Litteris et Artibus
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Item Single stage acrylic acid obtaining based on methanol and acetic acid(Lviv Polytechnic Publishing House, 2015) Nebesnyi, Roman; Shpyrka, Iryna; Shatan, Anastasiia-Bohdana; Lukiyanchuk, Andriy; Ivasiv, Volodymyr; Nebesna, Yuliia; Lapychak, Nazariy; Lviv Polytechnic National UniversityThe new complex oxide acid type catalysts were developed and their performance in the process of aldol condensation of acetic acid with formaldehyde to acrylic acid was studied. The optimum conditions of the process were determined. It was established that these catalysts are effective in the process of methanol to formaldehyde oxidation, and also in the process of single stage acrylic acid obtaining from acetic acid and methanol in the presence of air.Item Simultaneous methyl methacrylate and methacrylic acid obtaining over zirconium-containing catalysts(Lviv Polytechnic Publishing House, 2015) Nebesna, Yuliia; Nebesnyi, Roman; Ivasiv, Volodymyr; Lapychak, Nazarii; Lviv Polytechnic National UniversityMethyl methacrylate and methacrylic acid are widely used monomers. The aldol condensation of methyl propionate and formaldehyde is perspective process for simultaneous obtaining of this methacrylate monomers. It was found that zirconium-containing catalysts are active in this process. The effect of zirconium content in the catalyst on methyl propionate conversion and yield of methyl methacrylate and methacrylic acid has been determined. The best catalyst for methyl propionate condensation with formaldehyde has been found.