A preliminary investigation concerning metal oxides as catalysts for esterification of lauric acid with isopropanol

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dc.citation.epage166
dc.citation.issue2
dc.citation.journalTitleChemistry & Chemical Technology
dc.citation.spage158
dc.citation.volume12
dc.contributor.affiliationFederal University of Paraná
dc.contributor.authorKrause, Fernanda
dc.contributor.authorMaruyama, Swami Area
dc.contributor.authorWypych, Fernando
dc.coverage.placenameLviv
dc.date.accessioned2019-06-18T13:20:50Z
dc.date.available2019-06-18T13:20:50Z
dc.date.created2018-01-20
dc.date.issued2018-01-20
dc.description.abstractСинтезовано ізопропілаурат з викорис- танням як каталізатора суміші оксидів металів. Найвищу кон- версію отримано за таких умов: 393 К, молярне співвідно- шення ізопропанол:лауринова кислота 10:1, склад каталіза- тора 33 % CuO, 33 % Ag2O і 33 % Al2O3, співвідношення каталізатор/лауринова кислота становить 8 мас %, час реакції 2 год. Показано, що оксиди каталізатора після естерифікації не перетворюються в інші речовини.
dc.description.abstractThis paper reports the synthesis of isopropyl laurate while using a mixture of metal oxides as a catalyst. The best conversion value was obtained in the following conditions: 393 K, isopropanol:lauric acid molar ratio is10:1, composition of the catalyst is 33 % CuO, 33%Ag2O and 33 % Al2O3, catalyst/lauric acid ratio is 8%(w/w), and reaction time 2 h. Isolation of the catalysts after esterification showed that the oxides were not converted into other materials.
dc.format.extent158-166
dc.format.pages9
dc.identifier.citationKrause F. A preliminary investigation concerning metal oxides as catalysts for esterification of lauric acid with isopropanol / Fernanda Krause, Swami Area Maruyama, Fernando Wypych // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2018. — Vol 12. — No 2. — P. 158–166.
dc.identifier.citationenKrause F. A preliminary investigation concerning metal oxides as catalysts for esterification of lauric acid with isopropanol / Fernanda Krause, Swami Area Maruyama, Fernando Wypych // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2018. — Vol 12. — No 2. — P. 158–166.
dc.identifier.urihttps://ena.lpnu.ua/handle/ntb/45157
dc.language.isoen
dc.publisherLviv Politechnic Publishing House
dc.relation.ispartofChemistry & Chemical Technology, 2 (12), 2018
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dc.relation.referencesen[7] https://pubchem.ncbi.nlm.nih.gov/compound/1118#section=Toxicity
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dc.relation.referencesen[9] Sun J., Yang J., Li S. et al., Catal. Commun., 2016, 83, 35.https://doi.org/10.1016/j.catcom.2016.05.002
dc.relation.referencesen[10] Cordeiro C., Silva R., Wypych F. et al., Quim. Nova, 2011, 34,477. https://doi.org/10.1590/S0100-40422011000300021
dc.relation.referencesen[11]Maruyama S., Kanda L., Wypych F., J. Braz. Chem. Soc.,2017, 28, 985. https://doi.org/10.21577/0103-5053.20160251
dc.relation.referencesen[12]Wyckoff R., Am. J. Sci., 1922, 5, 184.https://doi.org/10.2475/ajs.s5-3.15.184
dc.relation.referencesen[13] Yong N., Ahmad A., Mohammad A., Int. J. Sci. Eng. Res.,2013, 4, 155.
dc.relation.referencesen[14] Isernia L.:Mater. Res., 2013, 16, 792.https://doi.org/10.1590/S1516-14392013005000044
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dc.relation.referencesen[16] Boumaza A., Djelloul A., Guerrab F., Powder Technol., 2010, 201, 177. https://doi.org/10.1016/j.powtec.2010.03.036
dc.relation.referencesen[17] SangappaM., Thiagarajan P., Indian J. Pharm. Sci., 2015, 77, 151.
dc.relation.referencesen[18] Azam A., Ahmed A., Oves M. et al., Int. J. Nanomed., 2012, 7, 3527. https://doi.org/10.2147/IJN.S29020
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dc.relation.urihttps://pubchem.ncbi.nlm.nih.gov/compound/25068
dc.relation.urihttp://www.panoleo.com/esters.html
dc.relation.urihttp://www.sigmaaldrich.com/catalog/
dc.relation.urihttps://doi.org/10.1016/j.saa.2016.07.006
dc.relation.urihttps://doi.org/10.1016/j.catcom.2014.10.033
dc.relation.urihttp://www.qca.ibilce.unesp.br/prevencao/produtos/acido_sulfurico.html
dc.relation.urihttps://pubchem.ncbi.nlm.nih.gov/compound/1118#section=Toxicity
dc.relation.urihttps://doi.org/10.1016/j.fuel.2016.05.078
dc.relation.urihttps://doi.org/10.1016/j.catcom.2016.05.002
dc.relation.urihttps://doi.org/10.1590/S0100-40422011000300021
dc.relation.urihttps://doi.org/10.21577/0103-5053.20160251
dc.relation.urihttps://doi.org/10.2475/ajs.s5-3.15.184
dc.relation.urihttps://doi.org/10.1590/S1516-14392013005000044
dc.relation.urihttps://doi.org/10.1016/j.powtec.2010.03.036
dc.relation.urihttps://doi.org/10.2147/IJN.S29020
dc.relation.urihttps://doi.org/10.1021/jp051577b
dc.relation.urihttps://doi.org/10.1016/j.biombioe.2010.10.035
dc.relation.urihttps://doi.org/10.1016/j.apcata.2008.10.053
dc.relation.urihttps://doi.org/10.1016/j.biortech.2015.06.079
dc.relation.urihttps://doi.org/10.1016/j.fuel.2015.03.021
dc.rights.holder© Національний університет „Львівська політехніка“, 2018
dc.rights.holder© Krause F., Maruyama S., Wypych F., 2018
dc.subjectоксид металу
dc.subjectізопропілаурат
dc.subjectесте- рифікація
dc.subjectлауринова кислота
dc.subjectізопропіловий спирт
dc.subjectmetal oxide
dc.subjectisopropyl laurate
dc.subjectesterification
dc.subjectlauric acid
dc.subjectisopropanol
dc.titleA preliminary investigation concerning metal oxides as catalysts for esterification of lauric acid with isopropanol
dc.title.alternativeДослідження оксидів металу, як каталізаторів естерифікації лауринової кислоти з ізопропанолом
dc.typeArticle

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Chemistry & Chemical Technology. – 2018. – Vol. 12, No. 2