Proton-initiated conversion of dithiocarbamates of 9,10-anthracenedione

Simple item page
dc.citation.epage304
dc.citation.issue3
dc.citation.journalTitleChemistry & Chemical Technology
dc.citation.spage300
dc.citation.volume12
dc.contributor.affiliationLviv Polytechnic National University
dc.contributor.affiliationInstitute of Organic Chemistry of National Academy of Sciences of Ukraine
dc.contributor.authorStasevych, Maryna
dc.contributor.authorZvarych, Viktor
dc.contributor.authorKhomyak, Semen
dc.contributor.authorLunin, Volodymyr
dc.contributor.authorKopak, Nazarii
dc.contributor.authorNovikov, Volodymyr
dc.contributor.authorVovk, Mykhailo
dc.coverage.placenameLviv
dc.date.accessioned2019-06-20T11:19:51Z
dc.date.available2019-06-20T11:19:51Z
dc.date.created2018-01-20
dc.date.issued2018-01-20
dc.description.abstractДосліджено протон-ініційоване перетво- рення дитіокарбаматних похідних 9,10-антрацендіону за умов кислотно-каталізованої циклодегідратації при дії суміші H2SO4-АсОН та подальшому обробленні перхлоратною кислотою. На основі даних спектральних методів (1Н, 13С ЯМР, ІЧ-, УФ-спектроскопії) встановлено, що реакція зупи- няється на стадії протонування атома Сульфуру тіокар- бонільної групи з утворенням перхлоратних солей. УФ спектри одержаних перхлоратів характеризуються гіпсохромним зсувом з чітко вираженим максимумом поглинання.
dc.description.abstractProton-initiated conversion of dithiocarbamate derivatives of the 9,10-anthracenedione under conditions of acid-catalyzed cyclodehydration using the action of a mixture of H2SO4-AcOH and further treatment with perchloric acid was investigated. Based on the data of the spectral methods (1H, 13C NMR, IR, UV spectroscopy), it is established that the reaction stops at the stage of protonation of the sulfur atom of the thiocarbonyl group with the formation of perchlorates. The UV spectra of the obtained perchlorates are characterized by a hypochromic shift with a clearly pronounced absorption maximum.
dc.format.extent300-304
dc.format.pages5
dc.identifier.citationProton-initiated conversion of dithiocarbamates of 9,10-anthracenedione / Maryna Stasevych, Viktor Zvarych, Semen Khomyak, Volodymyr Lunin, Nazarii Kopak, Volodymyr Novikov, Mykhailo Vovk // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2018. — Vol 12. — No 3. — P. 300–304.
dc.identifier.citationenProton-initiated conversion of dithiocarbamates of 9,10-anthracenedione / Maryna Stasevych, Viktor Zvarych, Semen Khomyak, Volodymyr Lunin, Nazarii Kopak, Volodymyr Novikov, Mykhailo Vovk // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2018. — Vol 12. — No 3. — P. 300–304.
dc.identifier.urihttps://ena.lpnu.ua/handle/ntb/45186
dc.language.isoen
dc.publisherLviv Politechnic Publishing House
dc.relation.ispartofChemistry & Chemical Technology, 3 (12), 2018
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dc.relation.referencesen[1] GorelikM., Khimiya Antrakhinonov i ikh Proizvodnykh. Khimiya, Moskva 1983.
dc.relation.referencesen[2]Malik E., Müller C.:Med. Res. Rev., 2016, 36, 705.https://doi.org/10.1002/med.21391
dc.relation.referencesen[3] Baqi Y., Müller C., Tetrahedron Lett., 2012, 53, 6739.https://doi.org/10.1016/j.tetlet.2012.09.011
dc.relation.referencesen[4] Aly A., Brown A., Bedai T., Ishak E., J. Sulfur Chem., 2012, 33,605. https://doi.org/10.1080/17415993.2012.718349
dc.relation.referencesen[5] Zvarych V., Stasevych M., Lunin V. et al.:Monatsh. Chem.,2016, 147, 2093. https://doi.org/10.1007/s00706-016-1839-y
dc.relation.referencesen[6] Zvarych V., Stasevych M., Lunin V. et al., Rus. J. Gen. Chem.,2016, 86, 2699. https://doi.org/10.1134/S1070363216120227
dc.relation.referencesen[7] Halenova T., Nikolaeva I., Stasevych M. et al., Res. J. Pharm. Biol. Chem. Sci., 2017, 8, 1626.
dc.relation.referencesen[8] StasevychM., Zvarych V., Lunin V. et al., SAR QSAR Environ. Res., 2017, 28, 355. https://doi.org/10.1080/1062936X.2017.1323796
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dc.relation.referencesen[11] Kratochvil N., NeprasM., Collect. Czechoslovak Chem. Comm. 1972, 37, 1533. https://doi.org/10.1135/cccc19721533
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dc.relation.referencesen[13] Axhausen J., Ruhl G., Kornath A., Z. Naturforsch., 2012, 67b,1235. https://doi.org/10.5560/ZNB.2012-0232
dc.relation.referencesen[14] Vandebeek R., Joris S., Aspila K., Chakraba C., J. Can. Chem.,1970, 48, 2204. https://doi.org/10.1139/v70-368
dc.relation.referencesen[15] ShankaranarayanaM., Patel C., Acta Chem. Scand., 1965, 19,1113. https://doi.org/10.3891/acta.chem.scand.19-1113
dc.relation.urihttps://doi.org/10.1002/med.21391
dc.relation.urihttps://doi.org/10.1016/j.tetlet.2012.09.011
dc.relation.urihttps://doi.org/10.1080/17415993.2012.718349
dc.relation.urihttps://doi.org/10.1007/s00706-016-1839-y
dc.relation.urihttps://doi.org/10.1134/S1070363216120227
dc.relation.urihttps://doi.org/10.1080/1062936X.2017.1323796
dc.relation.urihttps://doi.org/10.3762/bjoc.8.226
dc.relation.urihttps://doi.org/10.1135/cccc19721533
dc.relation.urihttps://doi.org/10.5560/ZNB.2012-0232
dc.relation.urihttps://doi.org/10.1139/v70-368
dc.relation.urihttps://doi.org/10.3891/acta.chem.scand.19-1113
dc.rights.holder© Національний університет „Львівська політехніка“, 2018
dc.rights.holder©Stasevych M., Zvarych V., Khomyak S., Lunin V., Kopak N., Novikov V., Vovk M., 2018
dc.subject9 10-антрацендіон
dc.subjectдитіокарбамати
dc.subjectкислотно-каталізована циклодегідратація
dc.subjectперхлорати
dc.subjectспектральні дослідження
dc.subject9 10-anthracenedione
dc.subjectdithiocarbamates
dc.subjectacidcatalyzed cyclodehydration
dc.subjectperchlorates
dc.subjectspectroscopic studies
dc.titleProton-initiated conversion of dithiocarbamates of 9,10-anthracenedione
dc.title.alternativeПротон-ініційоване перетворення дитіокарбаматів 9,10-антрацендіону
dc.typeArticle

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Chemistry & Chemical Technology. – 2018. – Vol. 12, No. 3