Interpenetrating network on the basis of methylcyclotetrasiloxane matrix

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dc.citation.epage70
dc.citation.issue1
dc.citation.spage64
dc.contributor.affiliationIv. Javakhishvili Tbilisi State University
dc.contributor.affiliationUniversity of Bialystok
dc.contributor.authorMukbaniani, Omari
dc.contributor.authorAneli, Jimsher
dc.contributor.authorPlonska-Brzezinska, Marta
dc.contributor.authorMarkarashvili, Eliza
dc.contributor.authorTatrishvili, Tamar
dc.coverage.placenameЛьвів
dc.coverage.placenameLviv
dc.date.accessioned2020-03-02T10:50:09Z
dc.date.available2020-03-02T10:50:09Z
dc.date.created2019-02-28
dc.date.issued2019-02-28
dc.description.abstractВивчено реакцію гідросилювання 2,4,6,8- тетрагідро-2,4,6,8-тетраметилциклотетрасилоксану (D4 H) алілтрифлуороацетату та вінілтриетоксисилану, у присут- ності платинових каталізаторів. З використанням Фур’є, 1H, 13C, та 29Si ЯМР спектроскопії проведено аналіз синтезованого продукту D4 R,R'. За допомогою соль-гелевих реакції систем D4 R,R', промотованих трифлуорометилсульфонатом літію (трифлат) одержано тверді полімерні електролітні мемб- рани. Встановлено, що електропровідність полімерних електролітних мембран за кімнатної температури змінюється в діапазоні (4·10-5)–(6·10-7) См/см.
dc.description.abstractHydrosilylation reaction of 2,4,6,8-tetrahydro- 2,4,6,8-tetramethylcyclotetra siloxane (D4 H) allyl trifluoroacetate and vinyltriethoxysilane catalysed by platinum catalysts has been studied.The synthesized D4 R,R' was analyzed with FTIR, 1H, 13C, and 29Si NMR spectroscopy. Via sol-gel reactions of D4 R,R' systems doped with lithium trifluoromethylsulfonate (triflate) solid polymer electrolyte membranes have been obtained. It has been found that the electric conductivity of the polymer electrolyte membranes at room temperature changes in the range of (4·10-5)–(6·10-7) S/cm.
dc.format.extent64-70
dc.format.pages7
dc.identifier.citationInterpenetrating network on the basis of methylcyclotetrasiloxane matrix / Omari Mukbaniani, Jimsher Aneli, Marta Plonska-Brzezinska, Eliza Markarashvili, Tamar Tatrishvili // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2019. — Vol 13. — No 1. — P. 64–70.
dc.identifier.citationenInterpenetrating network on the basis of methylcyclotetrasiloxane matrix / Omari Mukbaniani, Jimsher Aneli, Marta Plonska-Brzezinska, Eliza Markarashvili, Tamar Tatrishvili // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2019. — Vol 13. — No 1. — P. 64–70.
dc.identifier.urihttps://ena.lpnu.ua/handle/ntb/46415
dc.language.isoen
dc.publisherВидавництво Львівської політехніки
dc.publisherLviv Politechnic Publishing House
dc.relation.ispartofChemistry & Chemical Technology, 1 (13), 2019
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dc.relation.referencesen7. Fish D., Khan I., Wu E., Smid J., Polym. J., 1988, 20, 281. https://doi.org/10.1295/polymj.20.281
dc.relation.referencesen8. Spindler R., Shriver D.:Macromolecules, 1988, 21, 648. https://doi.org/10.1021/ma00181a019
dc.relation.referencesen9. Spindler R., Shriver D., J. Am. Chem. Soc., 1988, 110, 3036. https://doi.org/10.1021/ja00218a006
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dc.relation.urihttps://doi.org/10.1146/annurev.ms.16.080186.001333
dc.relation.urihttps://doi.org/10.1007/978-3-642-79175-8
dc.relation.urihttps://doi.org/10.1295/polymj.20.281
dc.relation.urihttps://doi.org/10.1021/ma0018446
dc.relation.urihttps://doi.org/10.1021/ma00061a010
dc.relation.urihttps://doi.org/10.1021/ma00181a019
dc.relation.urihttps://doi.org/10.1021/ja00218a006
dc.relation.urihttps://doi.org/10.1021/cm000420n
dc.relation.urihttps://doi.org/10.1016/S0013-4686(99)00300-X
dc.relation.urihttps://doi.org/10.1021/om990261l
dc.relation.urihttps://doi.org/10.1023/A:1020690025625
dc.relation.urihttps://doi.org/10.1002/masy.201350604
dc.relation.urihttps://doi.org/10.1515/epoly.2012.12.1.1023
dc.rights.holder© Національний університет „Львівська політехніка“, 2019
dc.rights.holder© Mukbaniani O., Aneli J., Plonska-Brzezinska M., Markarashvili E., Tatrishvili T., 2019
dc.subjectгідросилювання
dc.subjectсоль-гелеві реакції
dc.subjectспектроскопія
dc.subjectполімерна електролітна мембрана
dc.subjectелектропровідність
dc.subjecthydrosilylation
dc.subjectsol-gel reactions
dc.subjectspectroscopy
dc.subjectpolymer electrolyte membrane
dc.subjectelectric conductivity
dc.titleInterpenetrating network on the basis of methylcyclotetrasiloxane matrix
dc.title.alternativeВзаємопроникна сітка на основі метилциклотетрасилоксанової матриці
dc.typeArticle

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Chemistry & Chemical Technology. – 2019. – Vol. 13, No. 1