Oleochemical synthesis of sulfanes, their structure and properties

dc.citation.epage371
dc.citation.issue3
dc.citation.spage365
dc.citation.volume11
dc.contributor.affiliationInstitute of Bioorganic Chemistry and Petrochemistry of the National Academy of Sciences of Ukraine
dc.contributor.authorBodachivskyi, Iurii
dc.contributor.authorPop, Grigoriy
dc.contributor.authorZheleznyi, Leonid
dc.contributor.authorZubenko, Stepan
dc.contributor.authorOkhrimenko, Mykhailo
dc.coverage.placenameLviv
dc.date.accessioned2018-06-21T09:53:10Z
dc.date.available2018-06-21T09:53:10Z
dc.date.created2017-01-20
dc.date.issued2017-01-20
dc.description.abstractВперше внаслідок послідовної вулканізації алкілових естерів вищих жирних кислот ріпакової олії пероксидом бензоїлу та елементним сульфуром синтезовано олеохімічні сульфани. Методами інструментального аналізу встановлено їх будову і властивості. Показано, що олеохімічні сульфани – комлексні структури різного ступеню зшивання, характеризуються відмінними антиокиснювальними й трибо- логічними властивостями і не викликають корозії міді та сталі зажорстких умов тестування.
dc.description.abstractFor the first time, oleochemical sulfanes were synthesized via sequential vulcanization of fatty acid alkyl esters from rapeseed oil by benzoyl peroxide and elemental sulfur. Their structure and properties were established by the methods of instrumental analysis and it was shown that oleochemical sulfanes are complex structures with different cross-linking degrees, which provide excellent antioxidant and tribological characteristics and do not cause steel or copper corrosion under harsh test conditions.
dc.format.extent365-371
dc.format.pages7
dc.identifier.citationOleochemical synthesis of sulfanes, their structure and properties / Iurii Bodachivskyi, Grigoriy Pop, Leonid Zheleznyi, Stepan Zubenko, Mykhailo Okhrimenko // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2017. — Vol 11. — No 3. — P. 365–371.
dc.identifier.citationenOleochemical synthesis of sulfanes, their structure and properties / Iurii Bodachivskyi, Grigoriy Pop, Leonid Zheleznyi, Stepan Zubenko, Mykhailo Okhrimenko // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2017. — Vol 11. — No 3. — P. 365–371.
dc.identifier.urihttps://ena.lpnu.ua/handle/ntb/42088
dc.language.isoen
dc.publisherLviv Politechnic Publishing House
dc.relation.ispartofChemistry & Chemical Technology, 3 (11), 2017
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dc.relation.referencesen[1] Steudel R., Chem. Rev., 2002, 102, 3905. https://doi.org/10.1021/cr010127m
dc.relation.referencesen[2] Torbacke M., Rudolphi A., Kassfeldt E., Lubricants: Introduction to Properties and Performance. Wiley, Chichester 2014. https://doi.org/10.1002/9781118799734
dc.relation.referencesen[3] Cristano A., NLGI Spokesman, 2000, 64, 22.
dc.relation.referencesen[4] Rudnick L., Lubricant Additives: Chemistry and Application. CRC Press, New York 2010.
dc.relation.referencesen[5] Popov Y., Uskach Y, Ledenyov S. et al., Khim. i Technol. Topliv i Masel, 2014, 3, 17.
dc.relation.referencesen[6] Ledenyov S, Popov Y., Kroman D., Pavlova V., Khim. i Technol. Topliv i Masel, 2015, 5, 21.
dc.relation.referencesen[7] Krueger M., Byers J., Turchin H., Pat. EU 0656415A1, Publ. Jun. 07, 1995.
dc.relation.referencesen[8] Bodachivskyi Y., Pop G., Kataliz i Neftehimiya, 2014, 23, 27.
dc.relation.referencesen[9] Bodachivskyi Y., Pop G., Rogalskyi S., Kataliz i Neftehimiya, 2015, 24, 41.
dc.relation.referencesen[10] Armarego W., Chai C., Purification of Laboratory Chemicals. Elsevier Inc., Waltham 2013.
dc.relation.referencesen[11] Patrylak L., Patrylak K., Okhrimenko M. et al., Fuel, 2013, 113, 650. https://doi.org/10.1016/j.fuel.2013.06.020
dc.relation.referencesen[12] Zubenko S., Patrylak L., Kataliz i Neftehimiya, 2014, 23, 46.
dc.relation.referencesen[13] Frisch M., Trucks G., Schlegel H. et al., Gaussian 09, Revision A.02. Gaussian, Wallingford 2009.
dc.relation.referencesen[14] Ishchuk Yu., Technologia Plastichnyh Smazok. Naukova dumka, Kiev 1986.
dc.relation.referencesen[15] Antonovskyi V., Hursan S., Fizicheskaya Khimia Organicheskih Peroksidov. Akademkniga, Moskva 2003.
dc.relation.referencesen[16] Pretsch E., Buhlman P., Badertscher M., Structure Determination of Organic Compounds. Springer, Berlin 2009.
dc.relation.referencesen[17] Hofmann W., Vulkanizatsiya i Vulkanizuyuschiye Agenty. Khimiya, Moskva 1968.
dc.relation.referencesen[18] Zhaoa B., Wana P., Liua J. et al., Thermochimica Acta, 2012, 543, 232. https://doi.org/10.1016/j.tca.2012.05.029
dc.relation.referencesen[19] Lua K., Chena T., Hu K., J. Hazard. Mat., 2009, 161, 246. https://doi.org/10.1016/j.jhazmat.2008.03.078
dc.relation.referencesen[20] Lv J., Chen W., Chen L. et al., Proceed. AiChe Annual Meeting, USA, San Francisco 2013, 318455.
dc.relation.referencesen[21] Sun C., Yang S., Lin X. et al., Chem. Res. Chinese Univ., 2003, 19, 355.
dc.relation.referencesen[22] Wunderlich B., Thermal Analysis of Polymeric Materials. Springer, Berlin 2005.
dc.relation.urihttps://doi.org/10.1021/cr010127m
dc.relation.urihttps://doi.org/10.1002/9781118799734
dc.relation.urihttps://doi.org/10.1016/j.fuel.2013.06.020
dc.relation.urihttps://doi.org/10.1016/j.tca.2012.05.029
dc.relation.urihttps://doi.org/10.1016/j.jhazmat.2008.03.078
dc.rights.holder© Національний університет „Львівська політехніка“, 2017
dc.rights.holder© Bodachivskyi I., Pop G., Zheleznyi L., Zubenko S., Okhrimenko M., 2017
dc.subjectріпакова олія
dc.subjectорганічні сульфани
dc.subjectсинтез
dc.subjectмеханізми реакцій
dc.subjectдодатки до мастильних матеріалів
dc.subjectrapeseed oil
dc.subjectorganic sulfanes
dc.subjectsynthesis
dc.subjectreaction mechanisms
dc.subjectlubricant additives
dc.titleOleochemical synthesis of sulfanes, their structure and properties
dc.title.alternativeОлеохімічний синтез сульфанів, їх будова та властивості
dc.typeArticle

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