Я. Надашкевич, С. А. Воронов // Chemistry, Technology and Application of Substances. — Lviv : Lviv Politechnic Publishing House, 2019. — Том 2. — № 1. — С. 159–165. | |
| dc.identifier.citationen | Preparation and characteristics of cationic starches / O. A. Kostyk, O. H. Budishevska, V. B. Vostres, Z. Y. Nadashkevych, S. A. Voronov // Chemistry, Technology and Application of Substances. — Lviv : Lviv Politechnic Publishing House, 2019. — Vol 2. — No 1. — P. 159–165. | |
| dc.identifier.uri | https://ena.lpnu.ua/handle/ntb/46374 | |
| dc.language.iso | uk | |
| dc.publisher | Lviv Politechnic Publishing House | |
| dc.relation.ispartof | Chemistry, Technology and Application of Substances, 1 (2), 2019 | |
| dc.relation.references | 1. Vida Zargar, Morteza Asghari, & Amir Dashti. (2015). A Review on Chitin and Chitosan Polymers: Structure, Chemistry, Solubility, Derivatives, and Applications ChemBioEng Rev 2, 1–24. | |
| dc.relation.references | 2. Кряжев, В. Н., Романов, В. В.,& Широ- ков, В. А. (2010). Последние дослижения химии и технологии производных крахмала. Химия растительного сырья, (1), 5–12. | |
| dc.relation.references | 3. Prado, H. J., & Matulewicz, M. S. (2014). Cationization of polysaccharides: A pass to greener darivatives with many industrial applications. Europian Polymer Journal (52), 53–75. | |
| dc.relation.references | 4. Baek, K., Yang, J. S., Kwon, T. S., Yang, J. W., & Yang, Ji-Won (2007). Cationic starch-enhanced ultrafiltration for Cr (VI) removal. CBE-Journal Papers, 206, 245–250. | |
| dc.relation.references | 5. Ching Ting Tsao, Chih Hao Chang, Yu Yung Lin, Ming Fung Wu, Jaw-Lin Wang, Jin Lin Han, & Kuo Huang Hsieh (2010). Antibacterial activity and biocompatibility of a chitosan–c-poly (glutamic acid) polyelectrolyte complex hydrogel. Carbohydrate Research, 345, 1774–1780. | |
| dc.relation.references | 6. Бутрим, С. М., Бутрим, Н. С., Бильдю- кевич, Т. Д., & Юркштович, Т. Л. (2010). Способ получения катионного крахмала. Пат. BY 12847, МПК С 08В 31/100. 28.02.2010. | |
| dc.relation.references | 7. Sableviciene, D., Klimaviciute, R., Bendoraitiene, J., & Zemaitaitis, A. (2005). Flocculation properties of hight substituted cationic starches. Colloids and surfaces A: Physicochem. Tng. Aspects, 259, 23–30. | |
| dc.relation.references | 8. Popadyuk, N., Zholobko, O., Donchak, V., Harhay, H., Budishevska, O., Voronov, A., Kohut, A., & Voronov, S. (2014). Ionically and Covalently Crosslinked Hydrogel Particles Based on Chitosan and Poly (ethylene glycol). Chemistry and Chemical Thechnology, 8(2), 171–176. | |
| dc.relation.references | 9. Pi-xinWang, Xiu-liWu, Xue Dong-hua, Xu Kun, Tan Ying, Du Xi-bing, & Li Wen-bo. (2009). ЕР, % Preparation and characterization of cationic corn starch with a high degree of substitution in dioxane-THFwater media. Carbohydrate Research, 344, 851–855. | |
| dc.relation.references | 10. Литвяк, В. В., & Канарский, А. В. (2016). Особенности катионизации α-D-глюкопиранозы крахмала в положении3С атома (N-3-хлоро-2- гидроксипропил)-N, N, N-триметиламмоний хло- ридом. Пластические массы, 7–8, 27–31. | |
| dc.relation.references | 11. Khalil, M. I., Farag and, S., & Hushem, A. (1993) Preparation fnd Characterization of Some Cationic Starches. Journal Starch/stärke, 45 (6), 226–231. | |
| dc.relation.references | 12. Черонис, Н., & Ма, Т. С. (1973) Микро- и полумикро методы органического функционального анализа. М.: Химия, 576. | |
| dc.relation.references | 13. Pat. CN1187484A, China. Inventor Yang Jinzong Zhang Yonghua Yan Xiujun Wan Yongxiang Ding Wenguang (1997). Process for synthesizing 3- chloro-2-hydroxypropyl-trimethyl ammonium chloride. | |
| dc.relation.references | 14. Khalil, M. I. & Farag Dokki, A. (1998). Preparation of Some Cationic Starches using the Dry Process. Journal Starch/stärke, 50(6), 267-271. | |
| dc.relation.references | 15. Казицына, Л. А., & Куплетская, Н. Б. (1971). Применение УФ-, ИК- и ЯМР- спектроскопии в органической химии. – М: Высшая школа, 264. | |
| dc.relation.references | 16. Kizil, J. & Seetharaman, K. (2002). Characterization of Irradiated Starches by Using FTRaman and FTIR Spectroscopy. Journal of Agriculture and food chemistry, 50, 3912–3918. | |
| dc.relation.references | 17. Pereira, A. G., Paulino, A. T., Rubira, A. F., & Muniz, E. C. (2010). Polymer-polymer miscibility in PEO/cationic starch and PEO/hydrophobic starch bland. eXPRESS Polymer Letters, 4(8), 488–499. | |
| dc.relation.references | 18. Fanga, J. M., Fowlera, P. A., Sayersb, C. & Williams P. A. (2004). The chemical modification of a range of starches under aqueous reaction conditions. Carbohydrate Polymers, 55, 283–289. | |
| dc.relation.references | 19. Chun Bei Huang, Robert Jeng, Mohini Sain, Bradley A. Saville & Martin Hubbes. (2006). Production, characterization, and mechanical propertiesof starch modified by Ophiostoma spp. Bioresources, 1(2), 257–269. | |
| dc.relation.references | 20. Ловкис, З. В., Литвяк, В. В., & Петю- шев Н. Н. (2007). Технология крахмала и крахмало- продуктов: учеб. пособ., РУП “Научно-практичес- кий центр Национальной академии наук Беларуси по продовольствию. – Минск: Асобны, 178. | |
| dc.relation.references | 21. Quanxiao Liu, Jinli Li, & Wencai Xu. (2010). Application of Cationic Starch with High Degree of Substitution in Packaging Paper from High Yield Pulp. Scientific Research. Proceedings of the 17th IAPRI World Conference on Packaging, 35–38. | |
| dc.relation.referencesen | 1. Vida Zargar, Morteza Asghari, & Amir Dashti. (2015). A Review on Chitin and Chitosan Polymers: Structure, Chemistry, Solubility, Derivatives, and Applications ChemBioEng Rev 2, 1–24. | |
| dc.relation.referencesen | 2. Kriazhev, V. N., Romanov, V. V.,& Shiro- kov, V. A. (2010). Poslednie doslizheniia khimii i tekhnolohii proizvodnykh krakhmala. Khimiia rastitelnoho syria, (1), 5–12. | |
| dc.relation.referencesen | 3. Prado, H. J., & Matulewicz, M. S. (2014). Cationization of polysaccharides: A pass to greener darivatives with many industrial applications. Europian Polymer Journal (52), 53–75. | |
| dc.relation.referencesen | 4. Baek, K., Yang, J. S., Kwon, T. S., Yang, J. W., & Yang, Ji-Won (2007). Cationic starch-enhanced ultrafiltration for Cr (VI) removal. CBE-Journal Papers, 206, 245–250. | |
| dc.relation.referencesen | 5. Ching Ting Tsao, Chih Hao Chang, Yu Yung Lin, Ming Fung Wu, Jaw-Lin Wang, Jin Lin Han, & Kuo Huang Hsieh (2010). Antibacterial activity and biocompatibility of a chitosan–c-poly (glutamic acid) polyelectrolyte complex hydrogel. Carbohydrate Research, 345, 1774–1780. | |
| dc.relation.referencesen | 6. Butrim, S. M., Butrim, N. S., Bildiu- kevich, T. D., & Iurkshtovich, T. L. (2010). Sposob polucheniia kationnoho krakhmala. Pat. BY 12847, MPK P. 08V 31/100. 28.02.2010. | |
| dc.relation.referencesen | 7. Sableviciene, D., Klimaviciute, R., Bendoraitiene, J., & Zemaitaitis, A. (2005). Flocculation properties of hight substituted cationic starches. Colloids and surfaces A: Physicochem. Tng. Aspects, 259, 23–30. | |
| dc.relation.referencesen | 8. Popadyuk, N., Zholobko, O., Donchak, V., Harhay, H., Budishevska, O., Voronov, A., Kohut, A., & Voronov, S. (2014). Ionically and Covalently Crosslinked Hydrogel Particles Based on Chitosan and Poly (ethylene glycol). Chemistry and Chemical Thechnology, 8(2), 171–176. | |
| dc.relation.referencesen | 9. Pi-xinWang, Xiu-liWu, Xue Dong-hua, Xu Kun, Tan Ying, Du Xi-bing, & Li Wen-bo. (2009). ER, % Preparation and characterization of cationic corn starch with a high degree of substitution in dioxane-THFwater media. Carbohydrate Research, 344, 851–855. | |
| dc.relation.referencesen | 10. Litviak, V. V., & Kanarskii, A. V. (2016). Osobennosti kationizatsii α-D-hliukopiranozy krakhmala v polozhenii3S atoma (N-3-khloro-2- hidroksipropil)-N, N, N-trimetilammonii khlo- ridom. Plasticheskie massy, 7–8, 27–31. | |
| dc.relation.referencesen | 11. Khalil, M. I., Farag and, S., & Hushem, A. (1993) Preparation fnd Characterization of Some Cationic Starches. Journal Starch/stärke, 45 (6), 226–231. | |
| dc.relation.referencesen | 12. Cheronis, N., & Ma, T. S. (1973) Mikro- i polumikro metody orhanicheskoho funktsionalnoho analiza. M., Khimiia, 576. | |
| dc.relation.referencesen | 13. Pat. CN1187484A, China. Inventor Yang Jinzong Zhang Yonghua Yan Xiujun Wan Yongxiang Ding Wenguang (1997). Process for synthesizing 3- chloro-2-hydroxypropyl-trimethyl ammonium chloride. | |
| dc.relation.referencesen | 14. Khalil, M. I. & Farag Dokki, A. (1998). Preparation of Some Cationic Starches using the Dry Process. Journal Starch/stärke, 50(6), 267-271. | |
| dc.relation.referencesen | 15. Kazitsyna, L. A., & Kupletskaia, N. B. (1971). Primenenie UF-, IK- i IaMR- spektroskopii v orhanicheskoi khimii, M: Vysshaia shkola, 264. | |
| dc.relation.referencesen | 16. Kizil, J. & Seetharaman, K. (2002). Characterization of Irradiated Starches by Using FTRaman and FTIR Spectroscopy. Journal of Agriculture and food chemistry, 50, 3912–3918. | |
| dc.relation.referencesen | 17. Pereira, A. G., Paulino, A. T., Rubira, A. F., & Muniz, E. C. (2010). Polymer-polymer miscibility in PEO/cationic starch and PEO/hydrophobic starch bland. eXPRESS Polymer Letters, 4(8), 488–499. | |
| dc.relation.referencesen | 18. Fanga, J. M., Fowlera, P. A., Sayersb, C. & Williams P. A. (2004). The chemical modification of a range of starches under aqueous reaction conditions. Carbohydrate Polymers, 55, 283–289. | |
| dc.relation.referencesen | 19. Chun Bei Huang, Robert Jeng, Mohini Sain, Bradley A. Saville & Martin Hubbes. (2006). Production, characterization, and mechanical propertiesof starch modified by Ophiostoma spp. Bioresources, 1(2), 257–269. | |
| dc.relation.referencesen | 20. Lovkis, Z. V., Litviak, V. V., & Petiu- shev N. N. (2007). Tekhnolohiia krakhmala i krakhmalo- produktov: tutorial, RUP "Nauchno-praktiches- kii tsentr Natsionalnoi akademii nauk Belarusi po prodovolstviiu, Minsk: Asobny, 178. | |
| dc.relation.referencesen | 21. Quanxiao Liu, Jinli Li, & Wencai Xu. (2010). Application of Cationic Starch with High Degree of Substitution in Packaging Paper from High Yield Pulp. Scientific Research. Proceedings of the 17th IAPRI World Conference on Packaging, 35–38. | |
| dc.subject | катіонний крохмаль | |
| dc.subject | ступінь заміщення | |
| dc.subject | триетиламін | |
| dc.subject | cationic starch | |
| dc.subject | degree of substitution | |
| dc.subject | triethylamine | |
| dc.title | Одержання і характеристика катіонних крохмалів | |
| dc.title.alternative | Preparation and characteristics of cationic starches | |
| dc.type | Article |
Files
License bundle
1 - 1 of 1