Synthesis and characterization of mixed ligand complexes of zirconium(IV) with sulphur, nitrogen and oxygen donоr ligands

dc.citation.epage32
dc.citation.issue1
dc.citation.spage23
dc.contributor.affiliationG.L.A. University
dc.contributor.affiliationDeen Dayal Upadhyaya Gorakhpur University
dc.contributor.authorSrivastava, Abhishek
dc.contributor.authorSrivastava, Neetu
dc.contributor.authorNathTripathi, Umesh
dc.contributor.authorSiddiqui, Afshan
dc.coverage.placenameЛьвів
dc.coverage.placenameLviv
dc.date.accessioned2020-03-02T10:50:16Z
dc.date.available2020-03-02T10:50:16Z
dc.date.created2019-02-28
dc.date.issued2019-02-28
dc.description.abstractДосліджено новий спосіб синтезу нано- мірних змішаних лігандних комплексів Zr(IV) за реакцією хлориду цирконію(IV) з 3(2'-гідроксифеніл)-5-(4-заміщеним феніл) піразолінами та солями дитіофосфату амонію, який після оброблення H2S діє як прекурсор для ZrS2. За допомогою рентгено-дифракційного аналізу досліджено кристалічну/аморфну природу синтезованих комплексів. Визначено, що всі комплекси є аморфними твердими речо- винами. При визначенні молекулярної маси та проведенні елементарного аналізу і спектроскопічних дослідженнь (ІЧ, 1H ЯМР, 31P ЯМР) доведена димерна природа комплексів, в яких дитіофосфат та піразолін є бідентатним лігандом. З використанням скануючої електронної мікроскопії пока- зано, що частинки знаходяться в нанодіапазоні. Запропо- новано координаційне число 6 для цирконію з восьмигранною геометрією.
dc.description.abstractA new route to synthesize new nanosized mixed ligand complexes of Zr(IV) have been investigated by the reaction of zirconium(IV) chloride with 3(2'-hydroxyphenyl)-5-(4-substituted phenyl)pyrazolines and ammonium salts of dithiophosphate, which after being treated with H2S gas acts as a precursor for ZrS2. These complexes have been examined for crystalline/amorphous nature through XRD. The morphology of the complexes was studied by employing XRD which shows that all the complexes are amorphous solid. Molecular weight measurements, elemental analysis in conjugation with spectroscopic (IR, 1H NMR, 31P NMR) studies reveal dimeric nature of the complexes, in which dithiophosphate and pyrazoline are bidentate. Scanning electron microscopic images indicate that the particles are in a nano range. Putting all the facts together, coordination number six is proposed for zirconium with octahedral geometry.
dc.format.extent23-32
dc.format.pages10
dc.identifier.citationSynthesis and characterization of mixed ligand complexes of zirconium(IV) with sulphur, nitrogen and oxygen donоr ligands / Abhishek Srivastava, Neetu Srivastava, Umesh NathTripathi, Afshan Siddiqui // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2019. — Vol 13. — No 1. — P. 23–32.
dc.identifier.citationenSynthesis and characterization of mixed ligand complexes of zirconium(IV) with sulphur, nitrogen and oxygen donоr ligands / Abhishek Srivastava, Neetu Srivastava, Umesh NathTripathi, Afshan Siddiqui // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2019. — Vol 13. — No 1. — P. 23–32.
dc.identifier.urihttps://ena.lpnu.ua/handle/ntb/46427
dc.language.isoen
dc.publisherВидавництво Львівської політехніки
dc.publisherLviv Politechnic Publishing House
dc.relation.ispartofChemistry & Chemical Technology, 1 (13), 2019
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dc.relation.urihttps://doi.org/10.1021/ja4045289
dc.relation.urihttps://doi.org/10.1007/s11814-013-0140-6
dc.relation.urihttps://doi.org/10.1039/b903811f
dc.relation.urihttps://doi.org/10.5012/jkcs.2012.56.4.440
dc.relation.urihttps://doi.org/10.1051/jphyscol:1995557
dc.relation.urihttps://doi.org/10.1002/cvde.200506481
dc.relation.urihttps://doi.org/10.1016/j.matlet.2004.07.061
dc.relation.urihttps://doi.org/10.1039/C3DT52335G
dc.relation.urihttps://doi.org/10.1039/A901666J
dc.relation.urihttps://doi.org/10.1007/s11237-006-0034-3
dc.relation.urihttps://doi.org/10.1155/2013/903616
dc.relation.urihttps://doi.org/10.1016/j.ejmech.2006.03.020
dc.relation.urihttps://doi.org/10.1016/j.poly.2012.09.044
dc.relation.urihttps://doi.org/10.1039/C2DT31761C
dc.relation.urihttps://doi.org/10.1021/ja403170u
dc.relation.urihttps://doi.org/10.1002/pi.4450
dc.relation.urihttps://doi.org/10.1039/b911545e
dc.relation.urihttps://doi.org/10.1016/j.jdent.2007.07.008
dc.relation.urihttps://doi.org/10.1016/j.dental.2007.05.007
dc.relation.urihttps://doi.org/10.1080/01496395.2013.765472
dc.relation.urihttps://doi.org/10.1039/c3tb20127a
dc.relation.urihttps://doi.org/10.1016/j.jeurceramsoc.2003.11.004
dc.relation.urihttps://doi.org/10.1016/S0142-9612(98)00010-6
dc.relation.urihttps://doi.org/10.1302/0301-620X.87B12.16873
dc.relation.urihttps://doi.org/10.1039/c1ee01286j
dc.relation.urihttps://doi.org/10.1021/ja200400n
dc.relation.urihttps://doi.org/10.1080/00958970802326179
dc.relation.urihttps://doi.org/10.1080/03086648308073283
dc.rights.holder© Національний університет „Львівська політехніка“, 2019
dc.rights.holder© Srivastava A., Srivastava N., Tripathi U., Siddiqui A., 2019
dc.subjectцирконій(IV)
dc.subjectдитіофосфат
dc.subjectпіразолін
dc.subjectнаночастинка
dc.subjectсоль-гель
dc.subjectzirconium(IV)
dc.subjectdithiophosphate
dc.subjectpyrazoline
dc.subjectnanoparticle
dc.subjectsol-gel
dc.titleSynthesis and characterization of mixed ligand complexes of zirconium(IV) with sulphur, nitrogen and oxygen donоr ligands
dc.title.alternativeСинтез і характеристика змішаних лігандних комплексів цирконію(IV) з сульфур-, нітроген- та оксиген-донор лігандами
dc.typeArticle

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