Modified polyethersulfone membranes with photocatalytic properties

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dc.citation.epage284
dc.citation.issue3
dc.citation.spage277
dc.citation.volume11
dc.contributor.affiliationNational University of Kyiv-Mohyla Academy
dc.contributor.authorDzhodzhyk, Oleh
dc.contributor.authorKolesnyk, Iryna
dc.contributor.authorKonovalova, Victoriia
dc.contributor.authorBurban, Anatoliy
dc.coverage.placenameLviv
dc.date.accessioned2018-06-21T09:53:14Z
dc.date.available2018-06-21T09:53:14Z
dc.date.created2017-01-20
dc.date.issued2017-01-20
dc.description.abstractЗа допомогою електростатичної взаємодії поліелектролітів методом «layer-by-layer» одержані фото- каталітичні мембрани з наночастинками станум(IV) оксиду. Для іммобілізації нанокаталізатору використовувалися полі- електролітні комплекси різної природи. Як позитивно заряд- жений поліелектроліт використовувався поліетиленімін, як негативно заряджені – натрій карбоксиметилцелюлоза, нат- рій альгінат, κ- чи ι-карагінан. Наявність SnO2 на поверхні мембран підтверджена сканувальною електронною мікро- скопією (СЕМ). Утворення комплексів поліелектролітів під- тверджено за допомогою дзета-потенціометрії. Фотока- талітична активність нанокомпозитних мембран оцінена у процесі нанофільтрації молока. Модифікування поліетер- сульфонових мембран поліелектролітними шарами і наночас- тинками SnO2 дало можливість отримати висококонцент- рований ретентат і досягти стабільної продуктивності мембран більше 8 годин.
dc.description.abstractThe photocatalityc nanocomposite membranes with tin(IV) oxide nanoparticles were obtained by “layerby- layer” self-assembly. Polyelectrolyte complexes with different nature were analyzed as a binder for nanocatalysts. PEI was used as a positively charged polyelectrolyte, and CMC, sodium alginate, κ- or ι- carrageenans were used as negatively charged ones. The presence of SnO2 on the membrane surface was confirmed by a scanning electron microscopy (SEM). Polyelectrolyte complexation was studied by zeta-potential measurement. The photocatalytic activity of the nanocomposite membranes was evaluated in the process of milk nanofiltration. The modification of polyethersulfone membranes with polyelectrolyte layers and SnO2 nanoparticles allowed to produce a highly concentrated retentate and membrane flux remained stable for over 8 h.
dc.format.extent277-284
dc.format.pages8
dc.identifier.citationModified polyethersulfone membranes with photocatalytic properties / Oleh Dzhodzhyk, Iryna Kolesnyk, Victoriia Konovalova, Anatoliy Burban // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2017. — Vol 11. — No 3. — P. 277–284.
dc.identifier.citationenModified polyethersulfone membranes with photocatalytic properties / Oleh Dzhodzhyk, Iryna Kolesnyk, Victoriia Konovalova, Anatoliy Burban // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2017. — Vol 11. — No 3. — P. 277–284.
dc.identifier.urihttps://ena.lpnu.ua/handle/ntb/42095
dc.language.isoen
dc.publisherLviv Politechnic Publishing House
dc.relation.ispartofChemistry & Chemical Technology, 3 (11), 2017
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dc.relation.referencesen[16] Chin S., Chiang K., Fane A., J. Membr. Sci., 2006, 275, 202. https://doi.org/10.1016/j.memsci.2005.09.033
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dc.relation.referencesen[28] Chen X., Wang D., Wang W. et al., Desalin. Water Treat., 2011, 30, 146. https://doi.org/10.5004/dwt.2011.1941
dc.relation.referencesen[29] Madaeni S., Rahimpour A., Polym. Adv. Technol., 2005, 16, 717. https://doi.org/10.1002/pat.647
dc.relation.referencesen[30] Atra R., Vatai G., Bekassy-Molnar E. et al., J. Food Eng., 2005, 67, 325. https://doi.org/10.1016/j.jfoodeng.2004.04.035
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dc.relation.referencesen[32] Limsawat P., Asian J. Food Agro-Ind., 2010, 3, 236.
dc.relation.referencesen[33] Kolesnyk I., Dzhodzhyk O. et al., Ukr.-Polish Conf. "Membrane and sorption processes and technologies", Ukraine, Kyiv 2014, 100.
dc.relation.urihttps://doi.org/10.1016/j.envpol.2010.03.024
dc.relation.urihttps://doi.org/10.1016/j.cej.2016.05.071
dc.relation.urihttps://doi.org/10.1016/j.seppur.2010.03.021
dc.relation.urihttps://doi.org/10.1021/ie504848m
dc.relation.urihttps://doi.org/10.1016/j.seppur.2013.03.030
dc.relation.urihttps://doi.org/10.1002/fuce.201200040
dc.relation.urihttps://doi.org/10.1021/ie502407g
dc.relation.urihttps://doi.org/10.1021/acs.est.5b00904
dc.relation.urihttps://doi.org/10.1021/acs.est.5b03916
dc.relation.urihttps://doi.org/10.1016/j.memsci.2013.09.014
dc.relation.urihttps://doi.org/10.1016/j.seppur.2012.02.014
dc.relation.urihttps://doi.org/10.1016/j.memsci.2013.01.041
dc.relation.urihttps://doi.org/10.1016/j.memsci.2014.04.031
dc.relation.urihttps://doi.org/10.1016/j.memsci.2014.08.016
dc.relation.urihttps://doi.org/10.1016/S0920-5861(99)00227-8
dc.relation.urihttps://doi.org/10.1016/j.memsci.2005.09.033
dc.relation.urihttps://doi.org/10.1016/j.matlet.2016.01.041
dc.relation.urihttps://doi.org/10.1021/nl061700q
dc.relation.urihttps://doi.org/10.1021/es203945v
dc.relation.urihttps://doi.org/10.1007/b11350
dc.relation.urihttps://doi.org/10.3390/pharmaceutics6020281
dc.relation.urihttps://doi.org/10.3168/jds.S0022-0302(05)72865-4
dc.relation.urihttps://doi.org/10.3168/jds.S0022-0302(99)75447-0
dc.relation.urihttps://doi.org/10.5004/dwt.2011.1941
dc.relation.urihttps://doi.org/10.1002/pat.647
dc.relation.urihttps://doi.org/10.1016/j.jfoodeng.2004.04.035
dc.rights.holder© Національний університет „Львівська політехніка“, 2017
dc.rights.holder© Dzhodzhyk O., Kolesnyk I., Konovalova V., Burban A., 2017
dc.subjectполіетерсульфонова мембрана
dc.subjectстанум(IV) оксид
dc.subjectметод «layer-by-layer»
dc.subjectконцентрування молока
dc.subjectpolyethersulfone membrane
dc.subjecttin(IV) oxide
dc.subject“layer-by-layer” method
dc.subjectmilk concentration
dc.titleModified polyethersulfone membranes with photocatalytic properties
dc.title.alternativeМодифіковані поліетерсульфонові мембрани з фотокаталітичними властивостями
dc.typeArticle

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Chemistry & Chemical Technology. – 2017. – Vol. 11, No. 3