Synthesis of methanol from methane in cavitation field

Simple item page
dc.citation.epage73
dc.citation.issue1
dc.citation.spage69
dc.citation.volume12
dc.contributor.affiliationVolodymyr Dahl East Ukrainian National University
dc.contributor.affiliationJSC «ORGCHIM»
dc.contributor.authorTselishchev, Oleksii
dc.contributor.authorIjagbuji, Ayodeji
dc.contributor.authorLoriia, Maryna
dc.contributor.authorNosach, Vanadii
dc.coverage.placenameLviv
dc.date.accessioned2019-01-29T12:53:35Z
dc.date.available2019-01-29T12:53:35Z
dc.date.created2018-01-20
dc.date.issued2018-01-20
dc.description.abstractРозроблений спосіб синтезу метанолу за вільно-радикальним механізмом з використанням метану і гідроксильних радикалів. Метан та пероксид гідрогену подаються у кавітаційне поле. Головними продуктами реакції є метанол і вода. Розраховано ступінь перетворення метану, який дорівнює ~10 %.
dc.description.abstractMethanol synthesis was achieved by a free-radical mechanism of the compounding reaction of methane and hydroxyl radical. Experiments were performed by feeding methane and hydrogen-peroxide into a cavitation field. The major reaction products were methanol and water molecules. The calculated degree of methane conversion equals to ~10 %.
dc.format.extent69-73
dc.format.pages5
dc.identifier.citationSynthesis of methanol from methane in cavitation field / Oleksii Tselishchev, Ayodeji Ijagbuji, Maryna Loriia, Vanadii Nosach // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2-18. — Vol 12. — No 1. — P. 69–73.
dc.identifier.citationenSynthesis of methanol from methane in cavitation field / Oleksii Tselishchev, Ayodeji Ijagbuji, Maryna Loriia, Vanadii Nosach // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2-18. — Vol 12. — No 1. — P. 69–73.
dc.identifier.urihttps://ena.lpnu.ua/handle/ntb/43915
dc.language.isoen
dc.publisherLviv Politechnic Publishing House
dc.relation.ispartofChemistry & Chemical Technology, 1 (12), 2-18
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dc.relation.references[15] Tselischev A., Nosach V., KoshovetsM. et al.: Pat. UA104811 MEI G05D 19/00, Publ. Febr. 25, 2016.
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dc.relation.references[17] Tselischev A., Nosach V., KoshovetsM. et. al.: Pat. UA105427 MEI S10G 2/100, Publ. March 25, 2016.
dc.relation.references[18] Jiang H., Gong H., Yang Z. et al.: React. Kinetic Catal. Lett.,2002, 75, 315. https://doi.org/10.1023/A:1015207214720
dc.relation.references[19] Tselishchev A., LòriyaM., Eliseev P. et al.: East. Eur. J. Enterp. Technol., 2015, 6, 48.
dc.relation.references[20] Tselischev A., Elissev P., LòryiaM. et al.:Matematicheskoe Modelirovanie Technologicheskikh Protsessov. Vostochnoukr. Nats. Univ., Lugansk 2011.
dc.relation.referencesen[1] Imperial Chemical Industries (ICI). Methanol Synthesis Technology, London 1966.
dc.relation.referencesen[2] Dlugokencky E., Masarie K., Lang P. et al., Nature, 1998, 393,447. https://doi.org/10.1038/30934
dc.relation.referencesen[3] Crabtree R., Chem. Rev., 1995, 95, 987.https://doi.org/10.1021/cr00036a005
dc.relation.referencesen[4] Rozovskyy A., Lin G., Teoreticheskie Osnovy Processa Sinteza Metanola. Khimiya, Moskva 1990.
dc.relation.referencesen[5] Shilov A., Shul'pin G., Activation and Catalytic Reactions of Saturated Hydrocarbons in the Presence ofMetal Complexes [in:] Parkins A. (Ed.), Applied Organometallic Chemistry. Kluwer Academic Publishers, Dordrecht 2000.
dc.relation.referencesen[6] Rudakov E., Elektroliz v Neorganicheskoi Khimii. Naukova Dumka, Kiev 1985.
dc.relation.referencesen[7] Arutyunov V., Krylov E., Uspekhi Khimii, 2005, 74, 1216.https://doi.org/10.1070/RC2005v074n12ABEH001199
dc.relation.referencesen[8] Tselishchev A., Zakharov I., Loriya M. et al., Voprosy Khim. i Khim. Technol., 2012, 2, 39.
dc.relation.referencesen[9] Loriya M., Ijagbuji A., Tselischev A. et al., Adv. Mat. Res., 2013,660, 51. https://doi.org/10.4028/www.scientific.net/AMR.660.51
dc.relation.referencesen[10] Tselishchev A., LòriyaM., Zakharov I., Visnyk Kiev Polytech. Inst., 2011, 65, 111.
dc.relation.referencesen[11] Zakharov I., Ijagbuji A., Tselischev A. et al., J. Environ. Chem. Eng., 2015, 3, 405. https://doi.org/10.1016/j.jece.2014.08.008
dc.relation.referencesen[12] ZamilovM., Godin S., Quant. Potent. Corp., 2012, 1.
dc.relation.referencesen[13] Wang X., Wang J., GuoW. et al., J. Hazard. Mater, 2009, 169,486 – 491. https://doi.org/10.1016/j.jhazmat.2009.03.122
dc.relation.referencesen[14] Shah Y., Pandit A., Moholkar V., Cavitation Reaction Engineering. Kluwer Academic/Plenum Publ., New York 1999.https://doi.org/10.1007/978-1-4615-4787-7
dc.relation.referencesen[15] Tselischev A., Nosach V., KoshovetsM. et al., Pat. UA104811 MEI G05D 19/00, Publ. Febr. 25, 2016.
dc.relation.referencesen[16] Tselishchev A., Zakharov I., Loriya M. et al., Khim. Promysh. Ukrainy, 2014, 121, 39.
dc.relation.referencesen[17] Tselischev A., Nosach V., KoshovetsM. et. al., Pat. UA105427 MEI S10G 2/100, Publ. March 25, 2016.
dc.relation.referencesen[18] Jiang H., Gong H., Yang Z. et al., React. Kinetic Catal. Lett.,2002, 75, 315. https://doi.org/10.1023/A:1015207214720
dc.relation.referencesen[19] Tselishchev A., LòriyaM., Eliseev P. et al., East. Eur. J. Enterp. Technol., 2015, 6, 48.
dc.relation.referencesen[20] Tselischev A., Elissev P., LòryiaM. et al.:Matematicheskoe Modelirovanie Technologicheskikh Protsessov. Vostochnoukr. Nats. Univ., Lugansk 2011.
dc.relation.urihttps://doi.org/10.1038/30934
dc.relation.urihttps://doi.org/10.1021/cr00036a005
dc.relation.urihttps://doi.org/10.1070/RC2005v074n12ABEH001199
dc.relation.urihttps://doi.org/10.4028/www.scientific.net/AMR.660.51
dc.relation.urihttps://doi.org/10.1016/j.jece.2014.08.008
dc.relation.urihttps://doi.org/10.1016/j.jhazmat.2009.03.122
dc.relation.urihttps://doi.org/10.1007/978-1-4615-4787-7
dc.relation.urihttps://doi.org/10.1023/A:1015207214720
dc.rights.holder© Національний університет „Львівська політехніка“, 2018
dc.rights.holder© Tselishchev O., Ijagbuji A., Loriia M., Nosach V., 2018
dc.subjectактивація метану
dc.subjectгідроксильний радикал
dc.subjectметильний радикал
dc.subjectкавітація
dc.subjectсинтез метанолу
dc.subjectmethane activation
dc.subjecthydroxyl radical
dc.subjectmethyl radical
dc.subjectcavitation
dc.subjectmethanol synthesis
dc.titleSynthesis of methanol from methane in cavitation field
dc.title.alternativeСинтез метанолу з метану в кавітаційному полі
dc.typeArticle

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Chemistry & Chemical Technology. – 2018. – Vol. 12, No. 1