Synthesis of heterocyclic thioamides and copper(II) coordination compounds based on them
Date
2017-01-20
Journal Title
Journal ISSN
Volume Title
Publisher
Lviv Politechnic Publishing House
Abstract
Модифікованою реакцією Вільгеродта-
Кіндлера синтезовані ариламіди гетарил-2-тіокарбонової
кислоти. Отримані сполуки досліджені методами хімічного
аналізу, ІЧ- та 1Н ЯМР-спектроскопією. Методами тради-
ційного та прямого синтезу на основі бензімідазол-2-N-(4-
етоксифенил)карботіоаміда (НL4) отримано кординаційні
сполуки загальної формули [Cu(HL4)Cl2]2 · хCH3OH (х = 0, 2).
Молекулярна і кристалічна структура комплексу
[Cu(HL4)Cl2]2 · 2CH3OH встановлена методом рентгено-
структурного аналізу.
1Arylamides of hetaryl-2-thiocarboxylic acid were synthesized viaWillgerodt–Kindler modified reaction. The final products were studied by means of chemical analysis, IR- and 1H NMR-spectroscopy. The coordination compounds of the general formula [Cu(HL4)Cl2]2 · ·хCH3OH (х = 0, 2) were obtained via traditional and direct synthesis based on benzimidazol-2-N-(4-ethoxyphenyl) carbothioamide (HL4). Using X-ray analysis the molecular and crystal structures of [Cu(HL4)Cl2]2 · 2CH3OH complex were determined.
1Arylamides of hetaryl-2-thiocarboxylic acid were synthesized viaWillgerodt–Kindler modified reaction. The final products were studied by means of chemical analysis, IR- and 1H NMR-spectroscopy. The coordination compounds of the general formula [Cu(HL4)Cl2]2 · ·хCH3OH (х = 0, 2) were obtained via traditional and direct synthesis based on benzimidazol-2-N-(4-ethoxyphenyl) carbothioamide (HL4). Using X-ray analysis the molecular and crystal structures of [Cu(HL4)Cl2]2 · 2CH3OH complex were determined.
Description
Keywords
гетероциклічні тіоаміди, біядерні комплекси купруму(ІІ), рентгеноструктурний аналіз, heterocyclic thioamide, copper(II) binuclear complex, X-ray analysis
Citation
Ranskiy A. Synthesis of heterocyclic thioamides and copper(II) coordination compounds based on them / Anatoliy Ranskiy, Natalia Didenko, Olga Gordienko // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2017. — Vol 11. — No 1. — P. 11–18.