Researches of amphiphilic properties of copolyesters with chromophore groups

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dc.citation.epage325
dc.citation.issue3
dc.citation.journalTitleChemistry & Chemical Technology
dc.citation.spage318
dc.citation.volume12
dc.contributor.affiliationLviv Polytechnic National University
dc.contributor.authorYakoviv, Mariia
dc.contributor.authorFihurka, Nataliia
dc.contributor.authorNosova, Nataliya
dc.contributor.authorSamaryk, Volodymyr
dc.contributor.authorVasylyshyn, Taras
dc.contributor.authorHermanovych, Svitlana
dc.contributor.authorVoronov, Stanislav
dc.contributor.authorVarvarenko, Sergiy
dc.coverage.placenameLviv
dc.date.accessioned2019-06-20T11:19:53Z
dc.date.available2019-06-20T11:19:53Z
dc.date.created2018-01-20
dc.date.issued2018-01-20
dc.description.abstractВизначено коефіцієнти розподілу макромолекул амінофункційних кополістерів з хро- мофорними групами в системі н-октанол-вода та експериментальні і розрахункові характеристики їх гідро- фільно-ліпофільного балансу(HLB). Проведено множинний регресійний аналіз та отримано інтерполяційне рівняння коефіцієнту ліпофільності від параметрів, які харак- теризують якісний та кількісний склад кополіестеру. Виявлено чинники, які мають найбільш суттєвий вплив на коефіцієнт ліпофільності та HLB одержаних флуо- ресцеїнвміснихкополіестерів.
dc.description.abstractThe distribution coefficients of macromolecules of aminofunctional copolyesters with chromophore groups in the n-octanol–water system, as well as experimental and calculated characteristics of their hydrophilic-lipophilic balance (HLB) have been determined. A multiple regression analysis has been carried out and interpolation equation of the lipophilicity coefficient has been derived depending on the parameters characterizing the qualitative and quantitative composition of the copolyester. The factors which have the most significant influence on the lipophilicity factor and HLB of the obtained fluorescein-containing copolyester have been established.
dc.format.extent318-325
dc.format.pages8
dc.identifier.citationResearches of amphiphilic properties of copolyesters with chromophore groups / Mariia Yakoviv, Nataliia Fihurka, Nataliya Nosova, Volodymyr Samaryk, Taras Vasylyshyn, Svitlana Hermanovych, Stanislav Voronov, Sergiy Varvarenko // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2018. — Vol 12. — No 3. — P. 318–325.
dc.identifier.citationenResearches of amphiphilic properties of copolyesters with chromophore groups / Mariia Yakoviv, Nataliia Fihurka, Nataliya Nosova, Volodymyr Samaryk, Taras Vasylyshyn, Svitlana Hermanovych, Stanislav Voronov, Sergiy Varvarenko // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2018. — Vol 12. — No 3. — P. 318–325.
dc.identifier.urihttps://ena.lpnu.ua/handle/ntb/45189
dc.language.isoen
dc.publisherLviv Politechnic Publishing House
dc.relation.ispartofChemistry & Chemical Technology, 3 (12), 2018
dc.relation.references[1] Zheng H., Zhan X.-Q., BianQ.-N., ZhangX.-J.: Chem. Commun., 2013, 49, 429. https://doi.org/10.1039/c2cc35997a
dc.relation.references[2] http://www.acdlabs.com/software/logp/logp_prediction_ software.php
dc.relation.references[3] Kazicina L., Kupletskaja N.: Primenenie UF-, IK-, JaMR- Spektroskopii v Organicheskoi Khimii. Vysshaja shkola, Moskva 1971.
dc.relation.references[4] Varvarenko S., Samaryk V., Vlizlo V. et al.: Polimernyi Zh.,2015, 37, 193.
dc.relation.references[5] Oleksa V., Nagorniak M., Chekh B. et al.: Polymer Complexes of Microelements Based on N-derivativesof L-glutamic Acid for Correction of Metabolism [in:] Krynski A., Tebug G., Voloshanska S. (Eds.), Ecology and Human Health. Czestochowa Int. Publ., Czestochowa 2018, 7-19.
dc.relation.references[6] Hansch C., Fujita T.: J. Am. Chem. Soc., 1964, 86, 1616.https://doi.org/10.1021/ja01062a035
dc.relation.references[7] Davies J.: A Quantitative Kinetic Theory of Emulsion Type. 1. Physical Chemistry of the Emulsifying Agent [in:] Gas/Liquid and Liquid/Liquid Interfaces, Proceed. of 2nd Int. Congr. Surface Activity. Butterworths, London 1957, 426.
dc.relation.references[8] Varvarenko S., Tarnavchyk I., Voronov A. et al.: Chem. Chem. Technol., 2013, 7, 164.
dc.relation.references[9] NagornyakM., Fihurka N., Samaryk V. et al.: Chem. Chem. Technol., 2016, 10, 423. https://doi.org/10.23939/chcht10.04.423
dc.relation.referencesen[1] Zheng H., Zhan X.-Q., BianQ.-N., ZhangX.-J., Chem. Commun., 2013, 49, 429. https://doi.org/10.1039/P.2cc35997a
dc.relation.referencesen[2] http://www.acdlabs.com/software/logp/logp_prediction_ software.php
dc.relation.referencesen[3] Kazicina L., Kupletskaja N., Primenenie UF-, IK-, JaMR- Spektroskopii v Organicheskoi Khimii. Vysshaja shkola, Moskva 1971.
dc.relation.referencesen[4] Varvarenko S., Samaryk V., Vlizlo V. et al., Polimernyi Zh.,2015, 37, 193.
dc.relation.referencesen[5] Oleksa V., Nagorniak M., Chekh B. et al., Polymer Complexes of Microelements Based on N-derivativesof L-glutamic Acid for Correction of Metabolism [in:] Krynski A., Tebug G., Voloshanska S. (Eds.), Ecology and Human Health. Czestochowa Int. Publ., Czestochowa 2018, 7-19.
dc.relation.referencesen[6] Hansch C., Fujita T., J. Am. Chem. Soc., 1964, 86, 1616.https://doi.org/10.1021/ja01062a035
dc.relation.referencesen[7] Davies J., A Quantitative Kinetic Theory of Emulsion Type. 1. Physical Chemistry of the Emulsifying Agent [in:] Gas/Liquid and Liquid/Liquid Interfaces, Proceed. of 2nd Int. Congr. Surface Activity. Butterworths, London 1957, 426.
dc.relation.referencesen[8] Varvarenko S., Tarnavchyk I., Voronov A. et al., Chem. Chem. Technol., 2013, 7, 164.
dc.relation.referencesen[9] NagornyakM., Fihurka N., Samaryk V. et al., Chem. Chem. Technol., 2016, 10, 423. https://doi.org/10.23939/chcht10.04.423
dc.relation.urihttps://doi.org/10.1039/c2cc35997a
dc.relation.urihttp://www.acdlabs.com/software/logp/logp_prediction_
dc.relation.urihttps://doi.org/10.1021/ja01062a035
dc.relation.urihttps://doi.org/10.23939/chcht10.04.423
dc.rights.holder© Національний університет „Львівська політехніка“, 2018
dc.rights.holder©Yakoviv M., Fihurka N., Nosova N., Samaryk V., Vasylyshyn T.,Hermanovych S., Voronov S., Varvarenko S., 2018
dc.subjectкоефіцієнт розподілу
dc.subjectгідрофільно- ліпофільний баланс
dc.subjectкополіестери
dc.subjectфлуоресцеїн
dc.subjectсистеми доставки ліків
dc.subjectdistribution coefficient
dc.subjecthydrophilic-lipophilic balance
dc.subjectcopolyester
dc.subjectfluorescein
dc.subjectdrug delivery systems
dc.titleResearches of amphiphilic properties of copolyesters with chromophore groups
dc.title.alternativeДослідження амфіфільних властивостей кополіестерів з хромофорними групами
dc.typeArticle

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Chemistry & Chemical Technology. – 2018. – Vol. 12, No. 3