Decomposition of tert-butyl hydroperoxide in the presence of selected initiators and catalysts

Simple item page
dc.citation.epage157
dc.citation.issue2
dc.citation.journalTitleChemistry & Chemical Technology
dc.citation.spage154
dc.citation.volume12
dc.contributor.affiliationLviv Polytechnic National University
dc.contributor.affiliationIvan Franko National University of Lviv
dc.contributor.affiliationLeibniz Institute for Catalysis at the University Rostock
dc.contributor.authorMakota, Oksana
dc.contributor.authorTrach, Yuriy
dc.contributor.authorSaldan, Ivan
dc.contributor.authorEvers, Eike
dc.contributor.authorKalevaru, Narayana
dc.contributor.authorMartin, Andreas
dc.coverage.placenameLviv
dc.date.accessioned2019-06-18T13:20:50Z
dc.date.available2019-06-18T13:20:50Z
dc.date.created2018-01-20
dc.date.issued2018-01-20
dc.description.abstractВивчено розклад трет-бутилового гідро- пероксиду в присутності ініціаторів (трет-бутилпероксид(tBuOOtBu), азодіізобутиронитрил (AIBN)) та каталізаторів(Mo2B5, MoB, Mo2B, MoSi2, VB2, VSi2). Показано, що введення радикалів може зменшити каталітичну активність. Запропоновано механізм початкової стадії розкладу трет- бутилового гідропероксиду та рівняння швидкості реакції.
dc.description.abstractTert-butyl hydroperoxide decomposition in the presence of initiators (tert-butyl peroxide (tBuOOtBu), azodiisobutyronitrile(AIBN)) and catalysts (Mo2B5, MoB,Mo2B, MoSi2, VB2, VSi2) was studied. Our experiments suggest that the introduction of radicals may reduce the catalytic activity. The mechanism of the initial stage of tert-butyl hydroperoxide decomposition and reaction rate equation are proposed.
dc.format.extent154-157
dc.format.pages4
dc.identifier.citationDecomposition of tert-butyl hydroperoxide in the presence of selected initiators and catalysts / Oksana Makota, Yuriy Trach, Ivan Saldan, Eike Evers, Narayana Kalevaru, Andreas Martin // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2018. — Vol 12. — No 2. — P. 154–157.
dc.identifier.citationenDecomposition of tert-butyl hydroperoxide in the presence of selected initiators and catalysts / Oksana Makota, Yuriy Trach, Ivan Saldan, Eike Evers, Narayana Kalevaru, Andreas Martin // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2018. — Vol 12. — No 2. — P. 154–157.
dc.identifier.urihttps://ena.lpnu.ua/handle/ntb/45156
dc.language.isoen
dc.publisherLviv Politechnic Publishing House
dc.relation.ispartofChemistry & Chemical Technology, 2 (12), 2018
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dc.relation.referencesen[1] Weissermel K., Arpe H.-J., Industrial Organic Chemistry.Wiley-VCH, Weinheim 2003.
dc.relation.referencesen[2] Denisov E., Afanas’ev I., Oxidation and Antioxidants in Organic Chemistry and Biology. Taylor and Francis, Boca Raton, FL 2005.
dc.relation.referencesen[3] Denisov E., Denisova T., Pokidova T., Handbook of Free Radical Initiators. Wiley-VCH, Weinheim 2003.
dc.relation.referencesen[4] Rappoport Z., The Chemistry of Peroxides, v. 2. Wiley-VCH, Weinheim 2006.
dc.relation.referencesen[5] Kharlampidi Kh., Nurullina N., Batyrshin N. et al., Petrol. Chem., 2016, 56, 171. https://doi.org/10.1134/S0965544116020080
dc.relation.referencesen[6] Badra J., Fethi Kh., Raj B. et al., Phys. Chem. Chem. Phys.,2015, 17, 2421. https://doi.org/10.1039/P.4CP04322G
dc.relation.referencesen[7] Lam K.-Y., Davidson D., Hanson R., J. Phys. Chem., 2012, 116,5549. https://doi.org/10.1021/jp303853h
dc.relation.referencesen[8] Tirso L.-A., Mercedes B., Chouzier P. et al., J. Catal., 2016, 344,334. https://doi.org/10.1016/j.jcat.2016.09.032
dc.relation.referencesen[9] Elwardany A., Es-sebbar A., Khaled Et. et al., Fuel, 2016, 166,245. https://doi.org/10.1016/j.fuel.2015.10.098
dc.relation.referencesen[10] Blackmond D., Angew. Chem. Int. Ed., 2005, 44, 4302.https://doi.org/10.1002/anie.200462544
dc.relation.referencesen[11] Chorkendorff I., Niemantsverdriet J., Concept ofModern Catalysis and Kinetics.:Wiley–VCH, Weinheim 2003.
dc.relation.referencesen[12]Milas N., Surgenor D., J. Am. Chem. Soc., 1946, 68, 205.https://doi.org/10.1021/ja01206a017
dc.relation.referencesen[13] Trach Yu., Makota O., NikipanchukM. et al., Neftekhimia,2003, 43, 424.
dc.relation.referencesen[14] Emanuel N., Maizus Z., Skibida I., Angew. Chem. Int. Ed.,1969, 8, 97. https://doi.org/10.1002/anie.196900971
dc.relation.referencesen[15] Rothenberg G., Wiener H., Sasson Y., J. Mol. Catal. A: Chem.,1998, 136, 253. https://doi.org/10.1016/S1381-1169(98)00070-3
dc.relation.referencesen[16] Barton D., Le Gloahec V., Patin H. et al., New J. Chem., 1998,22, 559. https://doi.org/10.1039/A709266K
dc.relation.referencesen[17]MacFaul P., Arends I., Ingold K. et al., J. Chem. Soc., Perkin Trans., 1997, 2, 135. https://doi.org/10.1039/A606160E
dc.relation.urihttps://doi.org/10.1134/S0965544116020080
dc.relation.urihttps://doi.org/10.1039/C4CP04322G
dc.relation.urihttps://doi.org/10.1021/jp303853h
dc.relation.urihttps://doi.org/10.1016/j.jcat.2016.09.032
dc.relation.urihttps://doi.org/10.1016/j.fuel.2015.10.098
dc.relation.urihttps://doi.org/10.1002/anie.200462544
dc.relation.urihttps://doi.org/10.1021/ja01206a017
dc.relation.urihttps://doi.org/10.1002/anie.196900971
dc.relation.urihttps://doi.org/10.1016/S1381-1169(98)00070-3
dc.relation.urihttps://doi.org/10.1039/A709266K
dc.relation.urihttps://doi.org/10.1039/A606160E
dc.rights.holder© Національний університет „Львівська політехніка“, 2018
dc.rights.holder© Makota O., Trach Y., Saldan I., Evers E., Kalevaru N., Martin A., 2018
dc.subjectгідропероксид
dc.subjectреакція розкладу
dc.subjectгетерогенний каталіз
dc.subjecthydroperoxide
dc.subjectdecomposition reaction
dc.subjectheterogeneous catalysis
dc.titleDecomposition of tert-butyl hydroperoxide in the presence of selected initiators and catalysts
dc.title.alternativeРозклад трет-бутилгідропероксиду у присутності вибраних ініціаторів та каталізаторів
dc.typeArticle

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Chemistry & Chemical Technology. – 2018. – Vol. 12, No. 2