Production of Bitumen Modified with Low-Molecular Organic Compounds from Petroleum Residues. 6. Temperature Effect on the Chemical Modification of Bitumen with Maleic Anhydride

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dc.citation.epage483
dc.citation.issue3
dc.citation.spage475
dc.contributor.affiliationLviv Polytechnic National University
dc.contributor.authorGunka, Volodymyr
dc.contributor.authorHrynchuk, Yurii
dc.contributor.authorSidun, Iurii
dc.contributor.authorDemchuk, Yuriy
dc.contributor.authorPrysiazhnyi, Yuriy
dc.contributor.authorBratychak, Michael
dc.coverage.placenameЛьвів
dc.coverage.placenameLviv
dc.date.accessioned2024-01-22T12:00:10Z
dc.date.available2024-01-22T12:00:10Z
dc.date.created2022-03-16
dc.date.issued2022-03-16
dc.description.abstractПроведено процес хімічного модифікування окисненого бітуму виробленого на українському нафтопереробному заводі малеїновим ангідридом. Доведено, що найбільш суттєво впливає на модифікування - температура процесу. Підтверджено, що в процесі модифікування малеїновий ангідрид хімічно взаємодіє із складовими частинами окисненого бітуму. Показано, що за нижчих температур (до 403 К) процес модифікування відбувається за іншим хімізмом ніж за вищих температур. Проведено FTIR спектральні дослідження для бітумів модифікованих малеїновим ангідридом за різних температур процесу (403, 423 та 443 К) та встановлено структури цих модифікованих бітумів. Також проведено процес прогріття в тонкій плівці за 436 К (методом RTFOT) для бітумів модифікованих малеїновим ангідридом при різних температурах. Встановлено, що для бітуму модифікованого малеїновим ангідридом за 403 К після прогріття за методом RTFOT відбувається руйнування утвореної структури, що підтверджується зменшенням температури розм’якшення модифікованого бітуму. Також знято FTIR спектри вихідного окисненого бітуму та бітумів модифікованих малеїновим ангідридом за 403 і 443 К після процесу прогріття за методом RTFOT. На основі одержаних FTIR спектрів встановлено структурні перетворення, що відбуваються в процесі прогріття з цими бітумами.
dc.description.abstractThe oxidized bitumen produced at the Ukrainian refinery was modified with maleic anhydride. The process temperature was proved to have the most significant effect on modification. The chemical interaction of maleic anhydride with the components of oxidized bitumen was confirmed. At low temperatures (up to 403 K) the chemistry of the modification process is another than chemistry of the process carried out at high temperatures. The structures of the modified bitumen were established at different process temperatures (403, 423 and 443 K) using FTIR spectroscopy. A thin film heating at 436 K (RTFOT method) was performed for the bitumen under study. It was found that for bitumen modified at 403 K, the formed structure is destroyed after heating by RTFOT, which is confirmed by a decrease in the softening point of the bitumen. The FTIR spectra of the original oxidized bitumen and bitumen modified with maleic anhydride at 403 and 443 K were recorded after the RTFOT heating process. Based on the obtained data, the structural transformations that occurred during heating were established.
dc.format.extent475-483
dc.format.pages9
dc.identifier.citationProduction of Bitumen Modified with Low-Molecular Organic Compounds from Petroleum Residues. 6. Temperature Effect on the Chemical Modification of Bitumen with Maleic Anhydride / Volodymyr Gunka, Yurii Hrynchuk, Iurii Sidun, Yuriy Demchuk, Yuriy Prysiazhnyi, Michael Bratychak // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2022. — Vol 16. — No 3. — P. 475–483.
dc.identifier.citationenProduction of Bitumen Modified with Low-Molecular Organic Compounds from Petroleum Residues. 6. Temperature Effect on the Chemical Modification of Bitumen with Maleic Anhydride / Volodymyr Gunka, Yurii Hrynchuk, Iurii Sidun, Yuriy Demchuk, Yuriy Prysiazhnyi, Michael Bratychak // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2022. — Vol 16. — No 3. — P. 475–483.
dc.identifier.doidoi.org/10.23939/chcht16.03.475
dc.identifier.urihttps://ena.lpnu.ua/handle/ntb/60995
dc.language.isoen
dc.publisherВидавництво Львівської політехніки
dc.publisherLviv Politechnic Publishing House
dc.relation.ispartofChemistry & Chemical Technology, 3 (16), 2022
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dc.relation.references[2] Koval, I.; Starchevskyy, V. Gas Nature Effect on the Destruction of Various Microorganisms under Cavitation Action. Chem. Chem. Technol. 2020, 14 (2), 264-270. https://doi.org/10.23939/chcht14.02.264
dc.relation.references[3] Shevchuk, L.; Strogan, O.; Koval, I. Equipment for Magnetic-Cavity Water Disinfection. Chem. Chem. Technol. 2012, 2 (6), 219-223. https://doi.org/10.23939/chcht06.02.219
dc.relation.references[4] Polacco, G.; Berlincioni, S.; Biondi, D.; Stastna, J.; Zanzotto, L. Asphalt Modification with Different Polyethylene-Based Polymers. Eur. Polym. J. 2005, 41, 2831-2844. https://doi.org/10.1016/j.eurpolymj.2005.05.034
dc.relation.references[5] Giavarini, C.; De Filippis, P.; Santarelli, M.L.; Scarsella, M. Production of Stable Polypropylene-Modified Bitumens. Fuel 1996, 75, 681-686. https://doi.org/10.1016/0016-2361(95)00312-6
dc.relation.references[6] Abdel-Goad, M.A.H. Waste Polyvinyl Chloride-Modified Bitumen. J. Appl. Polym. Sci. 2006, 101(3), 1501-1505. https://doi.org/10.1002/app.22623
dc.relation.references[7] Padhan, R.K.; Sreeram, A.; Mohanta, C.S. Chemically Recycled Polyvinyl Chloride as a Bitumen Modifier: Synthesis, Characterisation and Performance evaluation. Road Mater. Pavement Des. 2021, 22(3), 639-652. https://doi.org/10.1080/14680629.2019.1614968
dc.relation.references[8] Lu, X.; Isacsson, U. Modification of Road Bitumens with Thermoplastic Polymers. Polym. Test. 2000, 20(1), 77-86. https://doi.org/10.1016/S0142-9418(00)00004-0
dc.relation.references[9] Becker, M.Y.; Muller, A.J.; Rodriguez, Y. Use of Rheological Compatibility Criteria to Study SBS Modified Asphalts. J. Appl. Polym. Sci. 2003, 90, 1772-1782. https://doi.org/10.1002/app.12764
dc.relation.references[10] Jasso, M.; Hampl, R.; Vacin, O.; Bakos, D.; Stastna, J.; Zanzotto, L. Rheology of Conventional Asphalt Modified with SBS, Elvaloy and Polyphosphoric acid. Fuel Process. Technol. 2015, 140, 172-179. https://doi.org/10.1016/j.fuproc.2015.09.002
dc.relation.references[11] Zhang, H.; Su, C.; Bu, X.; Zhang, Y.; Gao, Y.; Huang, M. Laboratory Investigation on the Properties of Polyurethane/Unsaturated Polyester Resin Modified Bituminous Mixture. Constr. Build. Mater. 2020, 260, 119865. https://doi.org/10.1016/j.conbuildmat.2020.119865
dc.relation.references[12] Gunka, V.; Demchuk, Yu.; Pyshyev, S.; Starovoit, A.; Lypko, Y. The Selection of Raw Materials for the Production of Road Bitumen Modified by Phenol-Cresol-Formaldehyde Resins. Pet. Coal 2018, 60 (6), 1199-1206.
dc.relation.references[13] Demchuk, Y.; Sidun, I.; Gunka, V.; Pyshyev, S.; Solodkyy, S. Effect of Phenol-Cresol-Formaldehyde Resin on Adhesive and Physico-Mechanical Properties of Road Bitumen. Chem. Chem. Technol. 2018, 12 (4), 456-461. https://doi.org/10.23939/chcht12.04.456
dc.relation.references[14] Pyshyev, S.; Demchuk, Y.; Gunka, V.; Sidun, I.; Shved, M.; Bilushchak, H.; Obshta, A. Development of Mathematical Model and Identification of Optimal Conditions to Obtain Phenol-Cresol-Formaldehyde Resin. Chem. Chem. Technol. 2019, 13 (2), 212-217. https://doi.org/10.23939/chcht13.02.212
dc.relation.references[15] Demchuk, Y.; Gunka, V.; Pyshyev, S.; Sidun, I.; Hrynchuk, Y.; Kucinska-Lipka, J.; Bratychak, M. Slurry Surfacing Mixes on the Basis of Bitumen Modified with Phenol-Cresol-Formaldehyde Resin. Chem. Chem. Technol. 2020, 14 (2), 251-256. https://doi.org/10.23939/chcht14.02.251
dc.relation.references[16] Gunka, V.; Demchuk, Y.; Sidun, I.; Miroshnichenko, D.; Nyakuma, B.B.; Pyshyev, S. Application of Phenol-Cresol-Formaldehyde Resin as an Adhesion Promoter for Bitumen and Asphalt Concrete. Road Mater. Pavement Des. 2021, 22 (12), 2906-2918. https://doi.org/10.1080/14680629.2020.1808518
dc.relation.references[17] Demchuk, Y.; Gunka, V.; Sidun, I.; Solodkyy, S. Comparison of Bitumen Modified by Phenol Formaldehyde Resins Synthesized from Different Raw Materials. Proc. of EcoComfort. 2020, 100, 95-102 https://doi.org/10.1007/978-3-030-57340-9_1
dc.relation.references[18] Pyshyev, S.; Demchuk, Y.; Poliuzhyn, I.; Kochubei, V. Obtaining and Use Adhesive Promoters to Bitumen from the Phenolic Fraction of Coal Tar. Int. J. Adhes. Adhes. 2022, 118, 103191. https://doi.org/10.1016/j.ijadhadh.2022.103191
dc.relation.references[19] Strap, G.; Astakhova, O.; Lazorko, O.; Shyshchak, O.; Bratychak, M. Modified Phenol-Formaldehyde Resins and Their Application in Bitumen-Polymeric Mixtures. Chem. Chem. Technol. 2013, 7, 279-287. https://doi.org/10.23939/chcht07.03.279
dc.relation.references[20] Bratychak, M.; Grynyshyn, O.; Astakhova, O.; Shyshchak, O.; Wacławek, W. Functional Petroleum Resins Based on Pyrolysis By-Products and Their Application for Bitumen Modification. Ecol. Chem. Eng. 2010, 17, 309-315.
dc.relation.references[21] Gunka, V.; Demchuk, Y.; Sidun, I.; Kochubei, V.; Shved. M.; Romanchuk, V.; Korchak, B. Chemical Modification of Road Oil Bitumens by Formaldehyde. Pet. Coal 2020, 62 (1), 420-429.
dc.relation.references[22] Bratychak, M.; Gunka, V.; Prysiazhnyi, Yu.; Hrynchuk, Yu.; Sidun, I.; Demchuk, Yu.; Shyshchak, O. Production of Bitumen Modified with Low-Molecular Organic Compounds from Petroleum Residues. 1. Effect of Solvent Nature on the Properties of Petroleum Residues Modified with Folmaldehyde. Chem. Chem. Technol. 2021, 15 (2), 274-283. https://doi.org/10.23939/chcht15.02.274
dc.relation.references[23] Gunka, V.; Prysiazhnyi, Yu.; Hrynchuk, Yu.; Sidun, I.; Demchuk, Yu.; Shyshchak, O.; Bratychak, M. Production of Bitumen Modified with Low-Molecular Organic Compounds from Petroleum Residues. 2. Bitumen Modified with Maleic Anhydride. Chem. Chem. Technol. 2021, 15 (3), 443-449. https://doi.org/10.23939/chcht15.03.443
dc.relation.references[24] Gunka, V.; Prysiazhnyi, Yu.; Hrynchuk, Yu.; Sidun, I.; Demchuk, Yu.; Shyshchak, O.; Poliak, O.; Bratychak, M. Production of Bitumen Modified with Low-Molecular Organic Compounds from Petroleum Residues. 3. Tar Modified with Formaldehyde. Chem. Chem. Technol. 2021, 15 (4), 608-620. https://doi.org/10.23939/chcht15.04.608
dc.relation.references[25] Gunka, V.; Bilushchak, H.; Prysiazhnyi, Yu.; Demchuk, Yu.; Hrynchuk, Yu.; Sidun, I.; Shyshchak, O.; Bratychak, M. Production of Bitumen Modified with Low-Molecular Organic Compounds from Petroleum Residues. 4. Determining the Optimal Conditions for Tar Modification with Formaldehyde and Properties of the Modified Products. Chem. Chem. Technol. 2022, 16 (1), 142-149. https://doi.org/10.23939/chcht16.01.142
dc.relation.references[26] Gunka, V.; Prysiazhnyi, Yu.; Demchuk, Yu.; Hrynchuk, Yu.; Sidun, I.; Reutskyy, V.; Bratychak, M. Production of Bitumen Modified with Low-Molecular Organic Compounds from Petroleum Residues. 5. Use Of Maleic Anhydride For Foaming Bitumens. Chem. Chem. Technol. 2022, 16 (2), 295-302. https://doi.org/10.23939/chcht16.02.295
dc.relation.references[27] Wręczycki, J.; Demchuk, Y.; Bieliński, D.M.; Bratychak, M.; Gunka, V.; Anyszka, R.; Gozdek, T. Bitumen Binders Modified with Sulfur/Organic Copolymers. Materials 2022, 15(5), 1774. https://doi.org/10.3390/ma15051774
dc.relation.references[28] Herrington, P.R.; Wu, Y.; Forbes, M.C. Rheological Modification of Bitumen with Maleic Anhydride and Dicarboxylic Acids. Fuel 1999, 78 (1), 101-110. https://doi.org/10.1016/S0016-2361(98)00120-3
dc.relation.references[29] Kang, Y.; Wang, F.; Chen, Z. Reaction of Asphalt and Maleic Anhydride: Kinetics and Mechanism. Chem. Eng. J. 2010, 164 (1), 230-237. https://doi.org/10.1016/j.cej.2010.08.020
dc.relation.references[30] BS EN 1427:2015, Bitumen and bituminous binders. Determination of the softening point. Ring and Ball method, 2015.
dc.relation.references[31] BS EN 1426:2015, Bitumen and bituminous binders. Determination of needle penetration, 2015.
dc.relation.references[32] BS EN 12593:2015, Bitumen and bituminous binders. Determination of the Fraass breaking point, 2015
dc.relation.references[33] BS EN 13587:2016, Bitumen and bituminous binders. Determination of the tensile properties of bituminous binders by the tensile test method, 2016.
dc.relation.references[34] DSTU 8787:2018 (National Standard of Ukraine), Bitumen and bituminous binders. Determination of adhesion with crushed stone, 2018.
dc.relation.references[35] BS EN 12607-1:2014, Bitumen and bituminous binders. Determination of the resistance to hardening under influence of heat and air RTFOT method, 2014.
dc.relation.referencesen[1] Zhu, J.; Birgisson, B.; Kringos, N. Polymer Modification of Bitumen: Advances and Challenges. Eur. Polym. J. 2014, 54. 18-38. https://doi.org/10.1016/j.eurpolymj.2014.02.005
dc.relation.referencesen[2] Koval, I.; Starchevskyy, V. Gas Nature Effect on the Destruction of Various Microorganisms under Cavitation Action. Chem. Chem. Technol. 2020, 14 (2), 264-270. https://doi.org/10.23939/chcht14.02.264
dc.relation.referencesen[3] Shevchuk, L.; Strogan, O.; Koval, I. Equipment for Magnetic-Cavity Water Disinfection. Chem. Chem. Technol. 2012, 2 (6), 219-223. https://doi.org/10.23939/chcht06.02.219
dc.relation.referencesen[4] Polacco, G.; Berlincioni, S.; Biondi, D.; Stastna, J.; Zanzotto, L. Asphalt Modification with Different Polyethylene-Based Polymers. Eur. Polym. J. 2005, 41, 2831-2844. https://doi.org/10.1016/j.eurpolymj.2005.05.034
dc.relation.referencesen[5] Giavarini, C.; De Filippis, P.; Santarelli, M.L.; Scarsella, M. Production of Stable Polypropylene-Modified Bitumens. Fuel 1996, 75, 681-686. https://doi.org/10.1016/0016-2361(95)00312-6
dc.relation.referencesen[6] Abdel-Goad, M.A.H. Waste Polyvinyl Chloride-Modified Bitumen. J. Appl. Polym. Sci. 2006, 101(3), 1501-1505. https://doi.org/10.1002/app.22623
dc.relation.referencesen[7] Padhan, R.K.; Sreeram, A.; Mohanta, C.S. Chemically Recycled Polyvinyl Chloride as a Bitumen Modifier: Synthesis, Characterisation and Performance evaluation. Road Mater. Pavement Des. 2021, 22(3), 639-652. https://doi.org/10.1080/14680629.2019.1614968
dc.relation.referencesen[8] Lu, X.; Isacsson, U. Modification of Road Bitumens with Thermoplastic Polymers. Polym. Test. 2000, 20(1), 77-86. https://doi.org/10.1016/S0142-9418(00)00004-0
dc.relation.referencesen[9] Becker, M.Y.; Muller, A.J.; Rodriguez, Y. Use of Rheological Compatibility Criteria to Study SBS Modified Asphalts. J. Appl. Polym. Sci. 2003, 90, 1772-1782. https://doi.org/10.1002/app.12764
dc.relation.referencesen[10] Jasso, M.; Hampl, R.; Vacin, O.; Bakos, D.; Stastna, J.; Zanzotto, L. Rheology of Conventional Asphalt Modified with SBS, Elvaloy and Polyphosphoric acid. Fuel Process. Technol. 2015, 140, 172-179. https://doi.org/10.1016/j.fuproc.2015.09.002
dc.relation.referencesen[11] Zhang, H.; Su, C.; Bu, X.; Zhang, Y.; Gao, Y.; Huang, M. Laboratory Investigation on the Properties of Polyurethane/Unsaturated Polyester Resin Modified Bituminous Mixture. Constr. Build. Mater. 2020, 260, 119865. https://doi.org/10.1016/j.conbuildmat.2020.119865
dc.relation.referencesen[12] Gunka, V.; Demchuk, Yu.; Pyshyev, S.; Starovoit, A.; Lypko, Y. The Selection of Raw Materials for the Production of Road Bitumen Modified by Phenol-Cresol-Formaldehyde Resins. Pet. Coal 2018, 60 (6), 1199-1206.
dc.relation.referencesen[13] Demchuk, Y.; Sidun, I.; Gunka, V.; Pyshyev, S.; Solodkyy, S. Effect of Phenol-Cresol-Formaldehyde Resin on Adhesive and Physico-Mechanical Properties of Road Bitumen. Chem. Chem. Technol. 2018, 12 (4), 456-461. https://doi.org/10.23939/chcht12.04.456
dc.relation.referencesen[14] Pyshyev, S.; Demchuk, Y.; Gunka, V.; Sidun, I.; Shved, M.; Bilushchak, H.; Obshta, A. Development of Mathematical Model and Identification of Optimal Conditions to Obtain Phenol-Cresol-Formaldehyde Resin. Chem. Chem. Technol. 2019, 13 (2), 212-217. https://doi.org/10.23939/chcht13.02.212
dc.relation.referencesen[15] Demchuk, Y.; Gunka, V.; Pyshyev, S.; Sidun, I.; Hrynchuk, Y.; Kucinska-Lipka, J.; Bratychak, M. Slurry Surfacing Mixes on the Basis of Bitumen Modified with Phenol-Cresol-Formaldehyde Resin. Chem. Chem. Technol. 2020, 14 (2), 251-256. https://doi.org/10.23939/chcht14.02.251
dc.relation.referencesen[16] Gunka, V.; Demchuk, Y.; Sidun, I.; Miroshnichenko, D.; Nyakuma, B.B.; Pyshyev, S. Application of Phenol-Cresol-Formaldehyde Resin as an Adhesion Promoter for Bitumen and Asphalt Concrete. Road Mater. Pavement Des. 2021, 22 (12), 2906-2918. https://doi.org/10.1080/14680629.2020.1808518
dc.relation.referencesen[17] Demchuk, Y.; Gunka, V.; Sidun, I.; Solodkyy, S. Comparison of Bitumen Modified by Phenol Formaldehyde Resins Synthesized from Different Raw Materials. Proc. of EcoComfort. 2020, 100, 95-102 https://doi.org/10.1007/978-3-030-57340-9_1
dc.relation.referencesen[18] Pyshyev, S.; Demchuk, Y.; Poliuzhyn, I.; Kochubei, V. Obtaining and Use Adhesive Promoters to Bitumen from the Phenolic Fraction of Coal Tar. Int. J. Adhes. Adhes. 2022, 118, 103191. https://doi.org/10.1016/j.ijadhadh.2022.103191
dc.relation.referencesen[19] Strap, G.; Astakhova, O.; Lazorko, O.; Shyshchak, O.; Bratychak, M. Modified Phenol-Formaldehyde Resins and Their Application in Bitumen-Polymeric Mixtures. Chem. Chem. Technol. 2013, 7, 279-287. https://doi.org/10.23939/chcht07.03.279
dc.relation.referencesen[20] Bratychak, M.; Grynyshyn, O.; Astakhova, O.; Shyshchak, O.; Wacławek, W. Functional Petroleum Resins Based on Pyrolysis By-Products and Their Application for Bitumen Modification. Ecol. Chem. Eng. 2010, 17, 309-315.
dc.relation.referencesen[21] Gunka, V.; Demchuk, Y.; Sidun, I.; Kochubei, V.; Shved. M.; Romanchuk, V.; Korchak, B. Chemical Modification of Road Oil Bitumens by Formaldehyde. Pet. Coal 2020, 62 (1), 420-429.
dc.relation.referencesen[22] Bratychak, M.; Gunka, V.; Prysiazhnyi, Yu.; Hrynchuk, Yu.; Sidun, I.; Demchuk, Yu.; Shyshchak, O. Production of Bitumen Modified with Low-Molecular Organic Compounds from Petroleum Residues. 1. Effect of Solvent Nature on the Properties of Petroleum Residues Modified with Folmaldehyde. Chem. Chem. Technol. 2021, 15 (2), 274-283. https://doi.org/10.23939/chcht15.02.274
dc.relation.referencesen[23] Gunka, V.; Prysiazhnyi, Yu.; Hrynchuk, Yu.; Sidun, I.; Demchuk, Yu.; Shyshchak, O.; Bratychak, M. Production of Bitumen Modified with Low-Molecular Organic Compounds from Petroleum Residues. 2. Bitumen Modified with Maleic Anhydride. Chem. Chem. Technol. 2021, 15 (3), 443-449. https://doi.org/10.23939/chcht15.03.443
dc.relation.referencesen[24] Gunka, V.; Prysiazhnyi, Yu.; Hrynchuk, Yu.; Sidun, I.; Demchuk, Yu.; Shyshchak, O.; Poliak, O.; Bratychak, M. Production of Bitumen Modified with Low-Molecular Organic Compounds from Petroleum Residues. 3. Tar Modified with Formaldehyde. Chem. Chem. Technol. 2021, 15 (4), 608-620. https://doi.org/10.23939/chcht15.04.608
dc.relation.referencesen[25] Gunka, V.; Bilushchak, H.; Prysiazhnyi, Yu.; Demchuk, Yu.; Hrynchuk, Yu.; Sidun, I.; Shyshchak, O.; Bratychak, M. Production of Bitumen Modified with Low-Molecular Organic Compounds from Petroleum Residues. 4. Determining the Optimal Conditions for Tar Modification with Formaldehyde and Properties of the Modified Products. Chem. Chem. Technol. 2022, 16 (1), 142-149. https://doi.org/10.23939/chcht16.01.142
dc.relation.referencesen[26] Gunka, V.; Prysiazhnyi, Yu.; Demchuk, Yu.; Hrynchuk, Yu.; Sidun, I.; Reutskyy, V.; Bratychak, M. Production of Bitumen Modified with Low-Molecular Organic Compounds from Petroleum Residues. 5. Use Of Maleic Anhydride For Foaming Bitumens. Chem. Chem. Technol. 2022, 16 (2), 295-302. https://doi.org/10.23939/chcht16.02.295
dc.relation.referencesen[27] Wręczycki, J.; Demchuk, Y.; Bieliński, D.M.; Bratychak, M.; Gunka, V.; Anyszka, R.; Gozdek, T. Bitumen Binders Modified with Sulfur/Organic Copolymers. Materials 2022, 15(5), 1774. https://doi.org/10.3390/ma15051774
dc.relation.referencesen[28] Herrington, P.R.; Wu, Y.; Forbes, M.C. Rheological Modification of Bitumen with Maleic Anhydride and Dicarboxylic Acids. Fuel 1999, 78 (1), 101-110. https://doi.org/10.1016/S0016-2361(98)00120-3
dc.relation.referencesen[29] Kang, Y.; Wang, F.; Chen, Z. Reaction of Asphalt and Maleic Anhydride: Kinetics and Mechanism. Chem. Eng. J. 2010, 164 (1), 230-237. https://doi.org/10.1016/j.cej.2010.08.020
dc.relation.referencesen[30] BS EN 1427:2015, Bitumen and bituminous binders. Determination of the softening point. Ring and Ball method, 2015.
dc.relation.referencesen[31] BS EN 1426:2015, Bitumen and bituminous binders. Determination of needle penetration, 2015.
dc.relation.referencesen[32] BS EN 12593:2015, Bitumen and bituminous binders. Determination of the Fraass breaking point, 2015
dc.relation.referencesen[33] BS EN 13587:2016, Bitumen and bituminous binders. Determination of the tensile properties of bituminous binders by the tensile test method, 2016.
dc.relation.referencesen[34] DSTU 8787:2018 (National Standard of Ukraine), Bitumen and bituminous binders. Determination of adhesion with crushed stone, 2018.
dc.relation.referencesen[35] BS EN 12607-1:2014, Bitumen and bituminous binders. Determination of the resistance to hardening under influence of heat and air RTFOT method, 2014.
dc.relation.urihttps://doi.org/10.1016/j.eurpolymj.2014.02.005
dc.relation.urihttps://doi.org/10.23939/chcht14.02.264
dc.relation.urihttps://doi.org/10.23939/chcht06.02.219
dc.relation.urihttps://doi.org/10.1016/j.eurpolymj.2005.05.034
dc.relation.urihttps://doi.org/10.1016/0016-2361(95)00312-6
dc.relation.urihttps://doi.org/10.1002/app.22623
dc.relation.urihttps://doi.org/10.1080/14680629.2019.1614968
dc.relation.urihttps://doi.org/10.1016/S0142-9418(00)00004-0
dc.relation.urihttps://doi.org/10.1002/app.12764
dc.relation.urihttps://doi.org/10.1016/j.fuproc.2015.09.002
dc.relation.urihttps://doi.org/10.1016/j.conbuildmat.2020.119865
dc.relation.urihttps://doi.org/10.23939/chcht12.04.456
dc.relation.urihttps://doi.org/10.23939/chcht13.02.212
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dc.relation.urihttps://doi.org/10.3390/ma15051774
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dc.rights.holder© Національний університет “Львівська політехніка”, 2022
dc.rights.holder© Gunka V., Hrynchuk Y., Sidun I., Demchuk Y., Prysiazhnyi Y., Bratychak M., 2022
dc.subjectбітум
dc.subjectмалеїновий ангідрид
dc.subjectхімічне модифікування
dc.subjectвплив температури
dc.subjectbitumen
dc.subjectmaleic anhydride
dc.subjectchemical modification
dc.subjecttemperature effect
dc.titleProduction of Bitumen Modified with Low-Molecular Organic Compounds from Petroleum Residues. 6. Temperature Effect on the Chemical Modification of Bitumen with Maleic Anhydride
dc.title.alternativeОдержання бітуму, модифікованого низькомолекулярними органічними сполуками із нафтових залишків. 6. Вплив температури на процес хімічного модифікування бітумів малеїновим ангідридом
dc.typeArticle

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Chemistry & Chemical Technology. – 2022. – Vol. 16, No. 3