Electrophilic intramolecular cyclization of 1-(N-Alkenyl)-6-methylpyrimidine-2,4-diones

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dc.citation.epage289
dc.citation.issue3
dc.citation.journalTitleChemistry & Chemical Technology
dc.citation.spage285
dc.citation.volume12
dc.contributor.affiliationLesya Ukrainka Volyn National University
dc.contributor.affiliationKyiv National Trade-Economical University
dc.contributor.authorSlyvka, Natalia
dc.contributor.authorGevaza, Yuri
dc.contributor.authorSaliyeva, Lesya
dc.coverage.placenameLviv
dc.date.accessioned2019-06-20T11:19:42Z
dc.date.available2019-06-20T11:19:42Z
dc.date.created2018-01-20
dc.date.issued2018-01-20
dc.description.abstractCинтезовано N-аліл(цинаміл)заміщені похід- ні 6-метилурацилу та проведено реакції їх бромо- та йодо- циклізації, які приводять до утворення похідних дигідрооксазо- лопіримідинію та дигідрооксазинопіримідинію. Запропоновано чинники, які сприяють регіоселективному протіканню цих реакцій.
dc.description.abstractN-Allyl(cinnamyl)substituted derivatives of 6- methyluracil were synthesized. The reactions of their bromo- and iodocyclization were performed which led to the formation of the derivatives of dihydrooxazolopyrimidinium and dihydrooxazinepyrimidinium. The factors that favor the regioselectivity of these reactions were suggested.
dc.format.extent285-289
dc.format.pages5
dc.identifier.citationSlyvka N. Electrophilic intramolecular cyclization of 1-(N-Alkenyl)-6-methylpyrimidine-2,4-diones / Natalia Slyvka, Yuri Gevaza, Lesya Saliyeva // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2018. — Vol 12. — No 3. — P. 285–289.
dc.identifier.citationenSlyvka N. Electrophilic intramolecular cyclization of 1-(N-Alkenyl)-6-methylpyrimidine-2,4-diones / Natalia Slyvka, Yuri Gevaza, Lesya Saliyeva // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2018. — Vol 12. — No 3. — P. 285–289.
dc.identifier.urihttps://ena.lpnu.ua/handle/ntb/45177
dc.language.isoen
dc.publisherLviv Politechnic Publishing House
dc.relation.ispartofChemistry & Chemical Technology, 3 (12), 2018
dc.relation.references[1] Sukach V., Thachuk V., Rusanov E. et al.: Tetrahedron, 2012,68, 8408. https://doi.org/10.1016/j.tet.2012.07.099
dc.relation.references[2] Vaskevych R., Khrypak S., Stanynets V. et al.: Ukr. Khim. Zh.,2000, 66, 47.
dc.relation.references[3]Bentya A., Vaskevych R., StanynetsV.:Ukr. Khim. Zh., 2008, 74, 94.
dc.relation.references[4] Gevaza Yu., Stanynets V.: Ukr. Khim. Zh., 2002, 68, 67.
dc.relation.references[5] KimD., Shmygarev V.:Khimiya Heterotsikl. Soed., 1995, 2, 211.
dc.relation.references[6] Zborovskyi Yu., Orysyk V., Dobos A. et al.: Ukr. Khim. Zh.,2002, 68, 95.
dc.relation.references[7] Slyvka N., Gevaza Yu., Stanynets V., Korolchuk S.: Ukr. Khim. Zh., 2010, 76, 102.
dc.relation.references[8] Slyvka N., Gevaza Yu., Stanynets V.: Khimiya Heterotsikl. Soed., 2004, 5, 776.
dc.relation.references[9] Vaskevych A., Bentya A., Staninets V.: Zh. Org. Khim., 2009,45, 1848.
dc.relation.references[10] Saliyeva L., Slyvka N., Vaskevych R., VovkM.: Ukr. Khim. Zh., 2016, 82, 64.
dc.relation.references[11] Dyachenko I., Vaskevych R., VovkM.: Zh. Org. Khim., 2014,50, 270.
dc.relation.references[12] Sukach V., Thachuk V., Shoba V. et al.: Eur. J. Org. Chem.,2014, 7, 1452. https://doi.org/10.1002/ejoc.201301542
dc.relation.references[13] Dyachenko I., Vaskevych R., Vovk M. et al.: Zh. Org. Khim.,2016, 52, 745.
dc.relation.references[14] Shoba V., Thachuk V., Sukach V. et al.: [in:] Attanazi O., Spinelli D. (Eds.), Targets in Heterocyclic Systems: Chemitry and Properties. Vol. 17. Italian Society of Chemistry, Roma 2013, 147.
dc.relation.references[15] Novakov I., Orlinson B., Navrotskii M.: Zh. Org. Khim., 2005,41, 607.
dc.relation.referencesen[1] Sukach V., Thachuk V., Rusanov E. et al., Tetrahedron, 2012,68, 8408. https://doi.org/10.1016/j.tet.2012.07.099
dc.relation.referencesen[2] Vaskevych R., Khrypak S., Stanynets V. et al., Ukr. Khim. Zh.,2000, 66, 47.
dc.relation.referencesen[3]Bentya A., Vaskevych R., StanynetsV.:Ukr. Khim. Zh., 2008, 74, 94.
dc.relation.referencesen[4] Gevaza Yu., Stanynets V., Ukr. Khim. Zh., 2002, 68, 67.
dc.relation.referencesen[5] KimD., Shmygarev V.:Khimiya Heterotsikl. Soed., 1995, 2, 211.
dc.relation.referencesen[6] Zborovskyi Yu., Orysyk V., Dobos A. et al., Ukr. Khim. Zh.,2002, 68, 95.
dc.relation.referencesen[7] Slyvka N., Gevaza Yu., Stanynets V., Korolchuk S., Ukr. Khim. Zh., 2010, 76, 102.
dc.relation.referencesen[8] Slyvka N., Gevaza Yu., Stanynets V., Khimiya Heterotsikl. Soed., 2004, 5, 776.
dc.relation.referencesen[9] Vaskevych A., Bentya A., Staninets V., Zh. Org. Khim., 2009,45, 1848.
dc.relation.referencesen[10] Saliyeva L., Slyvka N., Vaskevych R., VovkM., Ukr. Khim. Zh., 2016, 82, 64.
dc.relation.referencesen[11] Dyachenko I., Vaskevych R., VovkM., Zh. Org. Khim., 2014,50, 270.
dc.relation.referencesen[12] Sukach V., Thachuk V., Shoba V. et al., Eur. J. Org. Chem.,2014, 7, 1452. https://doi.org/10.1002/ejoc.201301542
dc.relation.referencesen[13] Dyachenko I., Vaskevych R., Vovk M. et al., Zh. Org. Khim.,2016, 52, 745.
dc.relation.referencesen[14] Shoba V., Thachuk V., Sukach V. et al., [in:] Attanazi O., Spinelli D. (Eds.), Targets in Heterocyclic Systems: Chemitry and Properties. Vol. 17. Italian Society of Chemistry, Roma 2013, 147.
dc.relation.referencesen[15] Novakov I., Orlinson B., Navrotskii M., Zh. Org. Khim., 2005,41, 607.
dc.relation.urihttps://doi.org/10.1016/j.tet.2012.07.099
dc.relation.urihttps://doi.org/10.1002/ejoc.201301542
dc.rights.holder© Національний університет „Львівська політехніка“, 2018
dc.rights.holder©Kyiv National Trade-Economical University
dc.subjectелектрофільна внутрішньомолекулярна циклізація
dc.subjectметилурацил
dc.subjectбромоциклізація
dc.subjectйодоциклізація
dc.subjectрегіоселективність
dc.subjectдигідроксоазолопіримінідіум
dc.subjectдигідрокси- азинпіримінідіум
dc.subjectelectrophilic intramolecular cyclization
dc.subjectmethyluracil
dc.subjectbromocyclization
dc.subjectiodocyclization
dc.subjectregioselectivity
dc.subjectdihydrooxazolopyrimidinium
dc.subjectdihydrooxazinepyrimidinium
dc.titleElectrophilic intramolecular cyclization of 1-(N-Alkenyl)-6-methylpyrimidine-2,4-diones
dc.title.alternativeЕлектрофільна внутрішньомолекулярна циклізація 1-(N-Алкеніл)-6-метилпіримідин-2,4-діонів
dc.typeArticle

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Chemistry & Chemical Technology. – 2018. – Vol. 12, No. 3