Thermodynamic properties of butyl methacrylate solutions in organic solvents

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dc.citation.epage12
dc.citation.issue1
dc.citation.spage7
dc.citation.volume12
dc.contributor.affiliationLviv Polytechnic National University
dc.contributor.authorSerheyev, Valentyn
dc.contributor.authorThanh, Tran Van
dc.coverage.placenameLviv
dc.date.accessioned2019-01-29T12:53:40Z
dc.date.available2019-01-29T12:53:40Z
dc.date.created2018-01-20
dc.date.issued2018-01-20
dc.description.abstractСтатичним тензиметричним методом було виміряно тиск насиченої пари над розчинами бутил- метакрилату в ацетонітрилі, бензені, гексані та 1,2-дихло- ретані в температурному інтервалі 293–351 К. За даними температурної залежності тиску насиченої пари розраховано склад рівноважних фаз та коефіцієнти активності ком- понентів. За температурною та концентраційною залежніс- тю коефіцієнтів активності розраховані термодинамічні функції змішування досліджених розчинів.
dc.description.abstractThe saturated vapor pressure of butyl methacrylate solutions in acetonitrile, benzene, hexane and 1,2-diclorethane was measured by static tensimetric method in the temperature range of 291–351 K. The composition of the equilibrium phases and the activity factors were received from the experimental measurements of the temperature-dependent saturated vapor pressure. We then used the temperature and concentration dependent activity factors to calculate the thermodynamic functions of mixing of the solutions.
dc.format.extent7-12
dc.format.pages6
dc.identifier.citationSerheyev V. Thermodynamic properties of butyl methacrylate solutions in organic solvents / Valentyn Serheyev, Tran Van Thanh // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2-18. — Vol 12. — No 1. — P. 7–12.
dc.identifier.citationenSerheyev V. Thermodynamic properties of butyl methacrylate solutions in organic solvents / Valentyn Serheyev, Tran Van Thanh // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2-18. — Vol 12. — No 1. — P. 7–12.
dc.identifier.urihttps://ena.lpnu.ua/handle/ntb/43923
dc.language.isoen
dc.publisherLviv Politechnic Publishing House
dc.relation.ispartofChemistry & Chemical Technology, 1 (12), 2-18
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dc.relation.referencesen[1] Van-Chin-Syan Yu., Kochubei V., Sergeev V. et al., Zh. Fizich. Khim. A, 1996, 70, 1932.
dc.relation.referencesen[2] Eck B., Maurer G., Fluid Phase Equilibr., 2003, 209, 281.https://doi.org/10.1016/S0378-3812(03)00128-6
dc.relation.referencesen[3] Tu C.-H., Wu Y.-S., Liu T.-L., Fluid Phase Equilibr., 1997, 135,97. https://doi.org/10.1016/S0378-3812(97)00054-X
dc.relation.referencesen[4] Danov S., Obmelyuhina T., Chubarov G., Rus. J. Appl. Chem.,1990, 63, 596.
dc.relation.referencesen[5] Dolgopolov A., Obmelyuhina T., Danov S., Rus. J. Appl. Chem., 1991, 64, 1994.
dc.relation.referencesen[6] Scatchard G., Wilson G., J. Amer. Chem. Soc., 1964, 86, 133.https://doi.org/10.1021/ja01056a004
dc.relation.referencesen[7] Renon H., Prausnitz J., Ind. Eng. Chem. Proc. Des. Dev., 1968,7, 220. https://doi.org/10.1021/i260026a011
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dc.relation.referencesen[10] Serheyev V., Kos Yu., Van-Chin-Syan Yu., Chem. Chem. Technol., 2015, 9, 131.
dc.relation.referencesen[11] Sergeev V., Van-Chin-Syan Yu., Rus. J. Phys. Chem. A, 2015,89, 406. https://doi.org/10.1134/S0036024415030279
dc.relation.referencesen[12] Sergeev V., Rus. J. Phys. Chem. A, 2016, 90, 575.https://doi.org/10.1134/S0036024416030274
dc.relation.referencesen[13] Sergeev V., Rus. J. Gen. Chem., 2012, 82, 202. https://doi.org/10.1134/S1070363212020065
dc.relation.referencesen[14] Belousov V., Morachevsky A., Teploty Smesheniya Zydkostei. Khimiya, Leningrad 1970.
dc.relation.referencesen[15] Boublik T., Fried V., Hala E., The Vapour Pressure of Pure Substances. Elsevier, Amsterdam 1973.
dc.relation.urihttps://doi.org/10.1016/S0378-3812(03)00128-6
dc.relation.urihttps://doi.org/10.1016/S0378-3812(97)00054-X
dc.relation.urihttps://doi.org/10.1021/ja01056a004
dc.relation.urihttps://doi.org/10.1021/i260026a011
dc.relation.urihttps://doi.org/10.1134/S0036024411020300
dc.relation.urihttps://doi.org/10.1134/S0036024415030279
dc.relation.urihttps://doi.org/10.1134/S0036024416030274
dc.relation.urihttps://doi.org/10.1134/S1070363212020065
dc.rights.holder© Національний університет „Львівська політехніка“, 2018
dc.rights.holder© Serheyev V., Thanh T., 2018
dc.subjectбутилметакрилат
dc.subjectтиск насиченої пари
dc.subjectкоефіцієнти активності
dc.subjectрівновага рідина-пара
dc.subjectнад- лишкові термодинамічні функції
dc.subjectbutyl methacrylate
dc.subjectsaturated vapor pressure
dc.subjectactivity coefficients
dc.subjectvapor-liquid equilibrium
dc.subjectexcess thermodynamic functions
dc.titleThermodynamic properties of butyl methacrylate solutions in organic solvents
dc.title.alternativeТермодинамічні властивості розчинів бутилметакрилату в органічних розчинниках
dc.typeArticle

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Chemistry & Chemical Technology. – 2018. – Vol. 12, No. 1