Synthesis and Characterization of Mixed Al,Cu-Pillared and Copper Doped Al-Pillared Bentonite

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dc.citation.epage235
dc.citation.issue2
dc.citation.spage231
dc.contributor.affiliationShahid Bahonar University of Kerman
dc.contributor.affiliationInternational Center of High Technology & Environmental Science
dc.contributor.authorRavari, Maryam Hamidi
dc.contributor.authorSarrafi, Amir
dc.contributor.authorTahmooresi, Majid
dc.coverage.placenameЛьвів
dc.coverage.placenameLviv
dc.date.accessioned2020-03-02T12:28:07Z
dc.date.available2020-03-02T12:28:07Z
dc.date.created2019-02-28
dc.date.issued2019-02-28
dc.description.abstractЗ використанням зразка бентоніту одер- жано суміші глин, зшитих алюмінієм та міддю (Al, Cu-PILCs) з різним відсотком Cu та імпрегнованих алюмінієм (Cu@Al- PILC). Характеристику зразків проведено за допомогою рентгенівської дифракції, адсорбції-десорбції N2 та Фур‘є- спектроскопії. Визначено, що площа поверхні за БЕТ, загальна площа та об‘єм мікропор Al-PILC зменшуються в Cu@Al- PILC, проте збільшуються у випадку змішаних металів і досягають максимуму для Al, Cu-PILCs. Встановлено, що найвищий вміст міді є в Cu@Al-PILC, тому його каталітичні властивості покращуються. Фур‘є-спектроскопією підтверд- жено введення міді в структуру Al, Cu-PILCs.
dc.description.abstractIn this paper, mixed aluminum and copper pillared clays (Al,Cu-PILCs) with different percentage of Cu and copper impregnated aluminum pillared clay (Cu@Al-PILC) were prepared using a bentonite sample. The samples were characterized by X-ray diffraction, N2 adsorption-desorption and Fourier transformed infrared spectroscopy. The results showed bentonite had a main reflection of montmorillonite that characterized by basal spacing, increased by pillaring. The specific BET surface area, total surface area and micropore volume of Al-PILC decreased in Cu@Al-PILC but increased in the case of mixed metal pillars and the maximum of these parameters related to Al,Cu15-PILC. Maximum weight percentage of copper was in Cu@Al-PILC therefore it contained higher percent of copper and its catalytic properties increased. FTIR result of samples confirmed the successful intercalation of Cu.
dc.format.extent231-235
dc.format.pages5
dc.identifier.citationRavari M. H. Synthesis and Characterization of Mixed Al,Cu-Pillared and Copper Doped Al-Pillared Bentonite / Maryam Hamidi Ravari, Amir Sarrafi, Majid Tahmooresi // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2019. — Vol 13. — No 2. — P. 231–235.
dc.identifier.citationenRavari M. H. Synthesis and Characterization of Mixed Al,Cu-Pillared and Copper Doped Al-Pillared Bentonite / Maryam Hamidi Ravari, Amir Sarrafi, Majid Tahmooresi // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2019. — Vol 13. — No 2. — P. 231–235.
dc.identifier.urihttps://ena.lpnu.ua/handle/ntb/46461
dc.language.isoen
dc.publisherВидавництво Львівської політехніки
dc.publisherLviv Politechnic Publishing House
dc.relation.ispartofChemistry & Chemical Technology, 2 (13), 2019
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dc.relation.urihttps://doi.org/10.1080/01614940.2014.904182
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dc.relation.urihttps://doi.org/10.1016/j.molstruc.2015.10.072
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dc.relation.urihttps://doi.org/10.1016/j.crci.2015.08.004
dc.relation.urihttps://doi.org/10.1016/j.cattod.2007.03.041
dc.relation.urihttps://doi.org/10.1016/S0926-3373(98)00083-6
dc.relation.urihttps://doi.org/10.1016/j.micromeso.2007.05.011
dc.relation.urihttps://doi.org/10.1016/j.ccr.2012.03.010
dc.relation.urihttps://doi.org/10.1007/978-1-4020-2303-3_9
dc.relation.urihttps://doi.org/10.1016/0021-9517(65)90307-6
dc.relation.urihttps://doi.org/10.1016/j.jiec.2012.11.018
dc.relation.urihttps://doi.org/10.4236/jsemat.2013.34037
dc.rights.holder© Національний університет „Львівська політехніка“, 2019
dc.rights.holder© Hamidi RavariM., Sarrafi A., Tahmooresi M., 2019
dc.subjectалюміній
dc.subjectбентоніт
dc.subjectмідь
dc.subjectзшиті глини
dc.subjectaluminum
dc.subjectbentonite
dc.subjectcopper
dc.subjectpillared clays
dc.titleSynthesis and Characterization of Mixed Al,Cu-Pillared and Copper Doped Al-Pillared Bentonite
dc.title.alternativeСинтез та характеристика суміші Al,Cu-зшитого і промотованого міддю бентоніту
dc.typeArticle

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Chemistry & Chemical Technology. – 2019. – Vol. 13, No. 2