Ferrocenylmethylnucleobases: Synthesis, DFT Calculations, Electrochemical and Spectroscopic Characterization

Simple item page
dc.citation.epage153
dc.citation.issue2
dc.citation.spage146
dc.citation.volume14
dc.contributor.affiliationUniversity of El Oued
dc.contributor.affiliationUniversity of Ouargla
dc.contributor.authorLanez, Elhafnaoui
dc.contributor.authorBechki, Lazhar
dc.contributor.authorLanez, Touhami
dc.coverage.placenameЛьвів
dc.coverage.placenameLviv
dc.date.accessioned2020-12-30T08:53:30Z
dc.date.available2020-12-30T08:53:30Z
dc.date.created2020-01-24
dc.date.issued2020-01-24
dc.description.abstractСинтезовані три ферроценілметилнуклеїнові основи (FcMeNb). За допомогою методів циклічної вольтамперометрії, абсорбційної електронної спектроскопії, Фур‘є-спектроскопії та ЯМР-спектроскопії охарактеризовано синтезовані сполуки. Енергію прикордонних молекулярних орбіталей визначено за методом DFT/B3LYP у поєднанні з базовим набором 6-311++G(d, p) в ацетонітрилі. Встановлено, що нижчі стандартні константи швидкостей сполук FcMeNb порівняно з ферроценом вказують на більш повільну кінетику переносу електронів.
dc.description.abstractThree ferrocenylmethylnucleobases (FcMeNb) were synthesized and characterized by cyclic voltammetry, electronic absorption, FT-IR and NMR spectroscopy. The energy of frontier molecular orbitals was determined using DFT/B3LYP method combined with 6-311++G(d,p) basis set in acetonitrile. The lower standard rate constant values of the FcMeNb compounds as compared to ferrocene indicated slower electron transfer kinetics.
dc.format.extent146-153
dc.format.pages8
dc.identifier.citationLanez E. Ferrocenylmethylnucleobases: Synthesis, DFT Calculations, Electrochemical and Spectroscopic Characterization / Elhafnaoui Lanez, Lazhar Bechki, Touhami Lanez // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2020. — Vol 14. — No 2. — P. 146–153.
dc.identifier.citationenLanez E. Ferrocenylmethylnucleobases: Synthesis, DFT Calculations, Electrochemical and Spectroscopic Characterization / Elhafnaoui Lanez, Lazhar Bechki, Touhami Lanez // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2020. — Vol 14. — No 2. — P. 146–153.
dc.identifier.doidoi.org/10.23939/chcht14.02.146
dc.identifier.urihttps://ena.lpnu.ua/handle/ntb/55794
dc.language.isoen
dc.publisherВидавництво Львівської політехніки
dc.publisherLviv Politechnic Publishing House
dc.relation.ispartofChemistry & Chemical Technology, 2 (14), 2020
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dc.relation.referencesen[15] Wagstaff A., Faulds D., Goa K., Drugs, 1994, 47, 153. https://doi.org/10.2165/00003495-199447010-00009
dc.relation.referencesen[16] Zhao L., Zhang L., Liu J. et al., Eur. J. Med. Chem., 2012, 47, 255. https://doi.org/10.1016/j.ejmech.2011.10.050
dc.relation.referencesen[17] Cho Y., Lee J., Song S., Bioconjug. Chem., 2005, 16, 1529. https://doi.org/10.1021/bc049697u
dc.relation.referencesen[18] Meunier P., Quattara B., Gautheron J. et al., Eur. J. Med. Chem., 1991, 26, 351. https://doi.org/10.1016/0223-5234(91)90070-4
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dc.relation.urihttps://doi.org/10.1039/P19890002075
dc.relation.urihttps://doi.org/10.1039/P19900002437
dc.relation.urihttps://doi.org/10.1002/aoc.3664
dc.relation.urihttps://doi.org/10.2174/1389557516666161031141620
dc.relation.urihttps://doi.org/10.1016/S0022-328X(00)90515-1
dc.relation.urihttps://doi.org/10.1039/DT9960004115
dc.relation.urihttps://doi.org/10.1039/A905168F
dc.relation.urihttps://doi.org/10.1002/cplu.201600462
dc.relation.urihttps://doi.org/10.1016/j.ccr.2016.02.008
dc.relation.urihttps://doi.org/10.1002/ejoc.200390025
dc.relation.urihttps://doi.org/10.1021/jm0110284
dc.relation.urihttps://doi.org/10.1016/S0960-894X(99)00133-X
dc.relation.urihttps://doi.org/10.1016/S0968-0896(02)00253-5
dc.relation.urihttps://doi.org/10.1038/323464a0
dc.relation.urihttps://doi.org/10.2165/00003495-199447010-00009
dc.relation.urihttps://doi.org/10.1016/j.ejmech.2011.10.050
dc.relation.urihttps://doi.org/10.1021/bc049697u
dc.relation.urihttps://doi.org/10.1016/0223-5234(91)90070-4
dc.relation.urihttps://doi.org/10.23939/chcht13.01.011
dc.relation.urihttps://doi.org/
dc.relation.urihttps://doi.org/10.1002/aoc.1500
dc.relation.urihttps://doi.org/10.1021/om5000453
dc.relation.urihttps://doi.org/10.1039/JR9580000656
dc.relation.urihttps://doi.org/10.1021/ac60210a007
dc.relation.urihttps://doi.org/10.1021/ac60230a016
dc.relation.urihttps://doi.org/10.1021/ja00905a001
dc.rights.holder© Національний університет “Львівська політехніка”, 2020
dc.rights.holder© Lanez E., Bechki L., Lanez T., 2020
dc.subjectнуклеїнові основи
dc.subjectфероцен
dc.subjectциклічна вольтамперометрія
dc.subjectУФ-спектроскопія
dc.subjectДПФ
dc.subjectnucleobases
dc.subjectferrocene
dc.subjectcyclic voltammetry
dc.subjectUv-Vis spectroscopy
dc.subjectDFT
dc.titleFerrocenylmethylnucleobases: Synthesis, DFT Calculations, Electrochemical and Spectroscopic Characterization
dc.title.alternativeФерроценілметилнуклеїнові основи: синтез, розрахунок ДПФ, електрохімічна та спектроскопічна характеристика
dc.typeArticle

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Chemistry & Chemical Technology. – 2020. – Vol. 14, No. 2