Електроокиснення CH3OH на поверхні наноструктурованих Pd-Au/GC електродів

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dc.citation.epage110
dc.citation.issue2
dc.citation.spage105
dc.contributor.affiliationНаціональний університет “Львівська політехніка”
dc.contributor.authorДобровецька, О. Я.
dc.contributor.authorСтадник, Р. В.
dc.contributor.authorDobrovetska, O. Ya.
dc.contributor.authorStadnyk, R. V.
dc.coverage.placenameLviv
dc.coverage.placenameLviv
dc.date.accessioned2020-02-28T11:07:41Z
dc.date.available2020-02-28T11:07:41Z
dc.date.created2018-02-26
dc.date.issued2018-02-26
dc.description.abstractМетодом циклічної вольтамперометрії досліджено каталітичну активність нано- структурованих Pd-Au/GC електродів у реакціях електрохімічного окиснення СН3ОН у лужному середовищі. Встановлено, що під час електрохімічного окиснення метанолу на поверхні Pd-Au/GC проявляється послідовна каталітична дія компонентів Pd та Au. Збільшення вмісту паладію пришвидшує повне окиснення метанолу, сприяючи зменшенню вмісту проміжних сполук, що підтверджує високу ефективність наноструктурованих Pd-Au/GC електродів.
dc.description.abstractThe catalytic activity of nanostructured Pd-Au in electrochemical oxidation of СН3ОН in an alkaline environment was researched by the method of cyclic voltammetry. It was found, that during the in electrochemical oxidation of methanol on the surface of the Pd-Au/GC electrode is manifested sequential catalytic action of components Pd and Au. An increase in the content of palladium accelerates the complete oxidation of methane, contributing to a decrease in the content of intermediates, indicating the high efficiency of nanostructured Pd- Au/GC electrodes.
dc.format.extent105-110
dc.format.pages6
dc.identifier.citationДобровецька О. Я. Електроокиснення CH3OH на поверхні наноструктурованих Pd-Au/GC електродів / О. Я. Добровецька, Р. В. Стадник // Chemistry, Technology and Application of Substances. — Lviv : Lviv Politechnic Publishing House, 2018. — Том 1. — № 2. — С. 105–110.
dc.identifier.citationenDobrovetska O. Ya. Electrochemical oxidation of CH3OH on the surface of nanostructured bimetallic Pd-Au/GC electrodes / O. Ya. Dobrovetska, R. V. Stadnyk // Chemistry, Technology and Application of Substances. — Lviv : Lviv Politechnic Publishing House, 2018. — Vol 1. — No 2. — P. 105–110.
dc.identifier.urihttps://ena.lpnu.ua/handle/ntb/46339
dc.language.isouk
dc.publisherLviv Politechnic Publishing House
dc.relation.ispartofChemistry, Technology and Application of Substances, 2 (1), 2018
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dc.relation.referencesen13. Sus L. Controlled gold deposition by pulse electrolysis, L. Sus, Ye. Okhremchuk, I. Saldan, O. Kuntyi, O. Reshetnyak, S. Korniy, Materials Letters, 2015, Vol. 139, P. 296–299.
dc.relation.referencesen14. Fratini E. Nucleation and growth of Au and Au–Pd nanoparticles at the beginning of electrochemical deposition, E. Fratini, A. Girella, I. Saldan, C. Milanese, O. Dobrovetska, L. Sus, Ye. Okhremchuk, O. Kuntyi, O. Reshetnyak, Materials Letters, 2015, Vol. 161, P. 263–266.
dc.rights.holder© Національний університет „Львівська політехніка“, 2018
dc.rights.holder© Добровецька О. Я., Стадник Р. В., 2018
dc.subjectбіметалеві наноструктуровані електроди
dc.subjectPd-Au
dc.subjectкаталіз
dc.subjectелектроокиснення
dc.subjectСН3ОН
dc.subjectbimetal nanostructured electrodes
dc.subjectPd-Au
dc.subjectcatalysis
dc.subjectelecrtooxidation
dc.subjectCH3OH
dc.titleЕлектроокиснення CH3OH на поверхні наноструктурованих Pd-Au/GC електродів
dc.title.alternativeElectrochemical oxidation of CH3OH on the surface of nanostructured bimetallic Pd-Au/GC electrodes
dc.typeArticle

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Chemistry, Technology and Application of Substances. – 2018. – Vol. 1, No. 2