Target synthesis of functional biocompatible nanocomposites with “core-shell” structure

dc.citation.epage42
dc.citation.issue1
dc.citation.spage29
dc.citation.volume12
dc.contributor.affiliationLviv Polytechnic National University
dc.contributor.affiliationInstitute of Cell Biology NAS of Ukraine
dc.contributor.affiliationIvan Franko National University of Lviv
dc.contributor.authorZaichenko, Alexander
dc.contributor.authorMitina, Nataliya
dc.contributor.authorMiagkota, Olesia
dc.contributor.authorHevus, Orest
dc.contributor.authorBilyi, Rortyslav
dc.contributor.authorStoika, Rostyslav
dc.contributor.authorPayuk, Olena
dc.contributor.authorNadashkevych, Zoriana
dc.contributor.authorVoloshinovskii, Anatoliy
dc.coverage.placenameLviv
dc.date.accessioned2019-01-29T12:53:44Z
dc.date.available2019-01-29T12:53:44Z
dc.date.created2018-01-20
dc.date.issued2018-01-20
dc.description.abstractМеталокомплексні макроініціатори були успішно застосовані для синтезу полімерних нанокомпозитів зі структурою “ядро-оболонка” методом двоступінчатої вододисперсійної полімеризації. На першому етапі формування монодисперсних полімерних частинок бажаного розміру і функціональності досягається внаслідок цілеспрямованої зміни концентрації макроініціатору, вмісту катіонів металів в його структурі, і рН середовища. Ініціювання прищеплювальної полімеризації з поверхні затравкових частинок забезпечується залишковими пероксидними фрагментами макроініціатору.
dc.description.abstractMetal-complex macroinitiators were successfully applied for the synthesis of polymer nanocomposites with core-shell structure by two-stage water dispersed polymerization. On the first stage, formation of monodispersed polymer particles of desired size and functionality is achieved by target variation of macroinitiator concentration, content of metal cations in its structure, and pH of medium. Initiation of grafted polymerization from the surface of seeded particles is provided by residual peroxide moieties of macroinitiator.
dc.format.extent29-42
dc.format.pages14
dc.identifier.citationTarget synthesis of functional biocompatible nanocomposites with “core-shell” structure / Alexander Zaichenko, Nataliya Mitina, Olesia Miagkota, Orest Hevus, Rortyslav Bilyi, Rostyslav Stoika, Olena Payuk, Zoriana Nadashkevych, Anatoliy Voloshinovskii // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2-18. — Vol 12. — No 1. — P. 29–42.
dc.identifier.citationenTarget synthesis of functional biocompatible nanocomposites with “core-shell” structure / Alexander Zaichenko, Nataliya Mitina, Olesia Miagkota, Orest Hevus, Rortyslav Bilyi, Rostyslav Stoika, Olena Payuk, Zoriana Nadashkevych, Anatoliy Voloshinovskii // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2-18. — Vol 12. — No 1. — P. 29–42.
dc.identifier.urihttps://ena.lpnu.ua/handle/ntb/43929
dc.language.isoen
dc.publisherLviv Politechnic Publishing House
dc.relation.ispartofChemistry & Chemical Technology, 1 (12), 2-18
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dc.rights.holder© Національний університет „Львівська політехніка“, 2018
dc.rights.holder© Zaichenko A., Mitina N., Miagkota O., Hevus O., Bilyi R., Stoika R., Payuk O., Nadashkevych Z., Voloshinovskii A., 2018
dc.subjectдисперсійна полімеризація
dc.subjectмакроіні- ціатори
dc.subjectкомпозиційні полімерні частинки
dc.subjectdispersion polymerization
dc.subjectmacroinitiators
dc.subjectcomposite polymer particles
dc.titleTarget synthesis of functional biocompatible nanocomposites with “core-shell” structure
dc.title.alternativeЦільовий синтезфункціональних біосумісних нанокомпозитів будови «ядро-оболонка»
dc.typeArticle

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