The study of the kinetic and thermodynamic of the blood serum properties free- radical oxidation lipids applying the method of chemiluminescence

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dc.citation.journalTitleЕлементи теорії та прилади твердотілої електроніки
dc.contributor.affiliationLviv Polytechnic National Universityuk_UA
dc.contributor.authorAndrusyk, Iryna
dc.coverage.countryUAuk_UA
dc.coverage.placenameЛьвівuk_UA
dc.date.accessioned2018-08-28T14:35:23Z
dc.date.available2018-08-28T14:35:23Z
dc.date.issued2002
dc.description.abstractWe investigated the physical parameters of chemical reactions which take place in blood serum (BS) at the chemiluminescence (CL) accompanying the process of peroxide oxidization of lipids. The emission intensity, wavelength, lifetime and energy of activation of the CL BS are sensitive to the pathologies. Under investigation CL spectrum it was found essential distinctions in the luminescence intensity in the presence of pathological processes such as tuberculosis and cancer. It was established that the ketonic compounds luminescence. Using a Stern-Volmer the lifetime of excited states equation was found. The data obtained suggest that ketones are in triplet states make the main contribution into CL BS.. An empirical Arrhenius equation for FRO was offered. Dependences of total chemilum inescence on the temperature were estimated. The energy of activation was determined differences of pathological processes were found. It is shown that this parameters change under the condition of pathological processes such as tuberculosis and cancer.uk_UA
dc.format.pages159–164
dc.identifier.citationAndrusyk I. The study of the kinetic and thermodynamic of the blood serum properties free- radical oxidation lipids applying the method of chemiluminescence / I. Andrusyk // Вісник Національного університету "Львівська політехніка". – 2002. – № 458 : Елементи теорії та прилади твердотілої електроніки. – С. 159–164. – Bibliography: 6 titles.uk_UA
dc.identifier.urihttps://ena.lpnu.ua/handle/ntb/42536
dc.language.isoenuk_UA
dc.publisherВидавництво Національного університету "Львівська політехніка"uk_UA
dc.relation.references1. L. A Bulavin, N.M. Zabolotna “ Non-thermal influence on the mm-range electromagnetic radiation on the peroxide oxidation of egg yolk lipoproteins’// Journal of physical studies,- vol 4, -2001,-№l,-p.108-114. 2. A. S. Davydov, Bioloiia i kvantovaia miekhanika (Biology and Quantum mechanics) (Naukova Dumka, Kyiv, 1975.) 3. L. F. Dmitriev “ Radical Reaction and Energy Transformation in Microsomal Membranes. Aarrhenius Equation fir Membrane Process’// Biophysics.- vol 46,-2001,-^l.-p.60-68. 4. D. I. Roshchupkin, N. A. Chudina, and M. A. Murina “Kinetic Peculiarities of Luminol Chemilumine^ cence Induced by Biogenic Chloramines’// Biophysics,- vol 47, -2002,-№2,-p.211-218. 5. R Stephen Brown, John. D. Brennan, and Ulrich J. Krull ” Self-guenching of nitrobenzoxadiazole labeled phospholipids in lipid membranes’// J. Chem. Phys.100 (8),15April 1904., p.6019-6027. 6. V. L. Voeikov and M. V. Chimich “ Enhancement by Argon of luminol-Dependent chemi lumines¬cence in aqueous solutions of NaCl and H2O2"// Biophysics.-vol. 47.-№1.-2002.-p.5-12.uk_UA
dc.rights.holder© Iryna Andrusyk, 2002uk_UA
dc.subjectchemiluminescenseuk_UA
dc.subjectblood serumuk_UA
dc.subjectenergy of activationuk_UA
dc.subjectlifetimeuk_UA
dc.titleThe study of the kinetic and thermodynamic of the blood serum properties free- radical oxidation lipids applying the method of chemiluminescenceuk_UA
dc.typeArticleuk_UA

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Елементи теорії та прилади твердотілої електроніки. – 2002. – №458