Thermodynamic Properties of 2-Methyl-5-arylfuran-3 Carboxylic Acids Chlorine Derivatives in Organic Solvents

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dc.citation.epage287
dc.citation.issue3
dc.citation.spage280
dc.contributor.affiliationLviv Polytechnic National University
dc.contributor.affiliationIvan Franko National University of Lviv
dc.contributor.authorSobechko, Iryna
dc.contributor.authorHorak, Yuri
dc.contributor.authorDibrivnyi, Volodymyr
dc.contributor.authorObushak, Mykola
dc.contributor.authorGoshko, Lubomyr
dc.coverage.placenameЛьвів
dc.coverage.placenameLviv
dc.date.accessioned2020-03-02T13:09:27Z
dc.date.available2020-03-02T13:09:27Z
dc.date.created2019-02-28
dc.date.issued2019-02-28
dc.description.abstractЕкспериментально визначено температурні залежності розчинності 2-метил-5-(2-хлор-5-трифторметил- феніл)-фуран-3-карбонової та 2-метил-5-(2,5-дихлорфеніл)- фуран-3-карбонової кислот в ацетонітрилі, диметилкетоні, ізо-пропанолі та етилацетаті. Розраховані ентальпії плав- лення досліджених речовин та їх ентальпії та ентропії змішування за 298 К. Встановлено рівняння зв’язку концент- рації насиченого розчину з величинами ентальпії і ентропії розчинності за 298 К. Виявлений компенсаційний ефект змішування досліджених кислот зі всіма розчинниками, що містять карбонільну групу.
dc.description.abstractThe temperature dependences of the solubility of 2-methyl-5-(2-chloro-5-trifluoromethylphenyl)-furan- 3-carboxylic acid and 2-methyl-5-(2,5-dichlorophenyl)- furan-3-carboxylic acid in acetonitrile, dimethyl ketone, isopropanol and ethyl acetate have been experimentally determined. The enthalpies of fusion of the investigated substances, as well as their enthalpies and entropies of mixing at 298 K have been calculated. The dependence of the saturated solution concentration on the values of enthalpy and entropy of solubility at 298 K has been determined. The compensating effect of mixing the investigated acids with all solvents containing the carbonyl group has been established.
dc.format.extent280-287
dc.format.pages8
dc.identifier.citationThermodynamic Properties of 2-Methyl-5-arylfuran-3 Carboxylic Acids Chlorine Derivatives in Organic Solvents / Iryna Sobechko, Yuri Horak, Volodymyr Dibrivnyi, Mykola Obushak, Lubomyr Goshko // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2019. — Vol 13. — No 3. — P. 280–287.
dc.identifier.citationenThermodynamic Properties of 2-Methyl-5-arylfuran-3 Carboxylic Acids Chlorine Derivatives in Organic Solvents / Iryna Sobechko, Yuri Horak, Volodymyr Dibrivnyi, Mykola Obushak, Lubomyr Goshko // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2019. — Vol 13. — No 3. — P. 280–287.
dc.identifier.urihttps://ena.lpnu.ua/handle/ntb/46488
dc.language.isoen
dc.publisherВидавництво Львівської політехніки
dc.publisherLviv Politechnic Publishing House
dc.relation.ispartofChemistry & Chemical Technology, 3 (13), 2019
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dc.rights.holder© Національний університет „Львівська політехніка“, 2019
dc.rights.holder© Sobechko I., Horak Y., Dibrivnyi V., Obushak M., Goshko L., 2019
dc.subjectентальпія
dc.subjectентропія розчинності
dc.subjectзмішування і плавлення
dc.subject2-метил-5-(2-хлор-5-трифторметил-феніл)-фуран-3-карбонова кислота
dc.subject2-метил-5-(2
dc.subject5-дихлор-феніл)-фуран-3-карбонова кислота
dc.subjectenthalpy
dc.subjectentropy of solubility
dc.subjectmixing
dc.subjectmelting
dc.subject2-methyl-5-(2-chloro-5-trifluoromethylphenyl)-furan-3-carboxylic acid
dc.subject2-methyl-5-(2
dc.subject5-dichlorophenyl)-furan-3-carboxylic acid
dc.titleThermodynamic Properties of 2-Methyl-5-arylfuran-3 Carboxylic Acids Chlorine Derivatives in Organic Solvents
dc.title.alternativeТермодинамічні властивості розчинів хлорпохідних 2-метил-5-арилфуран-3-карбоксильних кислот в органічних розчинниках
dc.typeArticle

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Chemistry & Chemical Technology. – 2019. – Vol. 13, No. 3