Thermodynamic properties of solubility of 2-methyl-5-arylfuran-3-carboxylic acids in organic solvents

Simple item page
dc.citation.epage404
dc.citation.issue4
dc.citation.spage397
dc.citation.volume11
dc.contributor.affiliationLviv Polytechnic National University
dc.contributor.affiliationIvan Franko National University of Lviv
dc.contributor.affiliationInstitute of Macromolecular Chemistry AS CR
dc.contributor.authorSobechko, Iryna
dc.contributor.authorDibrivnyi, Volodymyr
dc.contributor.authorHorak, Yuri
dc.contributor.authorVelychkivska, Nadiia
dc.contributor.authorKochubei, Victoriia
dc.contributor.authorObushak, Mykola
dc.coverage.placenameLviv
dc.date.accessioned2018-06-22T13:26:09Z
dc.date.available2018-06-22T13:26:09Z
dc.date.created2017-01-20
dc.date.issued2017-01-20
dc.description.abstractДосліджені температурні залежності роз- чинності обох кислот в ацетонітрилі, диметилкетоні, ізо-про- панолі, етилацетаті та бензені. Результати представлені ліній- ною формою рівняння Шредера, за яким визначені ентальпії, ентропії та енергії Гіббса розчинності за 298 К. Теплоти плавлення кислот визначені методом диференційно-термічного аналізу, за якими розраховані ентальпії, ентропії та енергії Гіббса змішування. Виявлений компенсаційний ефект змішування для всіх розчинників, що містять карбонільну групу.
dc.description.abstractThe temperature dependencies of both acids solubility in acetonitrile, dimethylketone, isopropanol, ethylacetate and benzene were investigated. The results were represented by Shredder’s equation according to which enthalpies, entropies and Gibbs energy of solubility at 298 K were determined. Fusion heats of the acids were determined using differential thermal analysis. In accordance with obtained values the enthalpies, entropies and Gibbs energy of mixing were calculated. The compensating effect of mixing was observed for al solvents with carboxy group.
dc.format.extent397-404
dc.format.pages8
dc.identifier.citationThermodynamic properties of solubility of 2-methyl-5-arylfuran-3-carboxylic acids in organic solvents / Iryna Sobechko, Volodymyr Dibrivnyi, Yuri Horak, Nadiia Velychkivska, Victoriia Kochubei, Mykola Obushak // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2017. — Vol 11. — No 4. — P. 397–404.
dc.identifier.citationenThermodynamic properties of solubility of 2-methyl-5-arylfuran-3-carboxylic acids in organic solvents / Iryna Sobechko, Volodymyr Dibrivnyi, Yuri Horak, Nadiia Velychkivska, Victoriia Kochubei, Mykola Obushak // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2017. — Vol 11. — No 4. — P. 397–404.
dc.identifier.urihttps://ena.lpnu.ua/handle/ntb/42103
dc.language.isoen
dc.publisherLviv Politechnic Publishing House
dc.relation.ispartofChemistry & Chemical Technology, 4 (11), 2017
dc.relation.references[1] Fürstner A., Castanet A., Radkowski K., Lehmann C.: J. Org. Chem., 2003, 68, 1521. https://doi.org/10.1021/jo026686q
dc.relation.references[2] Holla B., Akberali P., ShivanandaM.: Farmaco, 2000, 55, 256.https://doi.org/10.1016/S0014-827X(00)00030-6
dc.relation.references[3]Williams D., LeeM.-R., Song Y.-A. et al.: J. Am. Chem. Soc.,2007, 129, 9258. https://doi.org/10.1021/ja072817z
dc.relation.references[4] Obushak N., Gorak Yu., Matiichuk V., Lytvyn R.: Russ. J. Org. Chem., 2008, 44, 1689.https://doi.org/10.1134/S1070428008110213
dc.relation.references[5] Obushak N., Gorak Yu., Matiichuk V., Lytvyn R.: Russ. J. Org. Chem., 2009, 45, 541. https://doi.org/10.1134/S1070428009090103
dc.relation.references[6] Obushak N., Lesyuk A., Gorak Yu., Matiichuk V.: Russ. J. Org. Chem., 2009, 45, 1375.https://doi.org/10.1134/S1070428009090103
dc.relation.references[7] Obushak N., Lesyuk A., Ganushchak N. et al.: J. Org. Chem. USSR (Engl. Transl.), 1986, 22, 2093.
dc.relation.references[8] Obushak N., Ganushchak N., Lesyuk A. et al.: J. Org. Chem. USSR (Engl. Transl.), 1990, 26, 748.
dc.relation.references[9] Zhu J., Bienayme H. (Eds.):Multicomponent Reactions. Wiley- VCH, Weinheim 2005.
dc.relation.references[10] Sobechko I., Van-Chin-Syan Yu., Gorak Yu. et al.: Rus. J. Phys. Chem., 2015, 89, 919.https://doi.org/10.1134/S003602441506028X
dc.relation.references[11] Sobechko I., Gorak Yu., Van-Chin-Syan Yu. et al.: Izv. Vys. Ucheb. Zaved., 2015, 58, 45.
dc.relation.references[12] Sobechko I., Prokop R., Gorak Yu. et al.: Voprosy Khimii i Khim. Techn., 2013, 4, 12.
dc.relation.references[13] Sobechko I.: Voprosy Khimii i Khim. Techn., 2014, 5-6, 48.
dc.relation.references[14] Serheyev V.: Chem. Chem. Technol., 2012, 6, 15.
dc.relation.references[15] Serheyev V.: Chem. Chem. Technol., 2015, 9, 1.
dc.relation.references[16] Serheyev V.: Rus. J. Phys. Chem., 2016, 90, 575.https://doi.org/10.1134/S0036024416030274
dc.relation.references[17] Han S., Meng L., Du C. et al.: J. Chem. Thermodyn., 2017, 97, 17. https://doi.org/10.1016/j.jct.2015.11.025
dc.relation.references[18] Li X., Du C., Cong Y., Zhao H.: J. Chem. Thermodyn., 2017,104, 189. https://doi.org/10.1016/j.jct.2016.09.033
dc.relation.references[19] Chickos J., Acree W. Jr.: J. Phys. Chem. Ref. Data, 2003, 32,519. https://doi.org/10.1063/1.1529214
dc.relation.references[20] http://webbook.nist.gov (March 18th, 2015)
dc.relation.references[21] Vasil’ev I., Petrov V.: Thermodynamicheskie Svoistva Kislorod-soderzhashih Organicheskih Veshestv. Khimiya,Leningrad 1984.
dc.relation.referencesen[1] Fürstner A., Castanet A., Radkowski K., Lehmann C., J. Org. Chem., 2003, 68, 1521. https://doi.org/10.1021/jo026686q
dc.relation.referencesen[2] Holla B., Akberali P., ShivanandaM., Farmaco, 2000, 55, 256.https://doi.org/10.1016/S0014-827X(00)00030-6
dc.relation.referencesen[3]Williams D., LeeM.-R., Song Y.-A. et al., J. Am. Chem. Soc.,2007, 129, 9258. https://doi.org/10.1021/ja072817z
dc.relation.referencesen[4] Obushak N., Gorak Yu., Matiichuk V., Lytvyn R., Russ. J. Org. Chem., 2008, 44, 1689.https://doi.org/10.1134/S1070428008110213
dc.relation.referencesen[5] Obushak N., Gorak Yu., Matiichuk V., Lytvyn R., Russ. J. Org. Chem., 2009, 45, 541. https://doi.org/10.1134/S1070428009090103
dc.relation.referencesen[6] Obushak N., Lesyuk A., Gorak Yu., Matiichuk V., Russ. J. Org. Chem., 2009, 45, 1375.https://doi.org/10.1134/S1070428009090103
dc.relation.referencesen[7] Obushak N., Lesyuk A., Ganushchak N. et al., J. Org. Chem. USSR (Engl. Transl.), 1986, 22, 2093.
dc.relation.referencesen[8] Obushak N., Ganushchak N., Lesyuk A. et al., J. Org. Chem. USSR (Engl. Transl.), 1990, 26, 748.
dc.relation.referencesen[9] Zhu J., Bienayme H. (Eds.):Multicomponent Reactions. Wiley- VCH, Weinheim 2005.
dc.relation.referencesen[10] Sobechko I., Van-Chin-Syan Yu., Gorak Yu. et al., Rus. J. Phys. Chem., 2015, 89, 919.https://doi.org/10.1134/S003602441506028X
dc.relation.referencesen[11] Sobechko I., Gorak Yu., Van-Chin-Syan Yu. et al., Izv. Vys. Ucheb. Zaved., 2015, 58, 45.
dc.relation.referencesen[12] Sobechko I., Prokop R., Gorak Yu. et al., Voprosy Khimii i Khim. Techn., 2013, 4, 12.
dc.relation.referencesen[13] Sobechko I., Voprosy Khimii i Khim. Techn., 2014, 5-6, 48.
dc.relation.referencesen[14] Serheyev V., Chem. Chem. Technol., 2012, 6, 15.
dc.relation.referencesen[15] Serheyev V., Chem. Chem. Technol., 2015, 9, 1.
dc.relation.referencesen[16] Serheyev V., Rus. J. Phys. Chem., 2016, 90, 575.https://doi.org/10.1134/S0036024416030274
dc.relation.referencesen[17] Han S., Meng L., Du C. et al., J. Chem. Thermodyn., 2017, 97, 17. https://doi.org/10.1016/j.jct.2015.11.025
dc.relation.referencesen[18] Li X., Du C., Cong Y., Zhao H., J. Chem. Thermodyn., 2017,104, 189. https://doi.org/10.1016/j.jct.2016.09.033
dc.relation.referencesen[19] Chickos J., Acree W. Jr., J. Phys. Chem. Ref. Data, 2003, 32,519. https://doi.org/10.1063/1.1529214
dc.relation.referencesen[20] http://webbook.nist.gov (March 18th, 2015)
dc.relation.referencesen[21] Vasil’ev I., Petrov V., Thermodynamicheskie Svoistva Kislorod-soderzhashih Organicheskih Veshestv. Khimiya,Leningrad 1984.
dc.relation.urihttps://doi.org/10.1021/jo026686q
dc.relation.urihttps://doi.org/10.1016/S0014-827X(00)00030-6
dc.relation.urihttps://doi.org/10.1021/ja072817z
dc.relation.urihttps://doi.org/10.1134/S1070428008110213
dc.relation.urihttps://doi.org/10.1134/S1070428009090103
dc.relation.urihttps://doi.org/10.1134/S003602441506028X
dc.relation.urihttps://doi.org/10.1134/S0036024416030274
dc.relation.urihttps://doi.org/10.1016/j.jct.2015.11.025
dc.relation.urihttps://doi.org/10.1016/j.jct.2016.09.033
dc.relation.urihttps://doi.org/10.1063/1.1529214
dc.relation.urihttp://webbook.nist.gov
dc.rights.holder© Національний університет „Львівська політехніка“, 2017
dc.rights.holder© Sobechko I., Dibrivnyi V., Horak Y., Velychkivska N., Kochubei V., Obushak M., 2017
dc.subjectентальпія
dc.subjectентропія та енергія Гіббса розчинності
dc.subjectзмішування і плавлення
dc.subject2-метил-5-фенілфуран-3- карбонова кислота та 2-метил-5-(4-метилфеніл)-фуран-3- карбонова кислота
dc.subjectenthalpy
dc.subjectentropy
dc.subjectGibbs energy of solubility
dc.subjectmixing and fusion
dc.subject2-methyl-5-phenylfuran-3-carboxylic acid
dc.subject2-methyl-5-(4-methylphenyl)-furan-3-carboxylic acid
dc.titleThermodynamic properties of solubility of 2-methyl-5-arylfuran-3-carboxylic acids in organic solvents
dc.title.alternativeТермодинамічні властивості розчинності 2-метил-5-арилфуран-3-карбонових кислот в органічних розчинниках
dc.typeArticle

Files

Original bundle

Now showing 1 - 2 of 2
Thumbnail Image
Name:
2017v11n4_Sobechko_I-Thermodynamic_properties_397-404.pdf
Size:
432.56 KB
Format:
Adobe Portable Document Format
Download
Thumbnail Image
Name:
2017v11n4_Sobechko_I-Thermodynamic_properties_397-404__COVER.png
Size:
495.46 KB
Format:
Portable Network Graphics
Download

License bundle

Now showing 1 - 1 of 1
No Thumbnail Available
Name:
license.txt
Size:
3.03 KB
Format:
Plain Text
Description:
Download

Collections

Chemistry & Chemical Technology. – 2017. – Vol. 11, No. 4