The Intercalation Behaviour and Physico-Chemical Characterisation of Novel Intercalated Nanocomposite from Zinc/Aluminium Layered Double Hydroxides and Broadleaf Herbicide Clopyralid

dc.citation.epage46
dc.citation.issue1
dc.citation.spage38
dc.contributor.affiliationUniversity Pendidikan Sultan Idris
dc.contributor.affiliationUniversity Malaysia Terengganu
dc.contributor.affiliationUniversity Putra Malaysia
dc.contributor.authorSharif, Sharifah Norain Mohd
dc.contributor.authorHashim, Norhayati
dc.contributor.authorIsa, Illyas Md
dc.contributor.authorMamat, Mazidah
dc.contributor.authorAli, Noorshida Mohd
dc.contributor.authorBakar, Suriani Abu
dc.contributor.authorHussein, Mohd Zobir
dc.contributor.authorMustafar, Suzaliza
dc.coverage.placenameЛьвів
dc.coverage.placenameLviv
dc.date.accessioned2020-12-23T13:24:02Z
dc.date.available2020-12-23T13:24:02Z
dc.date.created2020-01-24
dc.date.issued2020-01-24
dc.description.abstractМетодом спільного осадження одержані нові нанокомпозити, що містять подвійний гідроксид цинку/алюмінію інтеркальований клопіралідом (Zn/Al-LDHCP). За допомогою порошкової дифракції (PXRD) підтверджено виникнення інтеркаляції. Встановлено, що результати Фур'є спектроскопії та елементного аналізу узгоджуються з результатами PXRD, та підтверджують інтеркаляцію клопіраліду. За допомогою термічних методів аналізу показано, що термічну стійкість нанокомпозиту є вищою у порівнянні з чистим клопіралідом. Запропонована хімічна формула нанокомпозиту [Zn0.75Al0.25 (OH) 2] [C5H2Cl2NCOO] -0.250.67H2O та розраховано вміст клопіраліду в Zn/Al-LDH (25,39 %). Приведені перспективи використання нового нанокомпозиту Zn/Al-LDH-CP.
dc.description.abstractThis study reports on the preparation of novel zinc/aluminium layered double hydroxide intercalated clopyralid (Zn/Al-LDH-CP) nanocomposites fabricated via co-precipitation. An expansion of the interlayer gallery of Zn/Al-LDH for the accommodation of clopyralid was observed from the powder X-ray diffraction (PXRD) pattern, confirming the occurrence of intercalation. The results from Fourier transform infrared and elemental analysis were consistent with those from PXRD, thus supporting the intercalation of clopyralid. The thermal studies showed that the nanocomposite had better thermal stability compared to pristine clopyralid. Based on these data, the chemical formula of the nanocomposite was proposed as [Zn0.75Al0.25(OH)2][C5H2Cl2NCOO]- 0.250.67H2O, and the percentage loading of clopyralid in the interlayer gallery of Zn/Al-LDH was calculated to be 25.39 %. These characterisation results indicate a very promising future for this novel Zn/Al-LDH-CP nanocomposite.
dc.format.extent38-46
dc.format.pages9
dc.identifier.citationThe Intercalation Behaviour and Physico-Chemical Characterisation of Novel Intercalated Nanocomposite from Zinc/Aluminium Layered Double Hydroxides and Broadleaf Herbicide Clopyralid / Sharifah Norain Mohd Sharif, Norhayati Hashim, Illyas Md Isa, Mazidah Mamat, Noorshida Mohd Ali, Suriani Abu Bakar, Mohd Zobir Hussein, Suzaliza Mustafar // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2020. — Vol 14. — No 1. — P. 38–46.
dc.identifier.citationenThe Intercalation Behaviour and Physico-Chemical Characterisation of Novel Intercalated Nanocomposite from Zinc/Aluminium Layered Double Hydroxides and Broadleaf Herbicide Clopyralid / Sharifah Norain Mohd Sharif, Norhayati Hashim, Illyas Md Isa, Mazidah Mamat, Noorshida Mohd Ali, Suriani Abu Bakar, Mohd Zobir Hussein, Suzaliza Mustafar // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2020. — Vol 14. — No 1. — P. 38–46.
dc.identifier.doidoi.org/10.23939/chcht14.01.038
dc.identifier.urihttps://ena.lpnu.ua/handle/ntb/55776
dc.language.isoen
dc.publisherВидавництво Львівської політехніки
dc.publisherLviv Politechnic Publishing House
dc.relation.ispartofChemistry & Chemical Technology, 1 (14), 2020
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dc.relation.urihttps://doi.org/10.1016/j.ssi.2007.04.016
dc.relation.urihttps://doi.org/10.1016/j.cej.2013.08.010
dc.rights.holder© Національний університет “Львівська політехніка”, 2020
dc.rights.holder© Sharif S., Hashim N., Isa I., Mamat M., Ali N., Bakar S., Hussein M., Mustafar S., 2020
dc.subjectподвійний гідроксид цинку/алюмінію
dc.subjectспільне осадження
dc.subjectклопіралід
dc.subjectінтеркаляція
dc.subjectгербіцид
dc.subjectzinc/aluminium layered double hydroxide
dc.subjectco-precipitation
dc.subjectclopyralid
dc.subjectintercalation
dc.subjectherbicide
dc.titleThe Intercalation Behaviour and Physico-Chemical Characterisation of Novel Intercalated Nanocomposite from Zinc/Aluminium Layered Double Hydroxides and Broadleaf Herbicide Clopyralid
dc.title.alternativeІнтеркаляційна поведінка і фізикохімічна характеристика нового інтеркальованого нанокомпозиту з подвійного гідроксиду цинку/алюмінію та клопіраліду з широколистяних гербіцидів
dc.typeArticle

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