Study of sorption of Мn2+ ions by natural clinoptilolite

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dc.citation.epage46
dc.citation.issue2
dc.citation.spage40
dc.contributor.affiliationНаціональний університет “Львівська політехніка”
dc.contributor.affiliationНаціональний університет “Львівська політехніка”
dc.contributor.affiliationLviv Polytechnic National University
dc.contributor.affiliationLviv Polytechnic National University
dc.contributor.authorПиріг, М. А.
dc.contributor.authorЗнак, З. О.
dc.contributor.authorPyrih, M. A.
dc.contributor.authorZnak, Z. O.
dc.coverage.placenameЛьвів
dc.coverage.placenameLviv
dc.date.accessioned2026-01-15T13:53:25Z
dc.date.created2024-10-10
dc.date.issued2024-10-10
dc.description.abstractДосліджено процес модифікації природного кліноптилоліту, попередньо збагаченого основним компонентом, іонами марганцю з нітратних розчинів як прекурсорів для отримання манган (IV) оксиду. Визначено значення сорбційної ємності різних фракцій кліноптилоліту щодо іонів марганцю за кімнатної температури, розраховано швидкість сорбції та константи швидкості цього процесу. Визначено вплив концентрації розчину нітрату марганцю на сорбційну здатність окремих фракцій цеоліту. Проаналізовано пе- ребіг іонного обміну між обмінними катіонами кліноптилоліту та іонами марганцю та встановлено вибірковість цього процесу.
dc.description.abstractThe process of modification of natural clinoptilolite, pre-enriched by the main component, with manganese ions from nitrate solutions as precursors for obtaining manganese (IV) oxide was studied. The value of the sorption capacity of different fractions of clinoptilolite with respect to manganese ions at room temperature was determined, and the sorption rate and rate constants of this process were calculated. The influence of the concentration of manganese nitrate solution on the sorption capacity of certain fractions of zeolite was determined. The course of ion exchange between the exchangeable cations of clinoptilolite and manganese ions was analyzed, and the selectivity of this process was established.
dc.format.extent40-46
dc.format.pages7
dc.identifier.citationPyrih M. A. Study of sorption of Мn2+ ions by natural clinoptilolite / M. A. Pyrih, Z. O. Znak // Chemistry, Technology and Application of Substances. — Lviv : Lviv Politechnic Publishing House, 2024. — Vol 7. — No 2. — P. 40–46.
dc.identifier.citation2015Pyrih M. A., Znak Z. O. Study of sorption of Мn2+ ions by natural clinoptilolite // Chemistry, Technology and Application of Substances, Lviv. 2024. Vol 7. No 2. P. 40–46.
dc.identifier.citationenAPAPyrih, M. A., & Znak, Z. O. (2024). Study of sorption of Мn2+ ions by natural clinoptilolite. Chemistry, Technology and Application of Substances, 7(2), 40-46. Lviv Politechnic Publishing House..
dc.identifier.citationenCHICAGOPyrih M. A., Znak Z. O. (2024) Study of sorption of Мn2+ ions by natural clinoptilolite. Chemistry, Technology and Application of Substances (Lviv), vol. 7, no 2, pp. 40-46.
dc.identifier.doihttps://doi.org/10.23939/ctas2024.02.040
dc.identifier.urihttps://ena.lpnu.ua/handle/ntb/124466
dc.language.isoen
dc.publisherВидавництво Львівської політехніки
dc.publisherLviv Politechnic Publishing House
dc.relation.ispartofChemistry, Technology and Application of Substances, 2 (7), 2024
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dc.relation.references11. Yadav, V., Rani, V., Kumar, L., Singh, N., Ezhilselvi, V. (2022) Efect of Surface Modifcation of Natural Zeolite on Ammonium Ion Removal fromWater Using Batch Study: an Overview. Water Air Soil Pollu,t233:465. https://doi.org/10.1007/s11270-022-05948-4
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dc.relation.references13. Znak Z. О., Коrnii S. А., Маshtaler A. S., Zin O. І. (2021). Production of Nanoporous Zeolites Modified by Silver Ions with Antibacterial Properties. Materials Science, 56, 4, 536–543. DOI: 10.1007/s11003-021-00461-1
dc.relation.references14. Znak, Z., Zin, O., Mashtaler, A., Korniy, S., Sukhatskiy, Yu., Gogate, P. R., Mnykh, R., Thanekar, P. (2021). Improved modification of clinoptilolite with silver using ultrasonic radiation. Ultrasonics Sonochemistry. 73,105496. https://doi.org/10.1016/j.ultsonch.2021.105496
dc.relation.references15. Ivanenko, O. I., Krysenko, D. A., Krysenko, T. V., Tobilko, V. Yu. (2020). Vykorystannia pryrodnoho tseolitu sokyrnytskoho rodovyshcha dlia otrymannia oksydno- marhantsevoho katalizatora okyslennia monooksydu vuhletsiu. Visnyk KhNTU, No. 3(74), 26–37 (in Ukrainian). https://doi.org/10.35546/kntu2078-4481.2020.3.3
dc.relation.references16. Zenovii Znak, Viktoria Kochubei (2023). Influence of Natural Clinoptilolite Modification with Ions and Zero-Valent Silver on its Sorption Capacity. Chemistry & Chemical Technology, 17, 3, 646–654.https://doi.org/10.23939/chcht17.03.646
dc.relation.referencesen1. Bertholini, M. G. (2016). Innovative applications of natural zeolite. Skripsi. Department of Physics Chemistry and Mechanical Engineering science and Engineering. Queensland University of Technology.
dc.relation.referencesen2. Mkilima, T., Devrishov, D., Kydyrbekova, Ubasdulayeva, N., Tleukolov, A., Khassenova, A., Yussupova, N., Birimzhanova, D. (2022). Natural Zeolite for The Purification of Saline Groundwater and Irrigation Potential Analysis. Molecules, 27(22): 7729. DOI:10.3390/molecules27227729
dc.relation.referencesen3. Kallo, D. (2001). Applications of Natural Zeolites in Water and Wastewater Treatment. Reviews in Mineralogy and Geochemistry, 45 (1): 519–550.https://doi.org/10.2138/rmg.2001.45.15
dc.relation.referencesen4. Margeta, K., Zabukovec, N., Šiljeg, V., Farkas, A. (2013). Natural Zeolites in Water Treatment – How Effective is Their Use. Water Treatment. 16 January.DOI: 10.5772/50738
dc.relation.referencesen5. Mastinu, A., Kumar, A., Maccarinelli, G., Bonini, S. A., Premoli, M., Aria, F., Gianoncelli, A., Memo, M. (2019). Zeolite Clinoptilolite: Therapeutic Virtues of an Ancient Mineral. Molecules, 24, 1517.DOI: 10.3390/molecules24081517 www.mdpi.com/journal/molecules
dc.relation.referencesen6. Pavelic, S. K., Medica, J. S., Gumbarevic, D., Filosevic, A., Przuli, N., Pavelic, K. (2018). Clinoptilolite Safety and Medical Applications in vivo. Frontiers in Pharmacology, 9, 1350. DOI: 10.3385/phar.2018.01350.
dc.relation.referencesen7. Brambilla, D., Mancuso, C., Scuderi, M. R., Bosco P., Cantarella, G., Lempereur, L. (2008). The role of antioxidant supplement in immune system, neoplastic, and neurodegenerative disorders: a point of view for an assessment of the risk/benefit profile. Nutr. J., 7, 29–38.DOI: 10.1186/1475-2891-7-29
dc.relation.referencesen8. Rehakova, M., ´Cuvanova, S., Dzivak, M., Rima, J., Gavalova, Z. (2004). Agricultural and agrochemical uses of natural zeolite of the clinoptilolite type. Current Opinion in Solid State and Materials Science, 8, 397–404.DOI: 10.1016/j.cossms.2005.04.004
dc.relation.referencesen9. De Velasco-Maldonado, P. S., Hernández- Montoya, V., Montes-Morán, M., Vázquez, N. A-R., Pérez-Cruz, M. A. (2018), Surface modification of a natural zeolite by treatment with cold oxygen plasma: Characterization and application in water treatment. Applied Surface Science, 434, 1193–1199. https://doi.org/10.1016/j.apsusc.2017.11.023
dc.relation.referencesen10. Abdulkerim, Y. (2012). Influence of acid activation on the ion-exchange properties of manisagordes clinoptilolite. Physicochem. Probl. Miner. Process,48, 591–598.
dc.relation.referencesen11. Yadav, V., Rani, V., Kumar, L., Singh, N., Ezhilselvi, V. (2022) Efect of Surface Modifcation of Natural Zeolite on Ammonium Ion Removal fromWater Using Batch Study: an Overview. Water Air Soil Pollu,t233:465. https://doi.org/10.1007/s11270-022-05948-4
dc.relation.referencesen12. Reeve, P. J., Fallowfield, H. J. (2017). Natural and surfactant modified zeolites: A review of their applications for water remediation with a focus on surfactant desorption and toxicity towards microorganisms. J. Environ. Manage, 1:205:253–261.DOI: 10.1016/j.jenvman.2017.09.077
dc.relation.referencesen13. Znak Z. O., Kornii S. A., Mashtaler A. S., Zin O. I. (2021). Production of Nanoporous Zeolites Modified by Silver Ions with Antibacterial Properties. Materials Science, 56, 4, 536–543. DOI: 10.1007/s11003-021-00461-1
dc.relation.referencesen14. Znak, Z., Zin, O., Mashtaler, A., Korniy, S., Sukhatskiy, Yu., Gogate, P. R., Mnykh, R., Thanekar, P. (2021). Improved modification of clinoptilolite with silver using ultrasonic radiation. Ultrasonics Sonochemistry. 73,105496. https://doi.org/10.1016/j.ultsonch.2021.105496
dc.relation.referencesen15. Ivanenko, O. I., Krysenko, D. A., Krysenko, T. V., Tobilko, V. Yu. (2020). Vykorystannia pryrodnoho tseolitu sokyrnytskoho rodovyshcha dlia otrymannia oksydno- marhantsevoho katalizatora okyslennia monooksydu vuhletsiu. Visnyk KhNTU, No. 3(74), 26–37 (in Ukrainian). https://doi.org/10.35546/kntu2078-4481.2020.3.3
dc.relation.referencesen16. Zenovii Znak, Viktoria Kochubei (2023). Influence of Natural Clinoptilolite Modification with Ions and Zero-Valent Silver on its Sorption Capacity. Chemistry & Chemical Technology, 17, 3, 646–654.https://doi.org/10.23939/chcht17.03.646
dc.relation.urihttps://doi.org/10.2138/rmg.2001.45.15
dc.relation.urihttps://doi.org/10.1016/j.apsusc.2017.11.023
dc.relation.urihttps://doi.org/10.1007/s11270-022-05948-4
dc.relation.urihttps://doi.org/10.1016/j.ultsonch.2021.105496
dc.relation.urihttps://doi.org/10.35546/kntu2078-4481.2020.3.3
dc.relation.urihttps://doi.org/10.23939/chcht17.03.646
dc.rights.holder© Національний університет „Львівська політехніка“, 2024
dc.subjectцеоліт
dc.subjectкліноптилоліт
dc.subjectочищення води
dc.subjectіони заліза
dc.subjectіони марганцю (II)
dc.subjectсірководень
dc.subjectмодифікація
dc.subjectкаталізатор
dc.subjectокиснення
dc.subjectсорбція
dc.subjectсорбційна здатність
dc.subjectман- ган (IV) оксид
dc.subjectzeolite
dc.subjectclinoptilolite
dc.subjectwater purification
dc.subjectiron ions
dc.subjectmanganese (II) ions
dc.subjecthydrogen sulfide
dc.subjectmodification
dc.subjectcatalyst
dc.subjectoxidation
dc.subjectsorption
dc.subjectsorption capacity
dc.subjectmanganese (IV) oxide
dc.titleStudy of sorption of Мn2+ ions by natural clinoptilolite
dc.title.alternativeДослідження сорбції йонів Мn2+ природним кліноптилолітом
dc.typeArticle

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Chemistry, Technology and Application of Substances. – 2024. – Vol. 7, No. 2